Synthesis, Table of Contents

Synthesis 2018; 50(05): 1015-1019
DOI: 10.1055/s-0036-1589153

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© Georg Thieme Verlag Stuttgart · New York

Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes

Kazutaka Matoba*

^aChemical Research Laboratories, Nissan Chemical Industries, Ltd., Funabashi, Chiba, 274-8507, Japan Email: matobak@nissanchem.co.jp

,

Aya Eizawa

^bDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan Email: ynishiba@sys.t.u-tokyo.ac.jp

,

Shunsuke Nishimura

^bDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan Email: ynishiba@sys.t.u-tokyo.ac.jp

,

Kazuya Arashiba

^bDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan Email: ynishiba@sys.t.u-tokyo.ac.jp

,

Kazunari Nakajima

^bDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan Email: ynishiba@sys.t.u-tokyo.ac.jp

,

Yoshiaki Nishibayashi *

^bDepartment of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan Email: ynishiba@sys.t.u-tokyo.ac.jp

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Abstract

A synthetic method for N-heterocyclic carbene- and phosphine-based PCP-type pincer ligand is described on a large scale. Some transition-metal complexes bearing the PCP-type pincer ligand are prepared and characterized by X-ray crystal structure analysis.

Key words

Key words

N-heterocyclic carbene - PCP ligand - phosphine - pincer ligand - transition-metal complexes

References
1 Eizawa A. Arashiba K. Tanaka H. Kuriyama S. Matsuo Y. Nakajima K. Yoshizawa K. Nishibayashi Y. Nat. Commun. 2017; 8: 14874

For recent selected reviews, see:

2a Bezdek MJ. Chirik PJ. Angew. Chem. Int. Ed. 2016; 55: 7892
2b Čorić I. Holland PL. J. Am. Chem. Soc. 2016; 138: 7200
2c Burford RJ. Fruzyk MD. Nat. Rev. Chem. 2017; 1: 26
2d Nitrogen Fixation, In Topics in Organometallic Chemistry . Vol. 60. Nishibayashi Y. Springer; Berlin: 2017

3a Nishibayashi Y. Inorg. Chem. 2015; 54: 9234
3b Tanaka H. Nishibayashi Y. Yoshizawa K. Acc. Chem. Res. 2016; 49: 987
3c Tanabe Y. Nishibayashi Y. Chem. Rec. 2016; 16: 1549

4 Arashiba K. Sasaki K. Kuriyama S. Miyake Y. Nakanishi H. Nishibayashi Y. Organometallics 2012; 31: 2035
5 Arashiba K. Miyake Y. Nishibayashi Y. Nat. Chem. 2011; 3: 120

6a Kinoshita E. Arashiba K. Kuriyama S. Miyake Y. Shimazaki R. Nakanishi H. Nishibayashi Y. Organometallics 2012; 31: 8437
6b Tanaka H. Arashiba K. Kuriyama S. Sasada A. Nakajima K. Yoshizawa K. Nishibayashi Y. Nat. Commun. 2014; 5: 3737
6c Kuriyama S. Arashiba K. Nakajima K. Tanaka H. Kamaru N. Yoshizawa K. Nishibayashi Y. J. Am. Chem. Soc. 2014; 136: 9719
6d Kuriyama S. Arashiba K. Nakajima K. Tanaka H. Yoshizawa K. Nishibayashi Y. Chem. Sci. 2015; 6: 3940
6e Arashiba K. Eizawa A. Tanaka H. Nakajima K. Yoshizawa K. Nishibayashi Y. Bull. Chem. Soc. Jpn. 2017; 90: 1111

7 Nishimura, S.; Eizawa, A.; Arashiba, K.; Nakajima, K.; Nishibayashi, Y. The 96th Annual Meeting of the Chemical Society of Japan, Kyoto, March 24, 2016; 1E5-38.
8 For a recent selected review, see: Milstein D. Top. Catal. 2010; 53: 915
9 Segawa Y. Yamashita M. Nozaki K. J. Am. Chem. Soc. 2009; 131: 9201

10a Hellmann H. Bader J. Birkner H. Schumacher O. Liebigs Ann. Chem. 1962; 659: 49
10b Steininger E. Chem. Ber. 1962; 95: 2541
10c Rudd PA. Liu S. Gagliardi L. Young VG. Jr. Lu CC. J. Am. Chem. Soc. 2011; 133: 20724

11 Steinke T. Shaw BK. Jong H. Patrick BO. Fryzuk MD. Organometallics 2009; 28: 2830
12 Viciano M. Poyatos M. Sanaú M. Peris E. Rossin A. Ujaque G. Lledós A. Organometallics 2006; 25: 1120

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Supplementary Material

Supporting Information