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Synfacts 2007(6): 0615-0615
DOI: 10.1055/s-2007-968555
DOI: 10.1055/s-2007-968555
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Pd-Catalyzed N-Arylation-Cyclization-C-Arylation of Homoallylhydroxylamines
J. Peng, W. Lin, S. Yuan, Y. Chen*
Chengdu Institute of Organic Chemistry and Graduate School of Chinese Academy of Sciences, Beijing, P. R. of China
Further Information
Publication History
Publication Date:
22 May 2007 (online)
Significance
Inspired by the recent work of Dongol and Tay (Tetrahedron Lett. 2006, 47, 927-930) on palladium-catalyzed cascade reactions with N-Boc-protected O-homoallylhydroxylamines and aryl iodides to form N-Boc isoxazolidines, the authors developed a tandem N-arylation-cyclization-C-arylation reaction.