DOI: 10.1055/s-00000131

Synfacts

Issue 05 · Volume 9 · May 2013 DOI: 10.1055/s-003-24865

Synform

A52
Zanda, Matteo: SYNFORM ISSUE 2013/05

Synthesis of Natural Products and Potential Drugs

z461
All PDFs of this category
0461
Total Synthesis of (±)-Goniomitine
0462
Synthesis of (–)-Huperzine A
0463
Commercial Manufacture of Halaven®
0464
Synthesis of a Dual NK-1/Serotonin Receptor Antagonist
0465
Total Syntheses of Xanthofulvin and Vinaxanthone
0466
Synthesis of Pumilaside Aglycon
0467
Synthesis of (−)-Trichodermatide A
0468
Synthesis of an MDM2 Antagonist
0469
Synthesis of (–)-Galanthamine
0470
Synthesis of Clinprost
0471
Total Synthesis of Cladoniamide G
0472
Total Synthesis of Teurilene
0473
Synthesis of LY2784544
0474
Total Synthesis of (–)-Acutumine and (–)-Dechloroacutumine

Synthesis of Heterocycles

z475
All PDFs of this category
0475
Palladium-Catalyzed Synthesis of 3-Alkynylindoles
0476
Synthesis of Tetrahydroquinazolinediones and Dihydropyrido[2,3-d]pyrimidines
0477
Copper-Catalyzed Synthesis of Furans via (2-Furyl)Carbene Complexes
0478
Interconversion of Benzodiazepinediones into Oxazoloquinolinones
0479
Gold(I)-Catalyzed Synthesis of Pyrrolo[1,2-a]indoles
0480
FeBr3-Catalyzed C–H Activation Route to Indazoles and Pyrazoles
0481
Phenanthridine Derivatives from Intramolecular Diels–Alder Reaction
0482
Rhodium-Catalyzed Synthesis of Phthalides from Benzoic Acids
0483
De Novo Synthesis of 2-Pyridones
0484
Two-Step Synthesis of 2H-Indazoles via C–H Activation of Azobenzenes
0485
One-Pot Synthesis of Benzo[4,5]imidazo[2,1-a]isoquinolines
0486
Zinc Triflate Catalyzed Double Michael Addition Route to Enantioenriched Chromans
0487
Synthesis of Pyrroles and 2H-Pyrrolo[3,4-c]quinolines
0488
Synthesis of 2-Aryl-2H-indazoles Using Silver Catalysis
0489
A Cloke–Wilson Rearrangement Approach to Fused Bromofurans

Synthesis of Materials and Unnatural Products

z491
All PDFs of this category
0491
Functional Phthalaldehyde–Benzaldehyde Copolymers
0492
A Route to Highly Substituted Phenanthrenes and Naphthalenes
0493
Bottom-up Synthesis of Nickel Bis(dithiolene) Complex Nanosheet
0494
Cross-Coupling at C–S Bonds
0495
Cross-Coupling at C–S Bonds
0496
Migration Insertion Polymerization: A Route to Metal-Containing Polymers
0497
[2+2+2] Reaction Leads the Way to a C70 Buckybowl
0498
Synthesis of a Bolaamphiphilic Sexithiophene
0499
Synthesis of [5]- and [7]Phenacenes
0500
Negative Photochromism of 1,1′-Binaphthyl-Bridged Imidazole Dimer
0501
Naphthalene Derivatives by an Iron-Catalyzed Benzannulation
0502
A Macroinimer Approach Affords Hyperbranched Block and Brush Copolymers

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z503
All PDFs of this category
0503
Synthesis of Aminoindanes via a Novel C−H Activation–[3+2]-Annulation Strategy
0504
Copper-Catalyzed Asymmetric Alkynylation of Ketoimines
0505
Copper-Catalyzed Asymmetric Synthesis of Piperidines by a [6+3] Cycloaddition
0506
Synthesis of α-Chiral Succinimides by Iridium-Catalyzed Hydrogenation
0507
Stereospecific Synthesis of β-Amido-α-diazoesters
0508
Palladium-Catalyzed Asymmetric Cycloaddition of Trimethylenemethanes
0509
Asymmetric Allylic Alkylation for the Synthesis of 3,3-Disubstituted Oxindoles
0510
Rhodium-Catalyzed Enantioselective Hydrogenation of Oxime Acetates
0511
Enantioselective Synthesis of cis- and trans-Thiazolidines
0512
Iridium-Catalyzed Enantio- and Diastereoselective Allylation of Azlactones
0513
Iridium-Catalyzed Enantioselective Heterohydroarylation of Bicycloalkenes
0514
Palladium-Catalyzed Allylic Alkylations of 3-Substituted Indoles
0515
Enantioselective Synthesis of 1,5-Dienes via Copper-Catalyzed Allyl–Allyl Coupling
0516
Chiral Bidentate Phosphite Ligands in Rhodium-Catalyzed Hydrogenation
0517
Asymmetric Catalytic Addition of Allylic Cyanides to Aldehydes
0518
Copper-Catalyzed Asymmetric Synthesis of Mixed 3,3′-Bisindoles
0519
Mechanistic Insights – A Chiral Organocatalyst Meets an Achiral Iridium Catalyst
0520
Palladium-Catalyzed Diamination of Alkyl Dienes
0521
Nitrogen-Containing Heterocycle Synthesis Initiated by Rh(III)-Catalyzed C−H Activation
0522
Copper-Catalyzed Enantioselective Intramolecular O–H Bond Insertion
0523
Iridium-Catalyzed Enantioselective Decarboxylative Allylic Etherification
0524
Ruthenium-Catalyzed [3+2] Cycloaddition via Allenylidene Intermediates
0525
Ruthenium-Catalyzed Cyclopropanation of Vinylcarbamates
0526
Copper-Catalyzed Enantioselective Fluorination of Keto Esters
0527
Au(I)–Chiral Phosphoric Acid Catalyzed Multi-Component Spiroketal Synthesis
0528
Copper-Catalyzed Asymmetric Conjugate Addition to Enones
0529
Copper-Catalyzed Reactions of α-Alkylidene β-Keto Imides
0530
Iridium-Catalyzed Asymmetric Hydrogenation of Isoquinolinium Salts
0531
2-Enoylpyridine N-Oxides in Asymmetric Mukaiyama–Michael Additions
0532
Rhodium-Catalyzed Enantioselective C–H Insertion of Sulfonyldiazoacetates

