DOI: 10.1055/s-00000131

Synfacts

Issue 02 · Volume 8 · February 2012 DOI: 10.1055/s-002-22763

Synform

A10
Zanda, Matteo: SYNFORM ISSUE 2012/02

Synthesis of Natural Products and Potential Drugs

z117
All PDFs of this category
0117
Synthesis of DPC 083
0118
Synthesis of (+)-Daphmanidin E
0119
Total Synthesis and Structural Revision of the Piperarborenines
0120
Synthesis of PF-00610355
0121
Synthesis of a Precursor to LY2140023
0122
Synthesis of Zanamivir Phosphonate Congeners
0123
Synthesis of (3S,5R)-3-Aminomethyl-5-methyloctanoic Acid
0124
Synthesis of Cribrostatin 6
0125
Synthesis of (–)-Neovibsanin G
0126
Synthesis of Imagabalin Hydrochloride
0127
Synthesis of Efavirenz
0128
Synthesis of Epoxykinamycin FL-120B′
0129
Synthesis of (–)-Huperzine-Q
0130
Synthesis of Florfenicol
0131
Total Synthesis of (±)-γ-Lycorane

Synthesis of Heterocycles

z133
All PDFs of this category
0133
(Pyrazolo)pyrimidines/Purines via a Three- Component Reaction
0134
A Tandem Amination–Cycloisomerization Approach to Imidazo[1,2-a]pyridines
0135
Rh-Catalyzed Alkyne Hydroacylation Route to Highly Substituted Furans
0136
Copper-Catalyzed Oxacyclization to Fused Heteroaryl Pyranones
0137
Highly Substituted Pyridines via C–H Rhodation of Unsaturated Ketoximes
0138
Pd-Catalyzed Three-Component Synthesis of Oxazolines and Benzoxazoles
0139
Synthesis of Quinolines from N-Alkyl Anilines and Olefins
0140
Pd-Catalyzed Intramolecular C–H-Activation Approach to Phenanthridines
0141
PhI(OCOCF3)2-Mediated Synthesis of 2-(Trifluoromethyl)oxazoles
0142
Modular Synthesis of Unsymmetrically Polysubstituted and Fused Pyridines
0143
Multicomponent Synthesis of 5-Carboxamide Oxazolines
0144
Copper/Copperless Synthesis of Tetrazoles via C–H and C–C Bond Cleavages
0145
Radical Cyclization Approach to Piperidyl Benzofuran/Benzopyran Spirocycles
0146
A Three-Component Synthesis of Imidazolines
0147
Three-Component Synthesis of Pyrazoles Using Titanium Catalysis

Synthesis of Materials and Unnatural Products

z149
All PDFs of this category
0149
Regioregular CDT-PT Copolymers
0150
Access to Soluble Polyacetylene Derivatives via Cyclopolymerization
0151
Losing it at Both Ends: A Dehydrative Organometallic Polymerization
0152
A Turn-On Fluorescent Probe for Azides
0153
Hermetically Encapsulated Oligothiophenes
0154
Benzo[e]pyrene-Type Dipyryliums
0155
A New Synthesis of 1,2-Benzanthracenes
0156
Efficient Access to Brush-Like Cyclic Polymers
0157
Easily Accessible Electron-Accepting Indenofluorenes
0158
An Improved Route to Thienothiazole
0159
BN-Substituted PAHs
0160
Silole Ring Opening: Mild, Efficient, Selective
0161
An Efficient Route to Tetraazaanthracenes

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z163
All PDFs of this category
0163
Diastereoselective Synthesis of Cyclopentyl-amines from Aminocyclopropanes
0164
New Chiral Phosphoramidite–Alkene Ligands in Intramolecular Hydroacylation
0165
Iron-Catalyzed Rearrangements and Cycloadditions of 2H-Chromenes
0166
Rhodium-Catalyzed Allylation of Aldehydes Using Vinyl Boronates
0167
Pt-Catalyzed Diboration of Cyclic Dienes
0168
Indium-Catalyzed Hosomi–Sakurai Reactions with N,O-Aminals and Boronates
0169
Palladium-Catalyzed Asymmetric Trimethylenemethane Cycloaddition
0170
Iridium-Catalyzed Asymmetric Allylic Amination of ortho-Aminostyrenes
0171
Rhodium-Catalyzed Asymmetric Annulation by C–H Activation of Ketimines
0172
Enantioselective Synthesis of Heterocyclic β-Amino Alcohols
0173
Iridium-Catalyzed Umpoled Donor–Acceptor Cyclopropane-Mediated Carbonyl Allylation
0174
Palladium-Catalyzed Stereoselective Allylic Oxidation of cis-Vinylsilanes
0175
Enantioselective N–H Insertion Reactions into α-Diazoacetates
0176
Mg-Catalyzed Asymmetric Vinylogous Michael Additions
0177
Copper-Catalyzed Annulation of 2-Nitrosopyridine with Allylstannanes
0178
Catalytic Asymmetric Hydroformylation of 1,1-Disubstituted Olefins
0179
Intramolecular Gold-Catalyzed Asymmetric [4+3] Cycloadditions
0180
Synthesis of Tetrahydroisoquinolines via Asymmetric Hydrogenation
0181
Asymmetric Hydrogenation Towards Drug Building Blocks
0182
Lautens, Mark; Liu, Hongqiang: Palladium-Catalyzed Allylic Alkylations via Allylic Amines
0183
Zinc-Catalyzed Enantioselective Michael Addition
0184
Au-Catalyzed Diastereoselective Synthesis of Piperidines
0185
Au(I)-Catalyzed Asymmetric Cyclization–Addition of Akynols and Azlactones
0186
Chiral Allene-Containing Phosphines in Asymmetric Catalysis
0187
Synthesis and Application of 2,6-Bis(tri-fluoromethyl)-4-pyridyl Phosphines
0188
Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazolide
0189
Palladium-Catalyzed 1,4-Addition of Diarylphosphines
0190
Chiral Ferrocenyl-DIPHOH/Cu(OAc)2 Complex for Asymmetric Michael Additions
0191
Ru-Catalyzed Asymmetric Hydrogenation
0192
Catalytic Asymmetric Synthesis of Oxetanes

