Solvent- and Base-Free Aerobic Oxidation with Pt@MOF-177

S. Proch; J. Herrmannsdörfer; R. Kempe; C. Kern; A. Jess; L. Seyfarth; [nl]J. Senker

doi:10.1055/s-0028-1087258

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synfacts 2009(1): 0111-0111
DOI: 10.1055/s-0028-1087258

Polymer-Supported Synthesis

Solvent- and Base-Free Aerobic Oxidation with Pt@MOF-177

Contributor(s): Yasuhiro Uozumi, Noboru Kobayashi
S. Proch, J. Herrmannsdörfer, R. Kempe*, C. Kern, A. Jess, L. Seyfarth, J. Senker
Universität Bayreuth, Germany

Further Information

Publication History

Publication Date:
18 December 2008 (online)

Permissions and Reprints

Significance

Platinum nanoparticles were prepared in the [Zn₄O(btb)₂]₈ {MOF-177, btb = 1,3,5-[^-OC(O)]₃C₆H₃} host lattice (Pt@MOF-177) by gas-phase loading of MOF-177 with [Me₃PtCp’], followed by reduction with 100 bar of hydrogen at 100 ˚C for 24 h. Pt@MOF-177 catalyzed the solvent- and base-free oxidation reaction of cinnamyl and benzylic primary alcohols at room temperature with air to afford the corresponding aldehydes with 50-99% conversion (9 examples). The TON of this oxidation was up to 968.