DOI: 10.1055/s-00000131

Synfacts

Issue 09 · Volume 8 · September 2012 DOI: 10.1055/s-002-23645

Synform

A85
Zanda, Matteo: SYNFORM ISSUE 2012/09

Synthesis of Natural Products and Potential Drugs

z929
All PDFs of this category
0929
Total Synthesis and Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol
0930
Syntheses of Chelidonine and Norchelidonine
0931
Synthesis of LY541850 and Its C4 Epimer
0932
Synthesis of (–)-Aurafuron A
0933
Synthesis of (–)-Teucvidin
0934
Synthesis of E2508
0935
Synthesis of (–)-Galanthamine
0936
Synthesis of an Aliskiren Intermediate
0937
Synthesis of (–)-Clavulactone
0938
Formal Synthesis of (–)-Huperzine A
0939
Synthesis of (–)-Tetrahydrolipstatin
0940
Synthesis of (–)-Oseltamivir
0941
Synthesis of (–)-Polycavernoside A
0942
Synthesis of a Topisomerase I Inhibitor
0943
Syntheis of Entecavir
0944
Synthesis of Neobenodrine
0945
Synthesis of PDE IVb Inhibitors
0946
Total Synthesis of (±)−Agelastatin A

Synthesis of Heterocycles

z947
All PDFs of this category
0947
Palladium-Catalyzed Synthesis of Quinolines
0948
Synthesis of Benzoxazoles by an Asymmetric Ugi-Type Reaction
0949
Ni-Catalyzed Synthesis of 3-Piperidones from 3-Azetidinones and Alkynes
0950
Regioselective, Modular C–N and Suzuki Coupling Route to Triazoles
0951
Piperidines and Tetrahydroisoquinolines via Hydride Transfer Cyclization
0952
Gold-Catalyzed Cyclizations Leading to Indenoazepines and Strained Bicycles
0953
Metal-Free Aziridine Synthesis from Unfunctionalized Olefins
0954
Iodocyclization Route to Pyrroles and Furans in PEG
0955
Organocatalytic Synthesis of Quinolines and Chiral 1,4-Dihydroquinolines
0956
Synthesis of Isoxazoles from 1,3-Dialkynes and Hydroxylamine
0957
Synthesis of Azetidines by Epoxide Ring-Opening–Ring-Closure Procedure
0958
Cu-Catalyzed Regioselective Synthesis of 1,2,3- or 1,2,4-Triaryltriazoles
0959
Isoindolinols and Dihydroisobenzofuranols via Combined Au–Pd Catalysis
0960
Sonogashira Coupling–Heteroannulation Route to Substituted 5-Azaindoles
0961
3,1-Benzoxazines from N-Acyl-o-Toluidines via Cu-Catalyzed Heteroannulation

Synthesis of Materials and Unnatural Products

z963
All PDFs of this category
0963
Oxygen Tolerant Polymerizations
0964
A Series of Carbon–Sulfur [n]Helicenes
0965
A Stable Hydroxide-Conducting Polymer
0966
Planar Thienyl-Vinylene Monomers Create Stable, Highly Mobile Polymers
0967
Push–Pull Chromophores: Location of a Thiophene Spacer Matters
0968
Shining Light on Polythiophenes
0969
A Gold-Catalyzed Route to Benzo[b]fluorenes
0970
Blocky Copolymers by Carbene Insertion Polymerization
0971
Unsubstituted Polythiophene with Minimal Defects
0972
Extended and Fused Pyrrolo-dC and Pyrrolo-C Analogues
0973
Diacetylenes from the Metathesis of Conjugated Diynes
0974
Convenient Two-Step Preparation of Phenanthrenes
0975
Probing the Polymerizability of 1,3-Dihydroadamantanes

