Synfacts
Ausgabe 11 · November 2013
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Ausgabe
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A132
SYNFORM
ISSUE 2013/11
FREIER ZUGRIFF
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Synthesis of Natural Products and Potential Drugs
z1141
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PDF (399 kb)
1141
Synthesis of (–)-Aspidospermidine, (–)-Tabersonine, and (–)-Vincadifformine
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PDF (109 kb)
1142
Synthesis of Hainanolidol and Harringtonolide
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PDF (114 kb)
1143
Total Synthesis of Scholarisine A
FREIER ZUGRIFF
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PDF (130 kb)
1144
Formal Synthesis of (
R
)-Flurbiprofen
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PDF (125 kb)
1145
Synthesis of MK-5172
FREIER ZUGRIFF
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PDF (146 kb)
1146
Synthesis of XL228
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PDF (118 kb)
1147
Synthesis of Sergliflozin Analogues
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PDF (144 kb)
1148
Synthesis of (+)-Crotogoudin
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PDF (125 kb)
1149
Total Synthesis (±)-Agelastatin A
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PDF (132 kb)
1150
Synthesis of (+)-Ingenol
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1151
Synthesis of MK-3207
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1152
Total Synthesis of (±)-Actinophyllic Acid
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Synthesis of Heterocycles
z1153
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PDF (368 kb)
1153
Organocatalytic Route to 2,3,4,6-Tetra- and 2,3,4,5,6-Pentasubstituted Pyridines
FREIER ZUGRIFF
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PDF (130 kb)
1154
Synthesis of 6
H
-Benzo[
c
]chromen-6-ones via Carbonylative C–H Cyclization
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PDF (122 kb)
1155
C–H Activation Route to C-4 Substituted Isoquinolones
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PDF (101 kb)
1156
Rh/Pd-Catalyzed Synthesis of Aza-Dihydrodibenzoxepines
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PDF (111 kb)
1157
Efficient Borane-Catalyzed
cis
-Selective Reduction of 2,6-Disubstituted Pyridines
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PDF (114 kb)
1158
1,3-Dipolar Cycloaddition Route to Pyrrolo-[3,4-
c
]pyrrole-1,3-diones
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PDF (100 kb)
1159
General Strategy for the Synthesis of Cyclopropane-Fused Heterocycles
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PDF (119 kb)
1160
Heteroannulation Route to 2-Hetarylbenzo-thiazoles through Redox Coupling
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PDF (106 kb)
1161
Asymmetric α-Arylation Route to 5,5-Disubstituted Hydantoins
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PDF (132 kb)
1162
Ionic Liquid Promoted Synthesis of Substituted Benzofurans
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PDF (100 kb)
1163
Pd(II)-Catalyzed C–H Activation Route to Indolines
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PDF (111 kb)
1164
Synthesis of Cytotoxic Fluorinated 1,2,4-Triazoles
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PDF (121 kb)
1165
Intramolecular Acylative Coupling Approach to Dibenzo[
b
,
e
]azepin-11-ones
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PDF (108 kb)
1166
Synthesis of Pyridazines and Their Fused Derivatives from 1,3-Diketones
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PDF (117 kb)
1167
Synthesis of Dihydropyrimidin-4-ones from Propargyl Amides and Sulfonyl Azides
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Synthesis of Materials and Unnatural Products
z1169
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1169
Copper is the Key to C–C Cross-Coupling of C1-Carboranes
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1170
A New Twist on Azahelicene
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1171
A New Type of Nanocarbon Material
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PDF (115 kb)
1172
A Spirocycle Feast
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PDF (113 kb)
1173
Taking Rylene Diimide Dyes to New Lengths
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PDF (108 kb)
1174
Complex Cage Architecture Incorporating All Ring Sizes from Three to Seven
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PDF (105 kb)
1175
Rationally Designing a Polymerization Catalyst for Electron-Deficient Monomers
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PDF (120 kb)
1176
A ‘Ring Walk’ in the Park: Pentafulvenes Rearrange at Room Temperature
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PDF (108 kb)
1177
Octiarenes from Unfunctionalized Ternaphthalenes and Substituted Benzenes
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PDF (98 kb)
1178
Atom-Economic Syntheses of Thiophenes and Bithiophenes
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PDF (114 kb)
1179
