Metallo-Enzyme Model in Pure Water: Cyclodextrin-Lanthanide Tris(perfluoroalkanesulfonyl)methide and Bis(perfluoroalkanesulfonyl)amide Complexes

Abstract

Inclusion complexes of cyclodextrin/cyclodextrin co­polymer and lanthanide tris(perfluorobutanesulfonyl)methide/bis(perfluorobutanesulfonyl)amide, namely metallo-enzyme mo­del, are efficient and recyclable super Lewis acid catalysts, which can promote Diels-Alder and Mukaiyama-aldol reactions in pure water.

cyclodextrin - Lewis acids - catalysis - lanthanides - aqueous reactions

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