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Synfacts 2006(10): 1030-1030
DOI: 10.1055/s-2006-949318
DOI: 10.1055/s-2006-949318
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Rhodium-Catalyzed Asymmetric Hydrogenation
B. Breit*, E. Fuchs
Albert-Ludwigs-Universität Freiburg, Germany
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. September 2006 (online)

Significance
Phosphabarrelenes with rhodium were recently shown by the same authors to be reactive catalysts for hydroformylation of internal alkenes (Chem. Commun. 2004, 694-695). Using these newly designed ligands, several monodentate and bidentate ligands were synthesized. These catalysts were subjected to hydrogenation conditions of itaconic ester and acetamidoacrylates.