Synfacts

Ausgabe 09 · September 2012

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Ausgabe
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A85
SYNFORM ISSUE 2012/09 FREIER ZUGRIFF

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Synthesis of Natural Products and Potential Drugs
z929
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0929
Total Synthesis and Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol

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0930
Syntheses of Chelidonine and Norchelidonine

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0931
Synthesis of LY541850 and Its C4 Epimer

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0932
Synthesis of (–)-Aurafuron A

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0933
Synthesis of (–)-Teucvidin

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0934
Synthesis of E2508

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0935
Synthesis of (–)-Galanthamine

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0936
Synthesis of an Aliskiren Intermediate

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0937
Synthesis of (–)-Clavulactone

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0938
Formal Synthesis of (–)-Huperzine A

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0939
Synthesis of (–)-Tetrahydrolipstatin

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0940
Synthesis of (–)-Oseltamivir

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0941
Synthesis of (–)-Polycavernoside A

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0942
Synthesis of a Topisomerase I Inhibitor

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0943
Syntheis of Entecavir

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0944
Synthesis of Neobenodrine

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0945
Synthesis of PDE IVb Inhibitors

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0946
Total Synthesis of (±)−Agelastatin A

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Synthesis of Heterocycles
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0947
Palladium-Catalyzed Synthesis of Quinolines

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0948
Synthesis of Benzoxazoles by an Asymmetric Ugi-Type Reaction

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0949
Ni-Catalyzed Synthesis of 3-Piperidones from 3-Azetidinones and Alkynes

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0950
Regioselective, Modular C–N and Suzuki Coupling Route to Triazoles

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0951
Piperidines and Tetrahydroisoquinolines via Hydride Transfer Cyclization

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0952
Gold-Catalyzed Cyclizations Leading to Indenoazepines and Strained Bicycles

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0953
Metal-Free Aziridine Synthesis from Unfunctionalized Olefins

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0954
Iodocyclization Route to Pyrroles and Furans in PEG

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0955
Organocatalytic Synthesis of Quinolines and Chiral 1,4-Dihydroquinolines

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0956
Synthesis of Isoxazoles from 1,3-Dialkynes and Hydroxylamine

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0957
Synthesis of Azetidines by Epoxide Ring-Opening–Ring-Closure Procedure

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0958
Cu-Catalyzed Regioselective Synthesis of 1,2,3- or 1,2,4-Triaryltriazoles

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0959
Isoindolinols and Dihydroisobenzofuranols via Combined Au–Pd Catalysis

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0960
Sonogashira Coupling–Heteroannulation Route to Substituted 5-Azaindoles

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0961
3,1-Benzoxazines from N-Acyl-o-Toluidines via Cu-Catalyzed Heteroannulation

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Synthesis of Materials and Unnatural Products
z963
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0963
Oxygen Tolerant Polymerizations

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0964
A Series of Carbon–Sulfur [n]Helicenes

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0965
A Stable Hydroxide-Conducting Polymer

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0966
Planar Thienyl-Vinylene Monomers Create Stable, Highly Mobile Polymers

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0967
Push–Pull Chromophores: Location of a Thiophene Spacer Matters

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0968
Shining Light on Polythiophenes

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0969
A Gold-Catalyzed Route to Benzo[b]fluorenes

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0970
Blocky Copolymers by Carbene Insertion Polymerization

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0971
Unsubstituted Polythiophene with Minimal Defects

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0972
Extended and Fused Pyrrolo-dC and Pyrrolo-C Analogues

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0973
Diacetylenes from the Metathesis of Conjugated Diynes

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0974
Convenient Two-Step Preparation of Phenanthrenes

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0975
Probing the Polymerizability of 1,3-Dihydroadamantanes

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z977
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0977
Asymmetric Dehydrative Amination via Gold(I) Catalysis

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0978
Cu-Catalyzed Asymmetric Allylic Alkylation Using Chiral Phosphoramidite Ligands

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0979
Cu-Catalyzed Electrophilic Trifluoromethylation of β-Keto Esters

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0980
Mg-Catalyzed Enantioselective C–H Bond Functionalization of Isoindolinones

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0981
Novel Phosphinite–Oxazole Ligands for Ir-Catalyzed Asymmetric Hydrogenation

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0982
Copper-Catalyzed Enantioselective Aldol Reaction of Thiolactams

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0983
Sigmatropic Rearrangement of Rhodium-Carbenoids and Allylic Alcohols

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0984
Ru-Catalyzed Asymmetric Hydrogenation of 1,5-Benzodiazepines

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0985
Rh-Catalyzed Enantioselective Synthesis of Chiral Succinates

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0986
Asymmetric Rh-Catalyzed 1,4-Addition of Arylboronic Acids to Chalcones

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0987
Pd-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes

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0988
Rhodium-Catalyzed Asymmetric Formal Cycloaddition

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0989
Asymmetric Methylation of Imines Catalyzed by a Chiral Diene/Rh Complex

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0990
Synthesis of Chiral Chloro Boronic Esters via Asymmetric Hydrogenation

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0991
Lewis Acid Catalyzed Diastereoselective Decarboxylative Mannich Reaction

