Synthesis of (-)-Clavosolide D

P. T. Seden; J. P. H. Charmant; C. L. Willis

doi:10.1055/s-2008-1078285

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Synfacts 2008(10): 1011-1011
DOI: 10.1055/s-2008-1078285

Synthesis of Natural Products and Potential Drugs

Synthesis of (-)-Clavosolide D

Contributor(s): Philip Kocienski, Indu Dager
P. T. Seden, J. P. H. Charmant, C. L. Willis*
University of Bristol, UK

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Publication History

Publication Date:
22 September 2008 (online)

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Significance

The first total synthesis of (-)-clavosolide D features a stereoselective Prins cyclization and Nicolaou NBS glycosidation protocol to construct both tetrahydrofuran fragments G and H.