Synthesis of β-Hydroxyhydrophosphonic Acids from Inorganic Sodium Hypophosphite

Dang-Wei Qian; Jin Yang; Gang-Wei Wang; Shang-Dong Yang

doi:10.1055/a-2133-1963

Synthesis, Inhaltsverzeichnis

Synthesis 2024; 56(11): 1677-1686
DOI: 10.1055/a-2133-1963

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New Trends in Organic Synthesis from Chinese Chemists

Synthesis of β-Hydroxyhydrophosphonic Acids from Inorganic Sodium Hypophosphite

Dang-Wei Qian

^aState Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. of China

,

Jin Yang

^aState Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. of China

,

Gang-Wei Wang

^aState Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. of China

,

Shang-Dong Yang∗

^aState Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. of China

^bState Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. of China

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Abstract

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Abstract

An efficient approach to access β-hydroxyhydrophosphonic acid derivatives is reported by ring-opening reaction of readily available epoxides with green, inexpensive, and safe inorganic salt sodium hypophosphate as the phosphorus source in the presence of silver trifluoromethanesulfonate as the catalyst. The reaction is achieved under simple operation and exhibits excellent selectivity as well as good functional group compatibility.

Key words

sodium hypophosphite - β-hydroxyhydrophosphonic acid - ethylene oxide compounds

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