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Synfacts 2024; 20(02): 0171
DOI: 10.1055/s-0043-1772976
DOI: 10.1055/s-0043-1772976
Polymer-Supported Synthesis
Cross-Coupling Reactions Catalyzed by Regularly Spaced Copper Atom Pairs on Polymeric Carbon Nitride
Hai X,
Zheng Y,
Yu Q,
Guo N,
Xi S,
*,
Zhao X,
Mitchell S,
Luo X,
Tulus V,
Wang M,
Sheng X,
Ren L,
Long X,
Li J,
He P,
Lin H,
Cui Y,
Peng X,
Shi J,
Wu J,
Zhang C,
Zou R,
Guillén-Gosálbez G,
Pérez-Ramírez J,
*,
Koh MJ,
*,
Zhu Y,
*,
Li J,
*,
Lu J.
*
National University of Singapore and Agency for Science, Technology and Research, Singapore; ETH Zurich, Switzerland; Tsinghua University, Beijing and Southern University of Science and Technology, Shenzhen, P. R. of China
Geminal-Atom Catalysis for Cross-Coupling.
Nature 2023;
622: 754-760
Geminal-Atom Catalysis for Cross-Coupling.
Nature 2023;
622: 754-760
Significance
A heterogeneous copper catalyst supported on polymeric carbon nitride (Cug/PCN) catalyzed cross-coupling reactions of aryl halides with amines, alcohols, alkynes, arenes, or thiols, resulting in the formation of the corresponding C–N, C–O, C–C or C–S coupled products (eqs. 2-5).
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Comment
Cug/PCN was prepared according to equation 1. Cug/PCN contains regularly spaced copper atom pairs, with a Cu–Cu distance of approximately 4 Å.
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Publikationsverlauf
Artikel online veröffentlicht:
16. Januar 2024
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