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Synfacts 2005(0): 0034-0034
DOI: 10.1055/s-2005-869982
DOI: 10.1055/s-2005-869982
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Preparation of Star-Shaped Linear Nanosized polycyclic aromatics
Contributor(s): Yasuhiro UozumiX.-Y. Cao, H. Zi, W. Zhang, H. Li, J. Pei*
Peking University, P. R. of China
Star-Shaped and Linear Nanosized Molecules Functionalized with Hexa-peri-hexabenzocoronene: Synthesis and Optical Properties
J. Org. Chem. 2005, 70: 3645-3653
Peking University, P. R. of China
Star-Shaped and Linear Nanosized Molecules Functionalized with Hexa-peri-hexabenzocoronene: Synthesis and Optical Properties
J. Org. Chem. 2005, 70: 3645-3653
Further Information
Publication History
Publication Date:
20 July 2005 (online)
Key words
polycyclic aromatic - hexabenzocoronene - optical property
Significance
Nanosized molecules bearing mono-, bis-, and tris(hexa-peri-hexabenzocoronene) group(s) (HBC) were prepared from truxene derivatives (R = hexyl) via Sonogashira coupling and decarbonylative Diels-Alder reaction followed by the oxidation with FeCl3 (preparation of trisHBC derivative is shown above).
Comment
The structural analysis and the optical properties of the star shaped aromatics were performed with MALDI-TOF, UV-Vis and other methods.