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Synlett 2024; 35(20): 2346-2366
DOI: 10.1055/s-0043-1775409
DOI: 10.1055/s-0043-1775409
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Special Issue to Celebrate the 75th Birthday of Prof. B. C. Ranu
Methanol for Hydrogenation and Methylation of Carbonyls: Advances and Challenges in Homogeneous Catalysis
The authors are grateful for funding from the University Grants Commission (UGC) and the Science and Engineering Research Board (SERB) (CRG/2021/002384).
Abstract
The catalytic dehydrogenation of methanol to give formaldehyde or formic acid, followed transfer hydrogenation and/or tandem (de)hydrogenation for the hydrogenation and C-methylation of carbonyls, offers advantages over traditional methods, including milder reaction conditions, improved safety, greater selectivity, and enhanced sustainability. This account provides a comprehensive overview of homogeneous catalysts reported for the transfer hydrogenation and C-methylation of various substrates, including ketones, chalcones, esters, and amides, using methanol as both a hydrogen donor and methylation source. We provide specific examples and mechanistic insights for each strategy, offering a thorough and concise overview of recent advancements from 2014 to 2024.
1 Introduction
2 Methanol Activation Strategies
3 Hydrogenation of Carbonyls
4 Methylation of Carbonyls
5 Outlook and Summary
Key words
methanol - hydrogenation - dehydrogenation - methylation - aldehyde - ketone - chalcone - carbonylPublikationsverlauf
Eingereicht: 06. August 2024
Angenommen nach Revision: 10. September 2024
Artikel online veröffentlicht:
18. Oktober 2024
© 2024. Thieme. All rights reserved
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