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Synfacts 2005(0): 0018-0018
DOI: 10.1055/s-2005-865369
DOI: 10.1055/s-2005-865369
Synthesis of Heterocycles
© Georg Thieme Verlag Stuttgart · New York
Synthesis of 1-Phosphabarrelene Phosphine Sulfide Substituted Palladium(II) Complexes
O. Piechaczyk, M. Doux, L. Ricard, P. le Floch*
Ecole Polytechnique, Palaiseau, France
Further Information
Publication History
Publication Date:
20 July 2005 (online)
Significance
A general Diels-Alder-based synthesis of 1-phosphabarrelenes from substituted phosphinines is reported. Palladium complexes have been prepared which serve as good ligands for cross-coupling reactions and in the allylation of secondary amines with TON up to 7 × 106. X-ray crystal structural analysis and computational data of the complexes are presented.