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z977
All PDFs of this category
0977
Asymmetric Dehydrative Amination via Gold(I) Catalysis
0978
Cu-Catalyzed Asymmetric Allylic Alkylation Using Chiral Phosphoramidite Ligands
0979
Cu-Catalyzed Electrophilic Trifluoromethylation of β-Keto Esters
0980
Mg-Catalyzed Enantioselective C–H Bond Functionalization of Isoindolinones
0981
Novel Phosphinite–Oxazole Ligands for Ir-Catalyzed Asymmetric Hydrogenation
0982
Copper-Catalyzed Enantioselective Aldol Reaction of Thiolactams
0983
Sigmatropic Rearrangement of Rhodium-Carbenoids and Allylic Alcohols
0984
Ru-Catalyzed Asymmetric Hydrogenation of 1,5-Benzodiazepines
0985
Rh-Catalyzed Enantioselective Synthesis of Chiral Succinates
0986
Asymmetric Rh-Catalyzed 1,4-Addition of Arylboronic Acids to Chalcones
0987
Pd-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes
0988
Rhodium-Catalyzed Asymmetric Formal Cycloaddition
0989
Asymmetric Methylation of Imines Catalyzed by a Chiral Diene/Rh Complex
0990
Synthesis of Chiral Chloro Boronic Esters via Asymmetric Hydrogenation
0991
Lewis Acid Catalyzed Diastereoselective Decarboxylative Mannich Reaction
0992
Enantioselective Cycloaddition of Propargyl Esters with Enamines
0993
Ca-Catalyzed Carbonyl–Ene and Friedel–Crafts Alkylations
0994
Rh-Catalyzed Aziridination of Allenic Sulfamates
0995
Platinum-Catalyzed 1,2-Borylation of 1,3-Dienes
0996
Palladium-Catalyzed Intramolecular [2+2] Cycloaddition
0997
Palladium-Catalyzed Oxyarylation of Hydroxyalkenes
0998
Scandium-Catalyzed Asymmetric Sulfenylation of Oxindoles
0999
Cu-Catalyzed Cascade Process for Pyrroloindoline Synthesis
1000
Cu-Catalyzed Asymmetric Desymmetrization of Cyclopentene-1,3-diones
1001
Bifunctional Ru Amido Catalyzed Conjugate Addition to Cyclic Enones
1002
Chlorination of β-Keto Esters and Subsequent SN2 Displacement
1003
Novel Hybrid Ligand for Asymmetric Henry Reaction
1004
Rhodium-Catalyzed Enantioselective Intramolecular Addition onto Ketones
1005
Synthesis of Homoallylic Esters and Lactones via Oxonia-Cope Reaction
1006
Pd-Catalyzed Chlorination of Cyclic β-Keto Esters

Metal-Mediated Synthesis

z1007
All PDFs of this category
1007
Ni-Catalyzed Monofunctionalization of Polyfluoroarenes with Organozincs
1008
Direct Alkenylation of Nonaromatic Enamides
1009
Cu-Mediated Fluorination of Aryl Iodides
1010
Au-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols via Au/Sn Transmetalation
1011
Synthesis of 1,4-Oxazines and 1,4-Oxazepines via exo-dig Cyclization
1012
Decarboxylative Etherification of Aromatic Carboxylic Acids
1013
NHC-Cu-Catalyzed Enantioselective Synthesis of Homoprogargyl Amines
1014
Cu-Catalyzed Enantioselective Allylic Substitution with Vinylboron Reagents
1015
Ru-Catalyzed C–H Bond Functionalization: Synthesis of Fluorescent Pyrans
1016
Synthesis of 9,10-Phenanthrene Quinones by Oxidative C–C Coupling
1017
Chelation-Controlled Synthesis of (E)-Di- and Trisubstituted Allylic Alcohols
1018
Ni-Catalyzed Alkylation of Aziridines with Organozinc Reagents
1019
Regioselectivity in Allylzincation of Imines
1020
CuAAC/Ullmann C–C Coupling Tandem Reaction: Synthesis of 1,2,3-Triazoles

Organo- and Biocatalysis

z1021
All PDFs of this category
1021
A Newly Designed Catalyst for Bromolactonization
1022
N-Sulfinyl Urea as Bifunctional Catalyst: Hydrosilylation of β-Amino Nitroolefins
1023
Reversal of Enantioselection between Phosphoric Acid and Ca Salt Catalysis
1024
NHC-Catalyzed Dynamic Kinetic Resolutions
1025
Quadruple Domino Organocatalysis
1026
Enantioselective Bromolactonization of 1,1-Disubstituted Olefinic Acids
1027
Enantioselective Protonation with an Organocatalyst Chiral Only at Sulfur
1028
Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut–Currier Reaction
1029
Enantioselective Mannich Reactions with Aliphatic and Aromatic Imines
1030
Highly Enantioselective Sulfoxidation with H2O2 in a Deep Chiral Pocket
1031
Kinetic Resolution of Alcohols by Chiral Brønsted Acid Catalyzed Acylation
1032
Asymmetric Decarboxylative Addition to Ketimines

Polymer-Supported Synthesis

z1033
All PDFs of this category
1033
A Highly Active Heterogeneous Polymeric Cu Catalyst for Click Chemistry
1034
Uozumi, Yasuhiro; Sakurai, Fumie: Ring Opening of N-Tosylaziridines Using PS-TBD
1035
Hydration of Nitriles Using Amorphous MnO2
1036
Azide–Alkyne Cycloaddition of Cyclic Sulfates and Cyclic Sulfamidates
1037
Cycloaddition of Solid-Supported (Cyclobutadiene)Fe(CO)3 with Alkenes
1038
Heck Reaction with PdNP@Polymeric Mesoporous Carbon Nanocage
1039
Hydrogenolysis of Allylic Carbonates to Terminal Alkenes with Au/HT
1040
Oxygenation of Primary Amines to Amides with Amorphous MnO2
1041
Semihydrogenation of Alkynes to Alkenes with Palladium on Boron Nitride
1042
Silica-HClO4 Catalyst for One-Pot Preparation of Flavans
1043
Oxidation of Styrenes to Aldehydes with Fe2O3NP/SBA-15 in Water
1044
Asymmetric Michael Addition Using Resin-Supported Peptide
1045
Condensation of Amines and 1,3-Dicarbonyls with ZnO NPs
1046
Silica-Supported Pd–NHC Catalysts