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Synfacts 2008(6): 0616-0616
DOI: 10.1055/s-2008-1072628
DOI: 10.1055/s-2008-1072628
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Vanadium-Catalyzed Asymmetric Transcyanation of Aliphatic Aldehydes
J. Takaki, H. Egami, K. Matsumoto, B. Saito, T. Katsuki*
Kyushu University, Fukuoka, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Mai 2008 (online)
Significance
Utilizing a non-conventional cyanide source to produce cyanohydrins the authors report a highly enantioselective method for aliphatic aldehydes. Continuing their investigation of the reduced salen ligand derivatives (salalen) the reaction was found to be sensitive to a number of factors including temperature and substrate choice.