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Synfacts 2008(10): 1051-1051  
DOI: 10.1055/s-2008-1078040
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

TriazaTMM Triplet Diradical

Contributor(s): Timothy M. Swager, Eric L. Dane
H. Quast*, W. Nudling, G. Klemm, A. Kirschfeld, P. Neuhaus, W. Sander, D. A. Hrovat, W. T. Borden
Universität Würzburg and Ruhr-Universität Bochum, Germany; University of North Texas, Denton, USA
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Publication History

Publication Date:
22 September 2008 (online)

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Significance

A triazaTMM triplet diradical is synthesized and characterized by EPR, confirming theoretical calculations from the authors that diradicals of this type would be high-spin. They generated the compound in several cryogenic matrices by photochemically eliminating dinitrogen.