Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C–F Bond Activation

Jingwen You; Qiang Chen; Yasushi Nishihara

doi:10.1055/a-1484-6216

Synthesis, Inhaltsverzeichnis

Synthesis 2021; 53(17): 3045-3050
DOI: 10.1055/a-1484-6216

special topic

Bond Activation – in Honor of Prof. Shinji Murai

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C–F Bond Activation

Jingwen You

^aGraduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan

,

Qiang Chen

^aGraduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan

,

Yasushi Nishihara ∗

^bResearch Institute for Interdisciplinary Science, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan

› Institutsangaben

Abstract

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Abstract

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon–sulfur bonds via a highly efficient decarbonylative process.

Key words

C–F bond activation - decarbonylation - thioetherification - acyl fluorides - sulfides

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Referenzen

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