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0992
Enantioselective Cycloaddition of Propargyl Esters with Enamines

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0993
Ca-Catalyzed Carbonyl–Ene and Friedel–Crafts Alkylations

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0994
Rh-Catalyzed Aziridination of Allenic Sulfamates

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0995
Platinum-Catalyzed 1,2-Borylation of 1,3-Dienes

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0996
Palladium-Catalyzed Intramolecular [2+2] Cycloaddition

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0997
Palladium-Catalyzed Oxyarylation of Hydroxyalkenes

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0998
Scandium-Catalyzed Asymmetric Sulfenylation of Oxindoles

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0999
Cu-Catalyzed Cascade Process for Pyrroloindoline Synthesis

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1000
Cu-Catalyzed Asymmetric Desymmetrization of Cyclopentene-1,3-diones

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1001
Bifunctional Ru Amido Catalyzed Conjugate Addition to Cyclic Enones

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1002
Chlorination of β-Keto Esters and Subsequent S_N2 Displacement

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1003
Novel Hybrid Ligand for Asymmetric Henry Reaction

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1004
Rhodium-Catalyzed Enantioselective Intramolecular Addition onto Ketones

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1005
Synthesis of Homoallylic Esters and Lactones via Oxonia-Cope Reaction

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1006
Pd-Catalyzed Chlorination of Cyclic β-Keto Esters

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Metal-Mediated Synthesis
z1007
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1007
Ni-Catalyzed Monofunctionalization of Polyfluoroarenes with Organozincs

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1008
Direct Alkenylation of Nonaromatic Enamides

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1009
Cu-Mediated Fluorination of Aryl Iodides

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1010
Au-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols via Au/Sn Transmetalation

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1011
Synthesis of 1,4-Oxazines and 1,4-Oxazepines via exo-dig Cyclization

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1012
Decarboxylative Etherification of Aromatic Carboxylic Acids

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1013
NHC-Cu-Catalyzed Enantioselective Synthesis of Homoprogargyl Amines

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1014
Cu-Catalyzed Enantioselective Allylic Substitution with Vinylboron Reagents

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1015
Ru-Catalyzed C–H Bond Functionalization: Synthesis of Fluorescent Pyrans

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1016
Synthesis of 9,10-Phenanthrene Quinones by Oxidative C–C Coupling

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1017
Chelation-Controlled Synthesis of (E)-Di- and Trisubstituted Allylic Alcohols

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1018
Ni-Catalyzed Alkylation of Aziridines with Organozinc Reagents

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1019
Regioselectivity in Allylzincation of Imines

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1020
CuAAC/Ullmann C–C Coupling Tandem Reaction: Synthesis of 1,2,3-Triazoles

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Organo- and Biocatalysis
z1021
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1021
A Newly Designed Catalyst for Bromolactonization

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1022
N-Sulfinyl Urea as Bifunctional Catalyst: Hydrosilylation of β-Amino Nitroolefins

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1023
Reversal of Enantioselection between Phosphoric Acid and Ca Salt Catalysis

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1024
NHC-Catalyzed Dynamic Kinetic Resolutions

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1025
Quadruple Domino Organocatalysis

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1026
Enantioselective Bromolactonization of 1,1-Disubstituted Olefinic Acids

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1027
Enantioselective Protonation with an Organocatalyst Chiral Only at Sulfur

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1028
Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut–Currier Reaction

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1029
Enantioselective Mannich Reactions with Aliphatic and Aromatic Imines

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1030
Highly Enantioselective Sulfoxidation with H₂O₂ in a Deep Chiral Pocket

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1031
Kinetic Resolution of Alcohols by Chiral Brønsted Acid Catalyzed Acylation

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1032
Asymmetric Decarboxylative Addition to Ketimines

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Polymer-Supported Synthesis
z1033
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1033
A Highly Active Heterogeneous Polymeric Cu Catalyst for Click Chemistry

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1034
Ring Opening of N-Tosylaziridines Using PS-TBD

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1035
Hydration of Nitriles Using Amorphous MnO₂

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1036
Azide–Alkyne Cycloaddition of Cyclic Sulfates and Cyclic Sulfamidates

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1037
Cycloaddition of Solid-Supported (Cyclobutadiene)Fe(CO)₃ with Alkenes

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1038
Heck Reaction with PdNP@Polymeric Mesoporous Carbon Nanocage

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1039
Hydrogenolysis of Allylic Carbonates to Terminal Alkenes with Au/HT

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1040
Oxygenation of Primary Amines to Amides with Amorphous MnO₂

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1041
Semihydrogenation of Alkynes to Alkenes with Palladium on Boron Nitride

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1042
Silica-HClO₄Catalyst for One-Pot Preparation of Flavans

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1043
Oxidation of Styrenes to Aldehydes with Fe₂O₃NP/SBA-15 in Water

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1044
Asymmetric Michael Addition Using Resin-Supported Peptide

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1045
Condensation of Amines and 1,3-Dicarbonyls with ZnO NPs

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1046
Silica-Supported Pd–NHC Catalysts

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