Synfacts 2008(6): 0585-0585  
DOI: 10.1055/s-2008-1067061
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York

Rhodamine Derivatives Get Redder with Silicon

Contributor(s): Timothy M. Swager, Jose M. Lobez
M. Fu, Y. Xiao*, X. Qian, D. Zhao, Y. Xu
Dalian University of Technology and East China University of Science and Technology, Shanghai, P. R. of China
Further Information

Publication History

Publication Date:
21 May 2008 (online)

Significance

Long-wavelength fluorescent dyes are relevant in biology because they can avoid the interference of inherent biological fluorescence. The substitution of oxygen atom by silicon in a rhodamine scaffold results in a bathochromic shift of absorption and emission. Despite the low quantum yields reported, this is an innovative strategy to tune the optical properties of dyes.