Synfacts

Ausgabe 04 · April 2014

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A44
Zanda, Matteo: SYNFORM ISSUE 2014/04 FREIER ZUGRIFF

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Synthesis of Natural Products and Potential Drugs
z333
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0333
Synthesis of Chemokine Receptor Antagonist NIBR-1282

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0334
Synthesis of Elansolid B1

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0335
Total Syntheses of Cladiellins

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0336
Synthesis of a Histamine-3 Receptor Antagonist

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0337
Synthesis of a Bruton’s Tyrosine Kinase Inhibitor

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0338
Total Synthesis of Lundurine B

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0339
Total Synthesis of (±)-Aspidophylline A

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0340
Synthesis of (±)-Aspidophylline A

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0341
Synthesis of Axitinib

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0342
Synthesis of Filibuvir

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0343
Synthesis of Niraparib

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0344
Total Synthesis of (–)-Leiodermatolide

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0345
Total Synthesis of Kulkenon

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0346
Synthesis of Ertugliflozin

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0347
Synthesis of a HIV Integrase Inhibitor

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Synthesis of Heterocycles
z349
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0349
New Route for the Construction of Indoles from Anilines and Epoxides

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0350
Synthesis of Benzisoxazolones by Ruthenium and Copper Catalysis

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0351
Transition-Metal-Free Synthesis of Carbazoles from 2-Nitrobiaryls

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0352
Synthesis of Annulated P-Heterocycles

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0353
One-Pot Synthesis of Carbazole-1,4-quinones

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0354
Asymmetric Synthesis of Highly Substituted Pyrrolidines via [3+2] Cycloaddition

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0355
Two-Step Synthesis of Benzimidazoles from Nitrosoaromatics

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0356
Palladium-Catalyzed C–H Activation Route to β‑Lactams

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0357
Synthesis of Pyrrolooxazoles by a [3+2] Cycloaddition Route

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0358
Synthesis of 3,4-Carbocycle-Fused Indoles by Rhodium Catalysis

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0359
Functionalization of Imidazoles via Metalation and Sulfoxide–Magnesium Exchange

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0360
β-Lactams from N-Allylamines Using Palladium Catalysis

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0361
One-Step Synthesis of 2-Sulfonylbenzofurans

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0362
Synthesis of Pyrazolopyrimidines from 1,2-Allenic Ketones and Aminopyrazoles

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0363
Multicomponent and Solvent-Free Synthesis of Pyrimidines From Ketones

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Synthesis of Materials and Unnatural Products
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0365
A Cage Full of Gold

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0366
Exploring Biphenylene: North-South Expansion to Graphene Nanoribbons

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0367
An Improved Method for the C3-C–H Arylation of Thiophenes

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0368
No Swelling Here: Polar Polyethylene by Direct Insertion Polymerization

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0369
A Super Diene Busts Up Benzene

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0370
Sensing Chiral Monoamines

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0371
Access to Selenazoles Using LiAlHSeH

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0372
An Unusual Biphenylene Analogue from a Ruthenium [2+2+2] Cycloaddition

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0373
Air- and Light-Stable NIR BisbenzoBODIPY Dyes

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0374
Novel Reactivity of DDQ

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0375
Cavitands with Different Subunits

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0376
A Nicholas Route to Macrocycles

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z377
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0377
Phosphahelicene-Catalyzed Enyne Cycloisomerization

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0378
Rhodium-Catalyzed Formation of Z-Selective Allylsilanes

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0379
Regiodivergent and Stereoselective Coupling of Imidazoles with Allenes

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0380
Sequential Intramolecular Cyclization–Asymmetric Reduction

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0381
Tungsten-Catalyzed Enantioselective Epoxidation of (Homo)Allylic Alcohols

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0382
Asymmetric Synthesis of Chiral Allenes

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0383
Asymmetric [2+2] and [4+2] Cycloadditions

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0384
Nickel-Catalyzed Suzuki Cross-Coupling of Quinolinium Ions

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0385
Diboration and Cross-Coupling Cascades of Terminal Alkenes

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0386
Silver-Catalyzed Asymmetric Mannich-Type Reaction

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0387
Enantioselective Ruthenium-Catalyzed Transfer Hydrogenation of Diynones

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0388
Chiral Phosphorus Compounds via Asymmetric 1,4-Addition

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0389
Copper-Catalyzed Asymmetric Propargylic Alkylation of Diketones

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0390
Decarboxylative Propargylic Alkylation of Propargyl β-Keto Esters

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0391
Syntheses of Biaryls by Asymmetric Suzuki–Miyaura Couplings

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0392
Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

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0393
Metal-Catalyzed Asymmetric Synthesis of Homoallylic Propargylic Alcohols

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0394
Asymmetric C1 Alkynylation of Tetrahydroisoquinolines