Rhodium Cascade Leads to Functionally Rich Acridines and Phenazines
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PDF (100 kb)
1180
Extensive Functionalization of Butyl Rubber
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PDF (106 kb)
1181
Diazadithia[7]helicenes
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PDF (102 kb)
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z1183
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1183
Asymmetric Hydrogenation of Indolizines and 1,2,3-Triazolo[1,5-
a
]pyridines
FREIER ZUGRIFF
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PDF (133 kb)
1184
Ru-Catalyzed Asymmetric Hydrogenation of Flavones and Chromones
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PDF (102 kb)
1185
Asymmetric Ni-Catalyzed Hydrocarbamoylation of Alkenes
FREIER ZUGRIFF
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PDF (142 kb)
1186
Asymmetric Hydrogenation by a BridgePHOS-Ligated Pd Complex
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PDF (102 kb)
1187
Rh-Catalyzed Asymmetric Hydrogenation of Nitroalkenes
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PDF (115 kb)
1188
Iron-Catalyzed Enantioselective Synthesis of Sulfimides
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PDF (101 kb)
1189
Enantioenriched Bicyclic Alcohols via Transannular Ketone-Ene Reaction
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PDF (116 kb)
1190
Ruthenium-Catalyzed Asymmetric Hydrogenation of
tert
-Alkyl Ketones
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PDF (124 kb)
1191
Electrophilic α-Oxygenation Reaction of β-Keto Esters
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PDF (133 kb)
1192
Synthesis of Bicyclic Ureas via Palladium-Catalyzed Carboamination
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PDF (109 kb)
1193
Ir-Catalyzed Dehydrogenative Alkene Silylation
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PDF (118 kb)
1194
Chiral α‑Amino Phosphonates via Rh(I)-Catalyzed Enantioselective 1,4-Addition
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PDF (125 kb)
1195
Palladium-Catalyzed Desymmetrization of Carbon Nucleophiles
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PDF (100 kb)
1196
Pd-Catalyzed Alkylation of Unactivated β-C(sp
3
)–H Bonds of α-Amino Acids
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PDF (132 kb)
1197
Regio- and Diasteroselective Ru-Catalyzed Hydrohydroxylation
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PDF (117 kb)
1198
Nickel-Catalyzed Asymmetric Arylation of Pyridinium Ions
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PDF (104 kb)
1199
Asymmetric Intermolecular Cyclization via Pd-Catalyzed Heck Reaction
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PDF (121 kb)
1200
Catalyst Controlled C–O versus C–N Allylic Functionalization of Olefins
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PDF (102 kb)
1201
Rh-Catalyzed Three-Component Reaction of Diazo Compounds
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PDF (126 kb)
1202
Synthesis of Chiral Allenoates by an ECNU-Phos-Ligated Pd Complex
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PDF (107 kb)
1203
Pd-DAAA Reaction: Construction of Vicinal Quaternary Stereocenters
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PDF (112 kb)
1204
Iron(II)-Catalyzed Asymmetric Aminohydroxylation of Indoles
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PDF (102 kb)
1205
Synthesis of Enantioenriched, Functionalized Secondary Alcohols
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PDF (117 kb)
1206
Ti-Catalyzed Asymmetric Pinacol Coupling of Aromatic Aldehydes
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PDF (116 kb)
1207
Enantioselective Cu(II)- and Amine-Catalyzed α-Alkenylation of Aldehydes
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PDF (134 kb)
1208
Relay Catalysis: Asymmetric Synthesis of
anti
-Homoallylic Alcohols
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PDF (113 kb)
1209
Cu-Catalyzed Asymmetric Borylative Cyclization of 1,6-Enynes
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PDF (104 kb)
1210
Stereoselective Ni-Catalyzed Cycloadditions and Alkenylative Cyclizations
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PDF (118 kb)
1211
Asymmetric Hydrogenation of Dienamides En Route to Chiral Amines
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PDF (105 kb)
1212
BiCl
3
-Promoted Synthesis of Perhydrofuro[2,3-
b
]pyrans and -furans
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PDF (108 kb)
Metal-Mediated Synthesis
z1213
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PDF (468 kb)
1213
Trifluoromethylation of Arenediazonium Tetrafluoroborates
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PDF (97 kb)
1214
Bi(V)-Mediated Coupling of Thioglycosides with Glycosyl Acceptors
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PDF (103 kb)
1215
Pd-Catalyzed Enantioselective Synthesis of α-(Trifluoromethyl)arylmethylamines
FREIER ZUGRIFF
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PDF (148 kb)
1216
Ru-Catalyzed Electrophilic Borylation of Heterocycles with Pinacolborane
