DOI: 10.1055/s-00000131

Synfacts

Issue 10 · Volume 8 · October 2012 DOI: 10.1055/s-002-23799

Editorial

I
Editorial

Synform

A96
Zanda, Matteo: SYNFORM ISSUE 2012/10

Synthesis of Natural Products and Potential Drugs

z1047
All PDFs of this category
1047
Total Synthesis of Neurymenolide A
1048
Synthesis of rac-Naproxen
1049
Synthesis of Suvorexant
1050
Synthesis of DPA-714
1051
Synthesis of (R)-(–)-Sumanirole
1052
Synthesis of MK-0893
1053
Total Synthesis of (+)-Gambieric Acid A
1054
Total Synthesis of (–)-Isoschizogamine
1055
Synthesis of (–)-Vincorine
1056
Synthesis of Benzo[g]indazole CK2 Inhibitors
1057
Synthesis of Omecamtiv Mecarbil
1058
Synthesis of a Histone Deacetylase Inhibitor
1059
Synthesis of Olopatadine
1060
Total Synthesis of (±)-Paracaseolide A
1061
Total Synthesis of Proposed Pipercyclo-butanamide A and Piperchabamide G
1062
Synthesis of (+)-Davidiin
1063
Synthesis of a JAK1 Inhibitor

Synthesis of Heterocycles

z1065
All PDFs of this category
1065
Gold-Catalyzed Intramolecular Annulation Route to 2,3-Dihydro-1H-pyrrolizines
1066
Au(I)-Catalyzed Synthesis of Indole- and Arene-Fused Hexahydroquinolizinones
1067
Synthesis of Benzoxazepines from Epoxides and Anthranilic Acids
1068
A Palladium-Catalyzed Enantioselective Hydroamination Route to Pyrrolidines
1069
Copper-Catalyzed Oxytrifluoromethylation of Alkenes to Oxygenated Heterocycles
1070
Cu-Catalyzed Carboetherification Approach to Polycyclic Tetrahydrofurans
1071
An Aryne Condensation–P-Cyclization Sequence to Dibenzophosphole-Boranes
1072
Synthesis of Aminopyrimidinethiones from α-Azidovinyl Ketones and Thiourea
1073
Pd-Catalyzed Synthesis of Indolines via Intramolecular Aryl C–H Amination
1074
Cu-Catalyzed Synthesis of Cinnolines from N-Methyl-N-phenylhydrazones
1075
Synthesis of Fluorinated (4-Aminoquinolinyl)phosphonates
1076
syn-1,2-Diamines and Arylpiperazines via [3,3]-Diaza-Cope Rearrangement
1077
Pd-Catalyzed Heteroannulation Route to Phthalazinones
1078
Iodine-Catalyzed Three-Component Reaction to 4-Arylfuro[2,3-a][4,7]phenanthrolines
1079
A C–H Activation Route to Indoloquinolines and Pyrroloquinoxalines

Synthesis of Materials and Unnatural Products

z1081
All PDFs of this category
1081
Neodymium Does Double Duty
1082
Bottom-up Synthesis of Zigzag Carbon Nanotube Belt Precursors
1083
Use of Acetylene Gas as Dienophile in a Diels–Alder Reaction
1084
Mechanophore Allowing Real-Time Monitoring of Polymer Chain Scission
1085
A Stable, Non-Cytotoxic NIR BODIPY Dye for Cell Labeling
1086
Controlled Oxidation of Poly(alkylene H-phosphonate)s
1087
α-End-Functionalized Polymers via Isocyanate RAFT/Click Chemistry
1088
Synthesis of Z-Shape Functionalized Perylenes
1089
Beyond Prodan: Cyclopenta[b]naphthalene Fluorophores
1090
Scholl Reaction Yields a Cycloheptatriene
1091
A Milder Route to Unsymmetric Azobenzenes
1092
High-Spin, Macrocyclic Double- and Triple-Decker Aryl Amines

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1093
All PDFs of this category
1093
Ru-Catalyzed Asymmetric Olefin Aziridination
1094
Asymmetric Tandem Hydroformylation–α-Alkylation
1095
Palladium-Catalyzed Vinyl-Substituted Trimethylenemethane Cycloaddition
1096
Direct Asymmetric Alkynylation of Acetaldehyde
1097
Cyclic Carbonate Synthesis Using Silver Catalysis
1098
Iridium-Catalyzed Intermolecular Hydroamination of Unactivated Alkenes
1099
Diastereodivergent Catalytic Asymmetric Allylic Alkylation
1100
Enantioselective Rh-Catalyzed Synthesis of α-Chloromethylene-γ-Butyrolactams
1101
From Central to Axial Chirality: One-Pot Synthesis of Substituted Allenes
1102
Gold(I)-Catalyzed Enantioselective Cyclopropenation
1103
A Powerful Hydrometalation–Asymmetric Conjugate Addition
1104
Z-Selective Metathesis Homocoupling of 1,3-Dienes
1105
Consecutive Intermolecular Reductive Hydroamination
1106
An Asymmetric Mannich-Type Route to Spirooxindoles
1107
Chemoselectivity at a Glance: Lewis versus Brønsted Acid Catalysis
1108
Gold-Catalyzed Diastereo- and Enantioselective [2+2+3] Cycloadditions
1109
Enantioselective Iridium-Catalyzed Carbonyl Propargylation
1110
Iridium-Catalyzed C–C Bond-Forming Transfer Hydrogenation
1111
Enantio- and Regioselective Ru-Catalyzed Epoxidation of Olefins
1112
Copper-Catalyzed Asymmetric 1,4-Addition of Alkylboranes
1113
Fe-Catalyzed Oxyamination of Alkenes with N-Sulfonyl Oxaziridines
1114
New P–N Ligands for Pd-Catalyzed Allylic Alkylation
1115
Three in a Row: Construction of Three Adjacent Quaternary Stereocenters
1116
Pd-Catalyzed Asymmetric Mizoroki–Heck Reaction
1117
Zinc-Catalyzed Nitro-Michael Addition of 5H-Oxazol-4-ones
1118
Copper/Quinine-Catalyzed Oxidative Olefination of Amines
1119
Diastereoselective Synthesis of 1,2-Diamines by Palladium Catalysis
1120
Synthesis of Tetrahydroisoquinolines via Asymmetric Hydrogenation
1121
β-Proline Derivatives through Tandem Chain Extension–Mannich Reaction
1122
Rh(I)-Catalyzed Synthesis of Cyclic Enones

