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Synfacts 2019; 15(08): 0950
DOI: 10.1055/s-0039-1690479
DOI: 10.1055/s-0039-1690479
Peptide Chemistry
Azotide Ligands for Hetero-Diels–Alder Reactions
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. Juli 2019 (online)
Significance
Azotides, which are abundantly found as scaffolds in natural products, are known to coordinate metal ions. The author report new azotide ligands for enantioselective Lewis acid catalysis.
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Comment
The ligands were readily prepared from the chiral pool of amino acids and demonstrated enantioselectivity when used as ligands in a cobalt(II)-catalyzed hetero-Diels–Alder reaction.
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