DOI: 10.1055/s-00000131

Synfacts

Issue 06 · Volume 9 · June 2013 DOI: 10.1055/s-003-25025

Synform

A66
Zanda, Matteo: SYNFORM ISSUE 2013/06

Synthesis of Natural Products and Potential Drugs

z577
All PDFs of this category
0577
Synthesis of an Adenosine A2A Receptor Antagonist
0578
Synthesis of 1,1-Diphenylpropyl-1-amines via Hydroaminomethylation
0579
Synthesis of Tatanans A–C and Their Glucokinase-Activating Properties
0580
Synthesis of (+)-Plectosphaeroic Acid B
0581
Synthesis of BI 201302
0582
Total Synthesis of Spirocurcasone
0583
Total Synthesis of Cyanolide A
0584
Synthesis of GPI 16539
0585
Synthesis of Atorvastatin
0586
Synthesis of Spiropiperidine BACE-1 Inhibitors
0587
Syntheses of Taiwaniaquinone F and Taiwaniaquinol A
0588
Total Synthesis (+)-Roseophilin
0589
Total Synthesis of (±)-Leuconolam
0590
Asymmetric Synthesis of cis-2,5-Disubstituted Pyrrolidines
0591
Synthesis of a Sodium–Hydrogen Exchange Type 1 Inhibitor

Synthesis of Heterocycles

z593
All PDFs of this category
0593
Synthesis of Pyrazolo[1,5-a]pyrimidines
0594
Synthesis of Indolizinones via Sequential Ritter and Pictet–Spengler Reactions
0595
Functionalized γ-Lactams via Dess–Martin Periodinane Oxidation of Pyrroles
0596
Intramolecular Cyclization Route to Disubstituted 4-Selenyl Isoxazoles
0597
Palladium-Catalyzed Oxidative Isocyanide Insertion for Heterocyclic Synthesis
0598
Synthesis of Substituted 1,2,4-Triazoles from Formamidrazones and Isocyanides
0599
Iridium-Catalyzed Synthesis of Pyrroles from Secondary Alcohols and β-Amino Alcohols
0600
Expedient Access to Biologically Relevant Furan-Based Scaffolds
0601
Scalable Approach to 4-Aminopyrimidines
0602
A Three-Component Copper-Catalyzed Synthesis of Bicyclic Isoxazolidines
0603
Synthesis of Trisubstituted Imidazoles via Oxidative Diamination of Alkynes
0604
A Copper-Catalyzed [3+2]-Cycloaddition Route to Substituted Imidazoles
0605
C–H Activation Route to Phthalazinones from N′-Methylenebenzohydrazides
0606
2-Aryl-3-fluoro-5-silylthiophenes via a [2,3]-Sigmatropic Rearrangement

Synthesis of Materials and Unnatural Products

z607
All PDFs of this category
0607
Large, Yet Soluble, Polycyclic Aromatics
0608
exo-Olefin-Terminated Polyisobutylene via Ether Quenching
0609
A One-Step, Two-Component, Triple Domino Process to Tetrasubstituted Alkenes
0610
Cyclic Oligofluoranthene in One Step
0611
A Novel Electron-Accepting Scaffold for Organic Electronics
0612
Synthesis of Borylated Dibenzoborepin via Skeletal Rearrangement
0613
Low Band Gap Conjugated Polymer Synthesis
0614
Solvent-Free Synthesis of Pyrrolophenanthrolines via Multicomponent Reactions
0615
Synthesis of Hexa(furan-2-yl)benzenes and Their π-Extended Derivatives
0616
Cyclodimerization Leads to a Fluorene-Containing Aromatic Framework
0617
Twisted Polycyclic Arenes by Intramolecular Scholl Reactions
0618
Heterotriangulene Macrocycles toward Honeycomb Networks

