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Synfacts 2009(6): 0658-0658
DOI: 10.1055/s-0029-1216684
DOI: 10.1055/s-0029-1216684
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Direct Cu(II)-Catalyzed Amination of Azoles with Amines and Oxygen
D. Monguchi, T. Fujiwara, H. Furukawa, A. Mori*
Kobe University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
25. Mai 2009 (online)

Significance
Direct transition-metal-catalyzed C-H functionalization is of great interest in organic chemistry due to its economic advantages and high atom efficiency. Catalytic oxidative amination of azoles via C-H, N-H coupling reported here, is a simple and useful method for the synthesis of aminoazoles which are highly important intermediates, especially in material sciences.