DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 9 · November 2013 DOI: 10.1055/s-003-25842

Synform

A132
Zanda, Matteo: SYNFORM ISSUE 2013/11

Synthesis of Natural Products and Potential Drugs

z1141
All PDFs of this category
1141
Synthesis of (–)-Aspidospermidine, (–)-Tabersonine, and (–)-Vincadifformine
1142
Synthesis of Hainanolidol and Harringtonolide
1143
Total Synthesis of Scholarisine A
1144
Formal Synthesis of (R)-Flurbiprofen
1145
Synthesis of MK-5172
1146
Synthesis of XL228
1147
Synthesis of Sergliflozin Analogues
1148
Synthesis of (+)-Crotogoudin
1149
Total Synthesis (±)-Agelastatin A
1150
Synthesis of (+)-Ingenol
1151
Synthesis of MK-3207
1152
Total Synthesis of (±)-Actinophyllic Acid

Synthesis of Heterocycles

z1153
All PDFs of this category
1153
Organocatalytic Route to 2,3,4,6-Tetra- and 2,3,4,5,6-Pentasubstituted Pyridines
1154
Synthesis of 6H-Benzo[c]chromen-6-ones via Carbonylative C–H Cyclization
1155
C–H Activation Route to C-4 Substituted Isoquinolones
1156
Rh/Pd-Catalyzed Synthesis of Aza-Dihydrodibenzoxepines
1157
Efficient Borane-Catalyzed cis-Selective Reduction of 2,6-Disubstituted Pyridines
1158
1,3-Dipolar Cycloaddition Route to Pyrrolo-[3,4-c]pyrrole-1,3-diones
1159
General Strategy for the Synthesis of Cyclopropane-Fused Heterocycles
1160
Heteroannulation Route to 2-Hetarylbenzo-thiazoles through Redox Coupling
1161
Asymmetric α-Arylation Route to 5,5-Disubstituted Hydantoins
1162
Ionic Liquid Promoted Synthesis of Substituted Benzofurans
1163
Pd(II)-Catalyzed C–H Activation Route to Indolines
1164
Synthesis of Cytotoxic Fluorinated 1,2,4-Triazoles
1165
Intramolecular Acylative Coupling Approach to Dibenzo[b,e]azepin-11-ones
1166
Synthesis of Pyridazines and Their Fused Derivatives from 1,3-Diketones
1167
Synthesis of Dihydropyrimidin-4-ones from Propargyl Amides and Sulfonyl Azides

Synthesis of Materials and Unnatural Products

z1169
All PDFs of this category
1169
Copper is the Key to C–C Cross-Coupling of C1-Carboranes
1170
A New Twist on Azahelicene
1171
A New Type of Nanocarbon Material
1172
A Spirocycle Feast
1173
Taking Rylene Diimide Dyes to New Lengths
1174
Complex Cage Architecture Incorporating All Ring Sizes from Three to Seven
1175
Rationally Designing a Polymerization Catalyst for Electron-Deficient Monomers
1176
A ‘Ring Walk’ in the Park: Pentafulvenes Rearrange at Room Temperature
1177
Octiarenes from Unfunctionalized Ternaphthalenes and Substituted Benzenes
1178
Atom-Economic Syntheses of Thiophenes and Bithiophenes
1179
Rhodium Cascade Leads to Functionally Rich Acridines and Phenazines
1180
Extensive Functionalization of Butyl Rubber
1181
Diazadithia[7]helicenes

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1183
All PDFs of this category
1183
Asymmetric Hydrogenation of Indolizines and 1,2,3-Triazolo[1,5-a]pyridines
1184
Ru-Catalyzed Asymmetric Hydrogenation of Flavones and Chromones
1185
Asymmetric Ni-Catalyzed Hydrocarbamoylation of Alkenes
1186
Asymmetric Hydrogenation by a BridgePHOS-Ligated Pd Complex
1187
Rh-Catalyzed Asymmetric Hydrogenation of Nitroalkenes
1188
Iron-Catalyzed Enantioselective Synthesis of Sulfimides
1189
Enantioenriched Bicyclic Alcohols via Transannular Ketone-Ene Reaction
1190
Ruthenium-Catalyzed Asymmetric Hydrogenation of tert-Alkyl Ketones
1191
Electrophilic α-Oxygenation Reaction of β-Keto Esters
1192
Synthesis of Bicyclic Ureas via Palladium-Catalyzed Carboamination
1193
Ir-Catalyzed Dehydrogenative Alkene Silylation
1194
Chiral α‑Amino Phosphonates via Rh(I)-Catalyzed Enantioselective 1,4-Addition
1195
Palladium-Catalyzed Desymmetrization of Carbon Nucleophiles
1196
Pd-Catalyzed Alkylation of Unactivated β-C(sp3)–H Bonds of α-Amino Acids
1197
Regio- and Diasteroselective Ru-Catalyzed Hydrohydroxylation
1198
Nickel-Catalyzed Asymmetric Arylation of Pyridinium Ions
1199
Asymmetric Intermolecular Cyclization via Pd-Catalyzed Heck Reaction
1200
Catalyst Controlled C–O versus C–N Allylic Functionalization of Olefins
1201
Rh-Catalyzed Three-Component Reaction of Diazo Compounds
1202
Synthesis of Chiral Allenoates by an ECNU-Phos-Ligated Pd Complex
1203
Pd-DAAA Reaction: Construction of Vicinal Quaternary Stereocenters
1204
Iron(II)-Catalyzed Asymmetric Aminohydroxylation of Indoles
1205
Synthesis of Enantioenriched, Functionalized Secondary Alcohols
1206
Ti-Catalyzed Asymmetric Pinacol Coupling of Aromatic Aldehydes
1207
Enantioselective Cu(II)- and Amine-Catalyzed α-Alkenylation of Aldehydes
1208
Relay Catalysis: Asymmetric Synthesis of anti-Homoallylic Alcohols
1209
Cu-Catalyzed Asymmetric Borylative Cyclization of 1,6-Enynes
1210
Stereoselective Ni-Catalyzed Cycloadditions and Alkenylative Cyclizations
1211
Asymmetric Hydrogenation of Dienamides En Route to Chiral Amines
1212
BiCl3-Promoted Synthesis of Perhydrofuro[2,3-b]pyrans and -furans

