DOI: 10.1055/s-00000131

Synfacts

Issue 06 · Volume 8 · June 2012 DOI: 10.1055/s-002-23259

Synform

A51
Zanda, Matteo: SYNFORM ISSUE 2012/06

Synthesis of Natural Products and Potential Drugs

z583
All PDFs of this category
0583
Synthesis of a Glycine Transporter 1 Inhibitor
0584
Synthesis of UK-432,097
0585
Synthesis of (–)-Anisatin
0586
Synthesis of Ripostatin B
0587
Synthesis of (±)-Mevashuntin
0588
Synthesis of (S)-Bisoranjidiol
0589
Synthesis of (–)-GB17
0590
Synthesis of Acrivastine
0591
Synthesis of AZD7545
0592
Synthesis of (–)-Dendrobine
0593
Synthesis of (±)-Indoxamycin B
0594
Synthesis of (+)-erythro-Mefloquine Hydrochloride
0595
Synthesis of Serine Hydrolase Inhibitor ABL303

Synthesis of Heterocycles

z597
All PDFs of this category
0597
Isoquinoline-Catalyzed Synthesis of Azirines
0598
Oxadiazoles: Synthesis, Properties and Significance in Medicinal Chemistry
0599
Synthesis of Tetrahydrothiopyrans via Thiocarbenium Ion Cyclization
0600
Cu-Promoted Oxidative Heteroannulation Approach to Benzofurans
0601
Synthesis of 4-Aryl-2-quinolinone by a Tandem Heck/C–H Amidation Approach
0602
Cu-Catalyzed Heteroannulation Route to [1,2,3]Triazolo[1,5-a]quinoxalin-4(5H)-ones
0603
Sonogashira-Mediated Route to Benzo[c]chromen-6-ones
0604
Copper Oxide Catalyzed Synthesis of Benzo[e][1,2,4]triazines
0605
Synthesis of Pyridazino[1,2-a]indazoliums by N–N Bond Forming
0606
Pyrrolobenzoxazoles via Three-Component [3+2] Heterocycloannulation
0607
Rh-Catalyzed De Novo Synthesis of Pyridines from Terminal Alkynes and Ketoximes
0608
Silver-Mediated Dual C–H/C–H Activation for the Synthesis of 3-Acyl Furans
0609
Synthesis of Furans by Au-Catalyzed Cyclization of (E)-1-Aryloxy-1-en-3-ynes
0610
Diverse Heterocycles from a Naphthofuran Hydroxypropenone Sodium Salt Synthon

Synthesis of Materials and Unnatural Products

z611
All PDFs of this category
0611
First Synthesis of Polysulfenamides
0612
Helically Chiral 1,1′-Bitriphenylenes
0613
Boroles are not Boring!
0614
Dithienophospholes as Charge Transfer Materials
0615
Making an Azaanthracene Sandwich? Use Cation–π!
0616
Cyclometalated Platinum(II) β-Diketonates
0617
Controlled Chain-Growth Polymerization
0618
Rapid Access to 2- and 2,7-Substituted Pyrenes
0619
Milder Bradsher Conditions for Blue Light Emitting Anthracenes
0620
Ladder-Type Triarylboranes
0621
An Asymmetric Dithienosilole
0622
Cross-Conjugated Phosphaalkene

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z623
All PDFs of this category
0623
Pd-Catalyzed Asymmetric [3+2] Cycloadditions
0624
Iridium-Catalyzed Direct Allylic Amination of Allylic Alcohols
0625
Iron(III) Porphyrin Catalyzed [4+2] Cycloaddition of Aldehydes and Dienes
0626
Z-Selective Cu-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents
0627
Palladium-Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates
0628
Ir(III)-Catalyzed Carbene Insertion to C–H and Si–H Bonds
0629
Rh-Catalyzed Tandem 1,4-Shift/1,4-Addition Reactions
0630
Copper-Catalyzed Asymmetric Direct Enantioconvergent Allylic Alkylation
0631
Sc-Catalyzed Asymmetric Diazoalkane–Carbonyl Homologation
0632
Asymmetric Synthesis of β-Amino Alcohol via Epoxide Ring Opening
0633
Enantioselective Bismuth-Catalyzed Allylation of Aromatic Aldehydes
0634
Synthesis of Optically Active Unsaturated Lactones
0635
Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines
0636
Asymmetric Ir-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids
0637
Regio- and Enantioselective Ir-Catalyzed Allylic Alkylation
0638
Enantioselective Desymmetrization of meso-Glutaric Anhydrides
0639
Rh(I)-Catalyzed Addition of Arylboroxines to Unactivated Ketones
0640
Rh(I)-Catalyzed One-Pot Synthesis of Chiral 3-Arylisoindolinones
0641
Pd-Catalyzed Regio- and Stereoselective Hydrosilylation of Alkynes
0642
Hf(IV)-Catalyzed Asymmetric Epoxidation and Oxaziridination
0643
Copper-Catalyzed Asymmetric Allylic Boronation
0644
Scandium-Catalyzed Asymmetric Conjugate Addition of Alkynones
0645
Synthesis of Pyrrolidines by Pd-Catalyzed Aerobic Oxidative Cyclization
0646
Zn-Catalyzed Alkynylation of N-(Diphenylphosphinoyl)imines
0647
Rh(I)-Catalyzed Intramolecular Addition of Arylboronic Acids to Ketones
0648
Cu-Catalyzed Enantioselective Coupling of Amines with Aldehydes
0649
Chiral Ag(I) Phosphate Catalyzed Kinetic Resolution of α-Allenic Alcohols
0650
Phosphoric Acid/Au(I) Catalyzed Synthesis of 1,2-Dihydroisoquinolines
0651
Novel Ligand for Rh-Catalyzed Addition of Arylboronic Acids

