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Synlett 2003(7): 0993-0994
DOI: 10.1055/s-2003-39318
DOI: 10.1055/s-2003-39318
LETTER
© Georg Thieme Verlag Stuttgart ˙ New York
A Formal Total Synthesis of (-)-Dysiherbaine
Further Information
Publication History
Received
14 April 2003
Publication Date:
20 May 2003 (online)


Abstract
A key intermediate hexahydrofuropyran 2 to (-)-dysiherbaine 1 has been synthesized concisely via intramolecular oxymercuration and iodocyclization to install the asymmetric centers at the ring junction and the amino group in the tetrahydropyran stereoselectively.
Key words
glutamate receptors - (-)-dysiherbaine - hexahydrofuropyran - iodocyclization - mercuriocyclization