Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2010(9): 1053-1053
DOI: 10.1055/s-0030-1257891
DOI: 10.1055/s-0030-1257891
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Directed Iron-Catalyzed Arylation of Olefins
L. Ilies, J. Okabe, N. Yoshikai, E. Nakamura*
The University of Tokyo, Japan
Further Information
Publication History
Publication Date:
23 August 2010 (online)
Significance
An iron-catalyzed oxidative Heck-type reaction which allows the straightforward coupling of organomagnesium and organozinc reagents with olefins was developed. The reaction proceeds via chelation-controlled arylation under mild conditions and without the need of external ligands.