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Synfacts 2008(10): 1072-1072  
DOI: 10.1055/s-2008-1078132
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Diastereoselective Cyclization/Borylation of Enediynes

Contributor(s): Mark Lautens, Frédéric Ménard
J. Marco-Martínez, E. Buñuel, R. Muñoz-Rodríguez, D. J. Cárdenas*
Universidad Autónoma de Madrid, Spain
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Publication History

Publication Date:
22 September 2008 (online)

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Significance

Organoboron reagents have found wide applicability in many metal-catalyzed processes. As most readily available organoborons are simple aromatic structures, access to more elaborated allylboron reagents is desirable. In the domino cyclization above, complex allylboronic esters are formed from simple linear precursors.