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z619
All PDFs of this category
0619
Calcium-Catalyzed Cyclopropanation
0620
Cooperative Oxovanadium–Lipase System for Dynamic Kinetic Resolution
0621
Asymmetric Iron–Brønsted Acid Catalyzed Hydrogenation
0622
Scandium-Catalyzed Asymmetric Mannich Reaction
0623
Nickel-Catalyzed 1,3-Dipolar Cycloadditions to Pyrazolones
0624
Copper-Catalyzed Friedel–Crafts Alkylation–N-Hemiacetalization
0625
Redox-Independent Ruthenium-Catalyzed [4+2] Cycloaddition
0626
Asymmetric Iron-Catalyzed N3-Transfer Using Azoiodinane
0627
Chiral Oxazolidine Diene Ligands for Asymmetric Conjugate Additions
0628
Ruthenium-Catalyzed Intramolecular Silylvinylation of Internal Alkynes
0629
Rhodium-Catalyzed Asymmetric Domino Transformation
0630
Rhodium-Catalyzed Asymmetric Synthesis of Oxazolidinone Scaffolds
0631
Y(III)–Arylamine System for Cooperative Enamine–Lewis Acid Asymmetric Catalysis
0632
Asymmetric Epoxidation of Allylic Alcohols by Chiral Dihydroperoxides
0633
Asymmetric Addition Reaction of Organoboronic Acids to Aldehydes
0634
Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition of Diynes
0635
Copper(II)-Catalyzed Asymmetric Henry Reaction
0636
Rhodium-Catalyzed Enantioselective Alkynylation of Trifluoropyruvates
0637
Copper-Catalyzed Regio- and Enantioselective Hydroboration
0638
Hafnium(IV)-Catalyzed Epoxidation of Tertiary Olefinic Alcohols
0639
Copper-Catalyzed Conjugate Addition to α,β-Unsaturated Lactams
0640
Redox-Neutral [4+2]-Annulation Reaction via Rhenium–Magnesium Catalysis
0641
Gold-Catalyzed Hetero-Diels–Alder Reaction of Diazenes
0642
Copper(I)-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins
0643
Enantioselective Nitro-Michael Addition to (E)-2-Azachalcones
0644
Synthesis of Brominated Enamines via Palladium-Catalyzed Aminohalogenation
0645
Copper-Catalyzed Vinylogous Mukaiyama–Michael Addition Reactions
0646
Nickel-Catalyzed Enantioselective Synthesis of Diarylalkanes and Triarylmethanes
0647
Cyanoalkylation of Imines Catalyzed by a Chiral Palladium Pincer Complex
0648
Copper-Catalyzed Asymmetric Annulation

Metal-Mediated Synthesis

z649
All PDFs of this category
0649
Direct Difluoroethylation of Hetero-aromatics, Michael Acceptors and Thiols
0650
Photo- and Base-Promoted Direct C–H Arylation
0651
Copper-Catalyzed Oxidative Cross-Coupling of Sulfoximines and Alkynes
0652
Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates
0653
Iridium-Catalyzed C–H Borylation of Cyclopropanes
0654
Palladium-Catalyzed Synthesis of N-Aryl Carbamates
0655
Asymmetric Synthesis of α-Heterocyclic Tertiary Boronic Esters
0656
Trifluoromethylation of Allylsilanes
0657
Construction of all-cis-Octatetraenes
0658
Iron-Catalyzed Alkene Hydroboration
0659
Boron-Mediated Asymmetric Aldol Reaction
0660
Copper-Catalyzed Hydrodefluorination of Fluoroarenes
0661
Ag-Promoted, Pd-Catalyzed Intramolecular Direct Arylation of Cyclopropanes
0662
Silver-Mediated Stereoselective Nitration of Mono- and Disubstituted Olefins
0663
Titanocene-Catalyzed Dehydroxylative Cross-Coupling

Organo- and Biocatalysis

z665
All PDFs of this category
0665
Biocatalytic Reductive Amination
0666
Asymmetric Henry Reaction Catalyzed by Planar-Chiral Cyclophane Thiourea
0667
Asymmetric Organocatalytic Thio-Diels−Alder Reactions
0668
Catalytic Asymmetric Diaziridination
0669
A Catalytic Asymmetric Acetalization
0670
NHC-Catalyzed Diastereoselective Synthesis of Substituted Coumarins
0671
Metal-Free Oxidative Coupling of Tertiary Amines to Ketones
0672
Aminocatalytic Addition of Acetaldehyde to Activated Ketones

Polymer-Supported Synthesis

z673
All PDFs of this category
0673
Benzylic Oxidation with Nano-MnO2
0674
Reduction of Nitrobenzenes and Nitroalkanes with NH3·BH3 using Au/TiO2
0675
Suzuki Coupling Using Co/C MNPs-Immobilized Dendritic Phosphine–Pd
0676
Synthesis of Alkylboronates with Silica-SMAP/Ir Complex
0677
Hydroamination of Alkynes by Au/TiO2-N and Visible Light
0678
N-Alkylation of Ammonia or Amines with Alcohols Using NiCuFeOx
0679
Intramolecular O-Arylation with a Polymeric Benzimidazolium Catalyst
0680
Nano-Silica-Supported Palladium Nanoparticles for C–C Couplings
0681
The Suzuki–Miyaura Coupling Catalyzed by SiO2-Tripodal-DPPP-Pd
0682
CuFe2O4-Catalyzed Etherification and Thioetherification of Aryl Halides
0683
WO3-Catalyzed Oxidation of Amines to Oximes using O2
0684
Nucleophilic Substitution Using Alkali Metal Salts Promoted by PSpentaEG
0685
Synthesis of Pyrroles via Paar–Knorr Reaction Using TiO2–SO42–