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Synthesis 2023; 55(07): 1123-1129
DOI: 10.1055/a-1983-3890
DOI: 10.1055/a-1983-3890
paper
Samarium-Promoted Homocoupling of Benzaldehydes and In Situ Condensation with Esters Under the Catalysis of Cuprous Iodide
The project was sponsored by the Shandong Provincial Key Research and Development Program (SPKR&DP) (2019GGXI02036), and the Open Project of Faculty of Chemistry of Qingdao University of Science and Technology (QUSTHX201902).
Abstract
A novel C–H functionalization method was successfully explored by a reductive three molecule coupling of benzaldehydes and esters mediated by samarium and cuprous iodide; thus, the diarylmethanol skeletons were afforded readily via an in situ esterification in one-pot. Substrates including a variety of esters and different benzaldehydes were investigated, and the desired products were readily obtained in moderate to good yields under mild conditions.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1983-3890.
- Supporting Information
Publication History
Received: 03 September 2022
Accepted after revision: 21 November 2022
Accepted Manuscript online:
21 November 2022
Article published online:
14 December 2022
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