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Synfacts 2007(9): 0954-0954
DOI: 10.1055/s-2007-968858
DOI: 10.1055/s-2007-968858
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Enantioselective Allylation of Imines Using a Pincer Complex
J. Aydin, K. S. Kumar, M. J. Sayah, O. A. Wallner, K. J. Szabó*
Stockholm University, Sweden
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. August 2007 (online)
Significance
The chiral pincer complex described here is successfully employed for the allylation of sulfonimines. It is important to recognize that the level of enantioselectivity achieved is the highest for pincer complex catalyzed allylations and for palladium-catalyzed allylation of sulfonimines.