Metal-Mediated Synthesis

z193
All PDFs of this category
0193
Fe-Catalyzed Cross-Coupling of Alkyl Halides with Alkynyl Grignard Reagents
0194
BF3-Activated Friedel–Crafts Benzylation
0195
Sulfinyl Exchange Alkylations of Nitriles
0196
Ni-Catalyzed Methyl-Carboxylation of Homopropargylic Alcohols
0197
Regioselective ortho-C–H Borylation of Arenes via Iridium Catalysis
0198
Reductive Scission of Heterocyclic Thioethers
0199
Fe-Catalyzed Oxidative Arylation of Primary Amines with Diorganozinc Reagents
0200
Synthesis of Substituted Allenes through γ-Selective and Stereospecific Coupling
0201
Ni-Catalyzed Coupling of Non-Activated Alkyl Halides with Alkynyl Grignards
0202
Cu-Mediated Regioselective Substitution of Cyclic Allylic Picolinates
0203
Homoallylboration and Diastereoselective Homocrotylation of Aldehydes
0204
Direct Arylation/Alkylation of Nitropyridine N-Oxides with Grignard Reagents
0205
Enantioselective Boronate Addition to N-Acyl Quinoliniums
0206
Monofluoroalkenes: Reaction of Organo-lithium Reagents with Difluoropropenes
0207
TiCl4-Promoted Ring Cleavage and Aldol Reaction of Cyclobutanones

Organo- and Biocatalysis

z209
All PDFs of this category
0209
Bis-Phosphoric Acid: Two is Better than One
0210
Aldehyde Catalysis
0211
Kinetic Resolution Catalyzed by Achiral NHC and Chiral Hydroxamic Acid
0212
Organocatalytic Intramolecular [6+2] Cycloaddition
0213
Diastereodivergent Asymmetric Sulfa-Michael Additions of α-Branched Enone
0214
Chiral Thiourea Catalyzed Asymmetric Neber Reaction
0215
Bromoetherification via Asymmetric Counteranion-Directed Catalysis
0216
NHC-Catalyzed Aerobic Oxidation of Aromatic Aldehydes to Aryl Esters
0217
Asymmetric Aldol Reaction between Functionalized Aliphatic Aldehydes
0218
A New Method to Generate the α,β-Unsaturated Acylazolium Intermediate

Polymer-Supported Synthesis

z219
All PDFs of this category
0219
ortho-C–H Borylation of Arenes Using Silica-Supported Rhodium Complexes
0220
Huisgen Cycloaddition with Hydroxyapatite-Supported Cu(II)
0221
Two-Step Flow Synthesis of N-(2-Amino-ethyl)acylamides from Oxazolines
0222
Oxidation of Alcohols with Polymeric Br3– and DMSO
0223
The Suzuki–Miyaura Coupling with Polymer-Coated Pd-SILC
0224
Regioselective Synthesis of Oxazolidinones Using PEG600(PPh3Br)2
0225
Hydrodeoxygenation of Phenols with Pt/C Catalyst
0226
Oxidative Cyclization of Phenolic Imines Using Pt Nanoparticles
0227
Preparation of Isoxazoles and Isoxazolines with PPA/SiO2
0228
Addition of ArB(OH)2 to Aldehydes with Polymer-Supported NHC–Rh
0229
Solid-Phase Synthesis of Trifluoromethyl-arenes
0230
The Heck Reaction with Nanoporous Metallic Glass Pd
0231
The Selective Hydrogenation of Phenols in Water by Using Pd/MIL-101