Metal-Mediated Synthesis

z653
All PDFs of this category
0653
Pd-Catalyzed Double Oxygenation of Arenes with PyrDipSi as Directing Group
0654
Fe(II)-Catalyzed Trifluoromethylation of Vinyltrifluoroborates
0655
Negishi Cross-Coupling Using Aryl Ethers as Coupling Partners
0656
Reformatsky-Type Enantioselective Synthesis of α-Fluoro-β-hydroxy Esters
0657
Copper-Free Allylic Alkylation Using Grignard Reagents
0658
Silicon-Mediated C(sp2)–C(sp2) Cross-Coupling
0659
Directed peri-Metalation of 7-Azaindoles by In Situ Anionic Shielding
0660
Alkynylation of Ar–H Activated by n-BuLi or t-BuLi
0661
Asymmetric Sulfoxide–Magnesium Exchange with i-Pr2Mg and (S)-BINOL
0662
Synthesis of 1,2-Dihydropyridines by Rh-Catalyzed Hydroboration of Pyridines
0663
Difluoromethylation of Aryl and Vinyl Iodides with TMSCF2H Mediated by CuI
0664
Cu-Catalyzed Oxidative Trifluoromethylation of Arylboronic Acids
0665
Chemoselective Reduction of Ketones and Esters in the Presence of Aldehydes
0666
Pd-Catalyzed Hydroxymethylation with Potassium Acetoxymethyltrifluoroborate
0667
Cu-Catalyzed Conversion of Boronates into 11C-Labeled Carboxylic Acids

Organo- and Biocatalysis

z669
All PDFs of this category
0669
Enzymatic Anti-Baldwin Epoxide Ring-Opening Reactions
0670
Stereoselective Aldol Reaction Catalyzed by Ammonium Betaines
0671
Confined Brønsted Acid Catalysis
0672
Cyclopropenimines as Chiral Brønsted Base Catalysts
0673
Achiral Counteranion Effects in an Asymmetric Iodolactonization
0674
Organocatalytic [2+2] Cycloaddition of Enals and Nitroalkenes
0675
Phosphoric Acid Catalyzed Three-Component Povarov Reaction
0676
Chiral Bis(betaine) Catalyzed Mannich Reaction
0677
Organocatalytic Michael Addition and Cyclization

Polymer-Supported Synthesis

z679
All PDFs of this category
0679
Asymmetric Diels–Alder Reactions with a PMHS-Supported Imidazolinone
0680
N-Formylation of Amines with HClO4-SiO2
0681
SBA-15-SO3H-Confined Acidic Ionic Liquid
0682
Biginelli Synthesis of Dihydropyrimidinones with HClO4-SiO2
0683
Arylation of Thiols with Aryl Halides Using CuI Nanoparticles in Water
0684
Pt/C-Catalyzed Monodechlorination of Trichloromethyl Compounds
0685
Solid-Supported Synthesis of Indoles via Gold-Catalyzed Cyclization
0686
Solid-Phase Synthesis of Isoxazoles and Isoxazolines
0687
Light-Mediated C–C and C–P Bond Formation with TiO2 and ZnO
0688
Biginelli Reaction Catalyzed by Bioglycerol-Based Sulfonic Acid
0689
β-Azidation of α,β-Unsaturated Ketones Using PS-DABCOF2
0690
Hydrogenation with Iron–Iron Oxide Core–Shell Nanoparticles
0691
Ullmann Diaryl Etherification with Copper Fluorapatite