Metal-Mediated Synthesis

z1213
All PDFs of this category
1213
Trifluoromethylation of Arenediazonium Tetrafluoroborates
1214
Bi(V)-Mediated Coupling of Thioglycosides with Glycosyl Acceptors
1215
Pd-Catalyzed Enantioselective Synthesis of α-(Trifluoromethyl)arylmethylamines
1216
Ru-Catalyzed Electrophilic Borylation of Heterocycles with Pinacolborane
1217
Highly Enantio- and Diastereoselective Aldol Reactions of N-Acryloylmorpholine
1218
Lithium-Mediated Synthesis of N-Substituted 2-Haloacetamides
1219
Direct Pd-Catalyzed Cross-Coupling of Organolithium Compounds
1220
Isocoumarine Synthesis via Tandem Michael Addition/Cyclization Reaction
1221
Enantioconvergent Couplings of Racemic α-Zn-Pyrrolidines with Alkyl Halides
1222
Asymmetric Br–Li Exchange Reaction in the Synthesis of Natural Products
1223
Fe-Catalyzed Reduction of Esters to Aldehydes
1224
Reductive Cleavage of Aryl O-Carbamates to Phenols
1225
Preparation of Fluoroalkenes by the Shapiro Reaction
1226
Rh-Catalyzed Boron Arylation of 1,2-Azaborines
1227
Organoaluminum-Mediated Interrupted Nazarov Reaction

Organo- and Biocatalysis

z1229
All PDFs of this category
1229
Photochemical α-Alkylation of Aldehydes
1230
Intramolecular Oxa-Michael Reaction of α,β-Unsaturated Amides and Esters
1231
Brønsted Acid Catalyzed Enantioselective Cross-Dehydrogenative Coupling
1232
Phase-Transfer Organocatalytic Deracemization
1233
Organocatalytic Asymmetric Mannich-Type Reaction of Aminals
1234
Boronic Acid Catalyzed Hydrosilylation of Amides to Amines
1235
Enantioselective Aza-Diels–Alder Reaction of Azadienes with Enecarbamates
1236
Kinetic Resolution of Secondary Alcohols by Chiral Phosphoric Acids
1237
Silanediols as a New Type of Anion-Binding Organocatalysts
1238
Procedure-Controlled Enantioselectivity Switch in 2‑Oxazolidinone Synthesis
1239
Arylation of Diazoesters by a Transient N–H Insertion Organocascade

Polymer-Supported Synthesis

z1241
All PDFs of this category
1241
Pd-Catalyzed Cross-Coupling Using Polymer-Supported Siloxane
1242
Preparation of Cyclic Carbonates with N-Heterocyclic Carbene–Ag Catalysts
1243
Direct Synthesis of Cyclohexylanilines from Nitrobenzenes with Pd/C
1244
N-Arylation of Amines Using a Cu–Mn Bimetallic Solid Catalyst
1245
Nanoporous Au-Catalyzed Oxidative N-Formylation of Amines with MeOH
1246
Heck and Sonogashira Reactions Using Pd-Fe3O4 Nanocrystals
1247
A Solid Base Catalyst for the Synthesis of Isatinylidene Rhodamines
1248
Preparation of Silyl Isocyanates Using Au/Al2O3
1249
FeNPs-Catalyzed C–Se and C–Te Bond Formation Reactions
1250
Suzuki–Miyaura Coupling with Cross-Linked Imidazolium/Silica-Pd Catalyst
1251
Friedel–Crafts Reaction Catalyzed by Urea-Postmodified MOF
1252
Polymer-Supported Ru–dm-Pheox for Quinones Synthesis
1253
Preparation of Tetrasubstituted Pyridines with Amberlite IRA-400 (OH–)
1254
A Metal-Organic Framework for the Diels–Alder Reaction