Metal-Mediated Synthesis

z1123
All PDFs of this category
1123
Synthesis of α-Aminoboronic Acids via Boroalkyl Group Migration
1124
FeCl2-Mediated Reductive Cyclization of Unsaturated Organic Halides
1125
Cu-Catalyzed Coupling of Secondary Alkyl Electrophiles and Alkyl Grignards
1126
Titanocene(II)-Promoted Stereospecific Reaction of Allyl Sulfides with Ketones
1127
Lewis Acid Promoted Substitutions to Yield Quaternary Benzylic Compounds
1128
Ni-Catalyzed Coupling of Alkyl Halides with Acid Anhydrides
1129
Ni-Catalyzed Reductive Coupling of Alkyl Halides with Aryl Acid Chlorides
1130
C(sp2)–C(sp3) Bond Formation via Nickel-Catalyzed Reductive Coupling
1131
Pd-Catalyzed Oxidative Diarylation–Carbocyclization of Enynes
1132
Ir- and Ru-Catalyzed Benzylic Silylation and Fluoride-Mediated Carboxylation
1133
Rh-Catalyzed Alkenylation of Benzoxathiazine 2,2-Dioxides
1134
Pd-Catalyzed Hiyama Couplings of α-Silylenoates and α-Silylenamides
1135
Reductive Cross-Coupling of Alkenylboronic Acids and Tosylhydrazones
1136
Cross-Couplings of Arylboronic Acids with Chlorotrifluoroethylene
1137
Synthesis of N-Aminosulfonamides via a Three-Component Coupling
1138
Asymmetric Silaborative C–C Cleavage of meso-Methylenecyclopropanes

Organo- and Biocatalysis

z1139
All PDFs of this category
1139
Catalytic Desymmetrization of Glycerol
1140
Organo-SOMO Catalysis: A New Approach towards Complex Pyrrolidines
1141
Brønsted Acid Catalyzed Asymmetric Synthesis of 1,2,4-Trioxanes
1142
Allyl–Allyl Cross-Coupling Reactions Catalyzed by Triflimide
1143
Designed Reagents for Reversed Polarity Phase-Transfer Catalysis
1144
Enantioselective Synthesis of Spiroethers by Organocatalytic C(sp3)–H Activation
1145
α-Selective Organocatalytic Synthesis of 2-Deoxygalactosides
1146
Hetero-Diels–Alder Reaction Catalyzed by a Highly Fluorinated Disulfonimide
1147
Formal Diaza-Ene Reactions of Hydrazones and α,β-Unsaturated Aldehydes
1148
Formal Carbonyl-Ene Reactions Catalyzed Through Dual Activation by Bis-Ureas

Polymer-Supported Synthesis

z1149
All PDFs of this category
1149
Porous Metalloporphyrinic Frameworks for Oxidation of Alkylbenzenes
1150
Oxidative Imination of Toluene Derivatives Using Pd–Au/SiO2
1151
Cross-Alkylation of Primary Alcohols with IrO2/Fe3O4
1152
Pd/C-Catalyzed Oxidative Aminocarbonylation of Terminal Alkynes
1153
Aerobic Oxidation of Alcohols Using Pd@IFMC in Water
1154
A Core–Shell Structured Chiral Rh Catalyst
1155
Henry Reaction Using Cu-Carboxylate MOF Encapsulated Magnetic Beads
1156
Hantzsch Reaction with γ-Fe2O3 Nanoparticles Supported Sulfonic Acid
1157
Hantzsch Dihydropyridine Synthesis with MgO Nanotubes
1158
Conjugated Additions with a Mesoporous Proline Organocatalyst
1159
Cyclative Cleavage of a Piperazine Amide Linker
1160
Transesterification over Basic Al2O3 under Ball-Milling Conditions
1161
Preparation of N-tert-Butylamides from Nitriles with SO42–/Ce0.07Zr0.93O2
1162
Resin-Supported Synthesis of γ-AApeptides