Metal-Mediated Synthesis

z533
All PDFs of this category
0533
Heterocycle Synthesis by a One-Pot Oxidative C(sp3)–N Coupling Reaction
0534
Deprotonation and Alkylation of 2-Boryl Allylic Sulfones
0535
Catalytic Semireduction of Alkynes to Alkenes
0536
Rhodium-Catalyzed Synthesis of Chiral Oxazolidinones
0537
Copper-Mediated Oxidative Coupling of 1,3,4-Oxadiazoles with Polyfluoroarenes
0538
Titanium–Magnesium-Mediated Enantioselective Alkylation of Aldehydes
0539
Formation of Carbazoles by the Reaction of Arynes with Nitrosoarenes
0540
Triethylborane–Oxygen-Mediated Hydrostannylation of Propargylic Alcohols
0541
Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes
0542
Nickel-Catalyzed (sp3)–(sp3) Cross-Coupling to Yield Fatty Acids
0543
Aryl Ether Synthesis via Directed C–H-Activating Alkoxylation with Decarboxylation
0544
Silver-Mediated Trifluoromethylation–Iodination of Arynes
0545
Reactions of Difluorocarbene with Benzyl- and Alkylzinc Reagents
0546
Copper-Promoted Decarboxylative Direct C3-Acylation of N-Substituted Indoles
0547
Copper-Catalyzed Trifluoromethylation of Aryl- and Vinylboronic Acids

Organo- and Biocatalysis

z549
All PDFs of this category
0549
Organocatalytic C–H Bond Arylation of Aldehydes to Bis-heteroaryl Ketones
0550
Highly Enantioselective Kita Oxidative Spirolactonization
0551
Kinetic Resolution via Brønsted Acid Catalyzed Lactonization
0552
Phase-Transfer-Catalyzed Asymmetric Synthesis of Tetrasubstituted Allenes
0553
Phase-Transfer-Catalyzed Asymmetric Cyanation of Alkylidenemalonates
0554
Pyridines via Synergistic Copper–Iminium Catalysis
0555
Enantioselective Allylation of Imides with Allylboronic Acid Pinacol Esters
0556
Lewis Base Catalyzed Double Aldol Reaction
0557
Organocatalytic SN2 Transetherification
0558
Asymmetric Organocatalytic Synthesis of Tetrasubstituted Chiral Biaryl Compounds
0559
A By-Product as a Lewis Base Catalyst for Conjugated Reductions

Polymer-Supported Synthesis

z561
All PDFs of this category
0561
Reduction of N-Heterocycles with a Raney-Nickel-Type Catalyst
0562
One-Pot Epoxidation of Alkenes over CuO/Al2O3 Using Cumene and Oxygen
0563
Hydrogenation of Alkenes Using Copper Nanoparticles Supported on Diamond
0564
Synthesis of Benzimidazoles Using Silica-Supported CuO Nanoparticles
0565
Cross-Coupling of Acyl Chlorides with Triarylbismuths Using MCM-41-2N-Pd(OAc)2
0566
Synthesis of 2-Oxo-2,5-Dihydropyrroles with TiO2 Nanopowder
0567
Oxirane Ring Opening with NaCN Using SiO2-PEG-ImBr
0568
A MNP-Supported Thiourea Catalyst for Asymmetric Diels–Alder Reactions
0569
Asymmetric Alkylation of N-Phosphinylimines Using Supported l-Prolinol
0570
Pd@Al2O3-Cellulose for Suzuki–Miyaura Cross-Couplings
0571
Stereospecific Allylic Substitution by in situ Generated Palladium Nanoparticles
0572
Passerini Reaction with Fe3O4 Nanoparticles Supported TEMPO
0573
Nano CuO-Catalyzed Ullmann-Type Coupling at Ambient Temperature
0574
Solid-Phase Synthesis of (S)-(+)-Clopidogrel

Erratum

0575
Radkowski, K.; Sundararaju, B.; Fürstner, A.: Ru-Catalyzed trans Hydrogenation of Alkynes
0575
Masutomi, K.; Sakiyama, N.; Noguchi, K.; Tanaka, K.: Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition
0575
Kong, Y.; Jiang, K.; Cao, J.; Fu, L.; Yu, L.; Lai, G.; Cui, Y.; Hu, Z.; Wang, G.: Carbocation-Induced Electrophilic Cyclization of Ynamides