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Synlett 2012; 23(17): 2501-2503
DOI: 10.1055/s-0031-1290462
letter
© Georg Thieme Verlag Stuttgart · New York

1,4,8,11,15,18,22,25-Octafluorophthalocyaninato Zinc (F8PcZn)

Göran Crucius
a   Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany   Fax: +49(7071)295244   Email: hanack@uni-tuebingen.de   Email: thomas.ziegler@uni-tuebingen.de
,
Alexey Lyubimtsev
b   Ivanovo State University of Chemistry and Technology, Organic Chemistry Department, F. Engels Str. 7, 153460 Ivanovo, Russia
,
Markus Kramer
a   Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany   Fax: +49(7071)295244   Email: hanack@uni-tuebingen.de   Email: thomas.ziegler@uni-tuebingen.de
,
Michael Hanack*
a   Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany   Fax: +49(7071)295244   Email: hanack@uni-tuebingen.de   Email: thomas.ziegler@uni-tuebingen.de
,
Thomas Ziegler*
a   Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany   Fax: +49(7071)295244   Email: hanack@uni-tuebingen.de   Email: thomas.ziegler@uni-tuebingen.de
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Further Information

Publication History

Received: 16 July 2012

Accepted after revision: 20 August 2012

Publication Date:
28 September 2012 (online)

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Abstract

1,4,8,11,15,18,22,25-Octafluorophthalocyanato zinc (F8PcZn), which is not described in the literature up to date, was obtained from 3,6-difluorophthalonitrile in anhydrous DMF, DBU, and Zn(OAc)2 at 145 °C. 3,6-Difluorophthalonitrile was synthesized by a multistep procedure.

Key words

1,4,8,11,15,18,22,25-octafluorophthalocyanato zinc - glycosylated phthalocyanines - fluorinated phthalocyanines - 3,6-difluorophthalonitrile - phthalocyanato metals
 

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