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Synlett 2018; 29(16): 2108-2116
DOI: 10.1055/s-0037-1609627
DOI: 10.1055/s-0037-1609627
account
The Invention of New Methodologies: An Opportunity for Dating Natural Products
Further Information
Publication History
Received: 12 June 2018
Accepted after revision: 02 July 2018
Publication Date:
14 August 2018 (online)
Abstract
This Account surveys almost two decades of methodological developments and their straightforward applications to the total synthesis of simple natural products. The main directions covered include radical chemistry and cascades, electrophilic catalysis based on coinage metals, and asymmetric synthesis based on bis(sulfoxides) auxiliaries.
1 Introduction
2 Radical Cascades
2.1 N-Cyanamides
2.2 Homolytic Substitution at Sulfur Atom to Give Sultines
3 Electrophilic Catalysis Based on Platinum(II) and Gold(I) Complexes
4 From Alkylydene Bis(sulfoxides) to Chiral Carboxylic Acids
5 Conclusion and Perspectives
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For representative contributions from our group, see:
See also:
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For some recent contributions:
For similar approaches, see:
Calculation assessed that the metallic species involved is a cuprate rather than a copper reagent, see:
For similar directing effect of the sulfinyl moiety, see also:
For reviews on fenoprofen pharmaceutical activity, see:
For the racemic synthesis, see: