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DOI: 10.1055/s-0031-1291005
Biomimetic in situ Regeneration of Cofactors NAD(P)+ and NAD(P)H Models Hantzsch Esters and Dihydrophenanthridine
Publication History
Received: 20 February 2012
Accepted after revision: 20 March 2012
Publication Date:
14 May 2012 (online)
Abstract
Biomimetic recycling of the expensive cofactors NAD(P)H/NAD(P)+ and their models is a promising area in bio-inspired synthesis. This paper highlights the recent advances in the in situ regeneration of the oxidized cofactors NAD(P)+ through oxidation of cofactors NAD(P)H in the presence of an alcohol dehydrogenase by means of dioxygen and a synthetic Fe(III) porphyrin as a biomimetic NAD(P)H oxidase or flavin as catalyst, and biomimetic in situ regeneration of the expensive NAD(P)H models Hantzsch esters (HEH) and 9,10-dihydrophenanthridine (DHPD) by transition-metal and chiral Brønsted acid catalyzed relay asymmetric hydrogenation.
1. Introduction
2. Biomimetic in situ Regeneration of NAD(P)+
3. Biomimetic in situ Regeneration of Hantzsch Esters (HEH)
4. Biomimetic in situ Regeneration of Dihydrophenanthridine (DHPD)
5. Future Perspective
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