Homoconjugated Oligomers

N. Caraballo-Martínez; M. del Rosario Colorado Heras; M. M. Blázquez; J. O. Barcina; A. G. Martínez; M. del Rosario Torres Salvador

doi:10.1055/s-2007-968991

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Synfacts 2007(10): 1049-1049
DOI: 10.1055/s-2007-968991

Synthesis of Materials and Unnatural Products

Homoconjugated Oligomers

Contributor(s): Timothy M. Swager, Jeewoo Lim
N. Caraballo-Martínez, M. del Rosario Colorado Heras, M. M. Blázquez, J. O. Barcina*, A. G. Martínez, M. del Rosario Torres Salvador
Universidad Complutense de Madrid, Spain

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Publikationsdatum:
07. November 2007 (online)

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Significance

The authors describe the synthesis of homoconjugated oligomers (1-4) from cofacial 7,7-diphenylnorbornane building blocks. While electron delocalization in conducting polymers via direct conjugation is well known, the examples of delocalization via homoconjugation are scarce.