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0395
Rhodium-Catalyzed Asymmetric Alkenylation of N-Tosyl Imines

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0396
Chiral-at-Metal Iridium Catalyst for the Asymmetric Conjugate Addition

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0397
Gold(I)-Catalyzed Formal Hydroacylation of Terminal Alkynes with Glyoxals

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0398
Electrophilic Trifluoromethylthiolations of β-Keto Esters

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0399
Silver-Promoted Diastereoselective Synthesis of Ring-Fused Oxazines

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0400
Copper-Catalyzed Enantioselective 1,4-Conjugate Silyl Additions

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0401
Asymmetric Intermolecular Heck Reaction of Aryl Halides

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0402
Use of a Difluoro(phenylsulfonyl)methyl Moiety in Conjugate Addition

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0403
Catalytic Enantioselective Amination of Alcohols

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0404
Iridium(I)-Catalyzed Asymmetric Hydrogenation of α-Alkylidene Carbonyls

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0405
Chiral Branched Allylic Ester via Iridium-Catalyzed Allylic Esterification

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0406
Chiral Fullerenes by [3+2] Cycloadditions

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Metal-Mediated Synthesis
z407
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0407
Synthesis of Silicon-Stereogenic N,O-Functionalized Organosilanes

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0408
Reactions of Carboxamides with N-Chloroamines Catalyzed by Iron

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0409
Platinum-Catalyzed Carboborylation of Alkynes and Sequential Arylation

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0410
Nickel Co-catalyzed Epoxide Ring Opening with Aryl Halides

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0411
Intra- and Intermolecular Reductive Coupling of Olefins

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0412
Improved in situ Generation and Application of the Schwartz Reagent

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0413
Oxidative Approach to Carbazoles and Related Compounds Using MoCl₅

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0414
Catalyzed Reduction of Alkyl Iodides and Deoxygenation of Alcohols

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0415
Enantioselective 1,4-Additions to Cyclohexenones

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0416
Synthesis, Characterization, and Reactions of Organocopper(I) Aggregates

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0417
Zirconium-Promoted Combined C–H and C–C Bond Activation

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0418
Synthesis of Pyrazoles with Diazirines as Electrophilic Nitrogen Sources

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0419
Vinylepoxide Linchpins for Through-Bond/Through-Space Anion Relay Chemistry

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0420
Regioselective Functionalization of 2-Arylazetidines

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0421
Reductive Cyclization of 1,6-Enynes Catalyzed by Iron

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Organo- and Biocatalysis
z423
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0423
Squaramide-Catalyzed Tamura Cycloaddition

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0424
Organocatalytic Coupling Reaction by Imidazolium Salts

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0425
NHC-Catalyzed [3+4] Cycloaddition and Kinetic Resolution of Azomethine Imines

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0426
Friedel−Crafts Reactions Catalyzed by an Unsymmetric Imidodiphosphoric Acid

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0427
Asymmetric Synthesis of α-Amino Phosphonic Acid Derivatives

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0428
Combining Asymmetric Organo- and Biocatalysis via Compartmentalization

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0429
Biocatalytic Synthesis of Enantiopure 2,5-Disubstituted Pyrrolidines

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0430
Asymmetric Aldol Reaction of Formaldehyde Catalyzed by Diarylprolinol

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0431
Dearomatization of Pyridine and Asymmetric Aza-Friedel–Crafts Alkylation

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0432
Cooperative Catalysis for Enantioselective S–H Insertions

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0433
Vinylogous Diels–Alder Reactions Catalyzed by Chiral Phosphoric Acids

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0434
Biocatalytic Intramolecular C–H Amination

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Polymer-Supported Synthesis
z435
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0435
Cross-Dehydrogenative Coupling with a Copper Metalloporphyrin Based MOF

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0436
Dehydrogenation of Amines and Alcohols Catalyzed by Copper Nanoparticles

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0437
Suzuki–Miyaura Cross-Coupling of Aryl Chlorides Using Silica-Supported Ar₃P–Pd

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0438
Au/OMS-2-Catalyzed Aerobic Dehydrogenative Amination

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0439
Solid-Phase Synthesis of N-Hydroxylamines and N-Methylamines

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0440
Selective C–H Borylation of Quinolines with an Iridium–Silica-SMAP Complex

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0441
Dehydrogenation of Alcohols Catalyzed by Rhenium Nanoparticles

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0442
Oxidative Carbonylation of Diols Using Palladium on Carbon

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PDF (96 kb)
0443
A Palladium Nanoparticles Catalyst for Hydrosilylation of Alkynes

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0444
Reductive N-Methylation with CO₂ and H₂ Using CuAlO_x

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0445
Oxidation of ArB(OH)₂ Using Fe₂O₃ Under Solar VIS-Light Irradiation

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0446
Biginelli Reaction with a γ-Fe₂O₃-SO₃H Nanocatalyst

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