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PDF (110 kb)
1217
Highly Enantio- and Diastereoselective Aldol Reactions of
N
-Acryloylmorpholine
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PDF (117 kb)
1218
Lithium-Mediated Synthesis of N-Substituted 2-Haloacetamides
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PDF (97 kb)
1219
Direct Pd-Catalyzed Cross-Coupling of Organolithium Compounds
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PDF (97 kb)
1220
Isocoumarine Synthesis via Tandem Michael Addition/Cyclization Reaction
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PDF (98 kb)
1221
Enantioconvergent Couplings of Racemic α-Zn-Pyrrolidines with Alkyl Halides
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PDF (127 kb)
1222
Asymmetric Br–Li Exchange Reaction in the Synthesis of Natural Products
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PDF (113 kb)
1223
Fe-Catalyzed Reduction of Esters to Aldehydes
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HTML
PDF (99 kb)
1224
Reductive Cleavage of Aryl
O
-Carbamates to Phenols
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PDF (106 kb)
1225
Preparation of Fluoroalkenes by the Shapiro Reaction
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PDF (100 kb)
1226
Rh-Catalyzed Boron Arylation of 1,2-Azaborines
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PDF (97 kb)
1227
Organoaluminum-Mediated Interrupted Nazarov Reaction
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PDF (119 kb)
Organo- and Biocatalysis
z1229
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PDF (324 kb)
1229
Photochemical α-Alkylation of Aldehydes
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PDF (135 kb)
1230
Intramolecular Oxa-Michael Reaction of α,β-Unsaturated Amides and Esters
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PDF (135 kb)
1231
Brønsted Acid Catalyzed Enantioselective Cross-Dehydrogenative Coupling
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PDF (126 kb)
1232
Phase-Transfer Organocatalytic Deracemization
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PDF (123 kb)
1233
Organocatalytic Asymmetric Mannich-Type Reaction of Aminals
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PDF (116 kb)
1234
Boronic Acid Catalyzed Hydrosilylation of Amides to Amines
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PDF (98 kb)
1235
Enantioselective Aza-Diels–Alder Reaction of Azadienes with Enecarbamates
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PDF (121 kb)
1236
Kinetic Resolution of Secondary Alcohols by Chiral Phosphoric Acids
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PDF (118 kb)
1237
Silanediols as a New Type of Anion-Binding Organocatalysts
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PDF (104 kb)
1238
Procedure-Controlled Enantioselectivity Switch in 2‑Oxazolidinone Synthesis
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PDF (122 kb)
1239
Arylation of Diazoesters by a Transient N–H Insertion Organocascade
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PDF (126 kb)
Polymer-Supported Synthesis
z1241
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PDF (380 kb)
1241
Pd-Catalyzed Cross-Coupling Using Polymer-Supported Siloxane
FREIER ZUGRIFF
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PDF (126 kb)
1242
Preparation of Cyclic Carbonates with N-Heterocyclic Carbene–Ag Catalysts
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PDF (120 kb)
1243
Direct Synthesis of Cyclohexylanilines from Nitrobenzenes with Pd/C
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PDF (112 kb)
1244
N-Arylation of Amines Using a Cu–Mn Bimetallic Solid Catalyst
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PDF (105 kb)
1245
Nanoporous Au-Catalyzed Oxidative N-Formylation of Amines with MeOH
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PDF (101 kb)
1246
Heck and Sonogashira Reactions Using Pd-Fe
3
O
4
Nanocrystals
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PDF (121 kb)
1247
A Solid Base Catalyst for the Synthesis of Isatinylidene Rhodamines
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PDF (101 kb)
1248
Preparation of Silyl Isocyanates Using Au/Al
2
O
3
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HTML
PDF (118 kb)
1249
FeNPs-Catalyzed C–Se and C–Te Bond Formation Reactions
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PDF (98 kb)
1250
Suzuki–Miyaura Coupling with Cross-Linked Imidazolium/Silica-Pd Catalyst
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PDF (108 kb)
1251
Friedel–Crafts Reaction Catalyzed by Urea-Postmodified MOF
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HTML
PDF (129 kb)
1252
Polymer-Supported Ru–
dm
-Pheox for Quinones Synthesis
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PDF (107 kb)
1253
Preparation of Tetrasubstituted Pyridines with Amberlite IRA-400 (OH
–
)
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HTML
PDF (114 kb)
1254
A Metal-Organic Framework for the Diels–Alder Reaction
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PDF (107 kb)
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