Understanding and Describing London Dispersion Effects in ­Transition-Metal-Catalyzed C–H Activations

Binbin Yuan; João C. A. Oliveira; Lutz Ackermann

doi:10.1055/a-2060-3288

Synlett, Inhaltsverzeichnis

Synlett 2023; 34(10): 1098-1112
DOI: 10.1055/a-2060-3288

account

Dispersion Effects

Understanding and Describing London Dispersion Effects in Transition-Metal-Catalyzed C–H Activations

Binbin Yuan‡

^aInstitut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammanstraße 2, 37077 Göttingen, Germany

,

João C. A. Oliveira ‡

^aInstitut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammanstraße 2, 37077 Göttingen, Germany

,

Lutz Ackermann ∗

^aInstitut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammanstraße 2, 37077 Göttingen, Germany

^bWöhler Research Institute for Sustainable Chemistry, Tammanstraße 2, 37077, Göttingen, Germany

› Institutsangaben

Abstract

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Abstract

Transition-metal-catalyzed C–H activation has emerged as a powerful strategy for molecular synthesis with unique levels of resource economy. Weak secondary dispersion interactions were found to play an essential role in these transformations in terms of kinetic efficacy and selectivity. This Account summarizes our group’s recent progress in the rationalization and quantification of London dispersion effects within the transition-metal-catalyzed C–H activation.

1 Introduction

2 Annulation Reactions

3 Alkylation Reactions

4 Arylation Reactions

5 Olefination Reactions

6 Oxygenation Reactions

7 Conclusion

Key words

C–H activation - London dispersion effect - DFT calculations - transition metals - catalysis

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Referenzen

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Understanding and Describing London Dispersion Effects in ­Transition-Metal-Catalyzed C–H Activations

Understanding and Describing London Dispersion Effects in Transition-Metal-Catalyzed C–H Activations