Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2006(3): 0297-0297
DOI: 10.1055/s-2006-932001
DOI: 10.1055/s-2006-932001
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart · New York
Hydrogenation Reactions Utilizing Capillary Column Reactors
J. Kobayashi, Y. Mori, S. Kobayashi*
The University of Tokyo, Japan
Further Information
Publication History
Publication Date:
21 February 2006 (online)
Significance
A less-space and low-cost capillary reactor was developed. Tetrakis(triphenylphosphine)palladium was immobilized onto the inner surface of the capillary column by using the polymer micelle incarceration method. The palladium-immobilized capillary was connected to a T-shaped connector, and hydrogen and a substrate were fed via the connector. Hydrogenation of 1-phenyl-1-cyclohexene gave phenylcyclohexane in a quantitative yield (2.8 mmol/h). No leaching of palladium was observed by ICP analysis after the reactions.