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Synlett 2014; 25(17): 2447-2450
DOI: 10.1055/s-0034-1379018
DOI: 10.1055/s-0034-1379018
letter
When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids
Weitere Informationen
Publikationsverlauf
Received: 10. Juni 2014
Accepted after revision: 03. August 2014
Publikationsdatum:
09. September 2014 (online)
Abstract
Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.
Key words
monocationic ionic liquids - dicationic ionic liquids - anion metathesis - dimethyl phosphateSupporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
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