DOI: 10.1055/s-00000131

Synfacts

Issue 06 · Volume 10 · June 2014 DOI: 10.1055/s-004-27025

Synform

A75
Zanda, Matteo: SYNFORM ISSUE 2014/06

Synthesis of Natural Products and Potential Drugs

z553
All PDFs of this category
0553
Total Synthesis of Cardamom Peroxide
0554
Synthesis of a Dipeptidyl Peptidase-4 Inhibitor
0555
Industrial Production of Artemisinin
0556
Synthesis of HCV Protease Inhibitor MK-1220
0557
Total Synthesis of Kendomycin
0558
Synthesis of (+)- and (–)-Frondosin B
0559
Synthesis of (–)-Taxuyunnanine D
0560
Synthesis of a Hepatitis C Replication Inhibitor
0561
Synthesis of Propolisbenzofuran B
0562
Total Synthesis of Halichondrin A
0563
Synthesis of Atorvastatin Calcium
0564
Synthesis of GS-9669
0565
Total Synthesis of (±)-Picrinine

Synthesis of Heterocycles

z567
All PDFs of this category
0567
Synthesis of N-Heterocycles via Rhodium(III)-Catalyzed C–H Activation
0568
Cu- and Pd-Catalyzed Heteroannulation Route to Imidazo[4,5-c]pyridines
0569
Benzofurans via Gold-Catalyzed Intramolecular Alkoxyboration of Alkynes
0570
Synthesis of β-Lactams via Intramolecular Oxidative Amidation
0571
Isoindolones via Intramolecular Amination of Benzylic C–H Bonds
0572
Synthesis of Isoindolin-1-ones by sp3 C–H Bond Activation–Cyclization
0573
Synthesis of Quinolinones via Aryne Insertion into C–S Bonds
0574
Oxidative Coupling of Acrylic Acids and Amides with Alkynes
0575
Two-Stage Chemoselective Methylation Method for Heteroarenes
0576
Allylation–Radical Cyclization to Difluoromethylated Dihydrobenzoheteroles
0577
Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers
0578
Palladium-Catalyzed One-Pot Synthesis of Oxazolopyrazines by Heteroannulation
0579
One-Pot Four-Step Regioselective Preparation of Pyrazoles and Isoxazoles
0580
Copper-Catalyzed Route to Azido-Substituted Isoxazolines

Synthesis of Materials and Unnatural Products

z581
All PDFs of this category
0581
Efficient Three-Fold Symmetrical Nanographene Synthesis
0582
‘A–zide’ You’ve Never Seen Before
0583
Poor Packing for Plentiful Pores
0584
Clar-ly Aromatic: A New Route to Tetrabenzo[8]circulene
0585
A Mild Method to Access Functionalized Carboranes
0586
Nucleophilic Substitution on Carbon Nanotubes
0587
A Creative Route to Tetracenes
0588
A Good Way to Dye: A Modular Synthesis of Soluble, Unsymmetric TPDO Dyes
0589
New Palladium Initiators for Living Polymerization of Isocyanides
0590
Cyclopropanation of Norbornene Derivatives with Benzyl Bromides
0591
Bottoms-up: Controlled Synthesis of BN-Heterosuperbenzenes
0592
Poly(α-aminophosphonates) by MCR without Isocyanides

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z593
All PDFs of this category
0593
Copper(II)-Catalyzed Regioselective Acylations of Monosaccharides
0594
Asymmetric Addition of Propargylic Boron to Imines Catalyzed by NHC–Cu
0595
C–C Bond Activation of Cyclobutanones by Rh(I) Catalysis
0596
Ru(II)–Porphyrin-Catalyzed Carbene/Nitrene Transfer and Insertions
0597
Ferrocenes via a Desymmetrization Process Involving C−H Functionalization
0598
Asymmetric Dearomatization of Indoles Catalyzed by Iridium
0599
Copper-Catalyzed Asymmetric Hydroamination of Alkenes
0600
Rhodium-Catalyzed Enantioselective Synthesis of Dihydropyrroloindolones
0601
Copper-Catalyzed Diastereoselective Synthesis of Unnatural Thiazoline Scaffolds
0602
Trimerization of Two Alkynes with Alkenes Catalyzed by a Rhodium Complex
0603
Enantioenriched P-Stereogenic Diarylphosphinites by Palladium Catalysis
0604
Synthesis of Chiral Organoboronates via Enantiotopic-Group-Selective Suzuki Reaction
0605
Mannich Reaction Using a Silver Salt and Cinchona-Derived Aminophosphine
0606
Co(III)(salen)-Catalyzed Phenolic Kinetic Resolution of Epoxides
0607
Asymmetric Allylic Alkylation Catalyzed by Molybdenum
0608
Ruthenium-Catalyzed Stereocontrolled Synthesis of Aminodiols
0609
Ruthenium-Catalyzed trans-Selective Hydrostannation of Alkynes
0610
Iron–Iminium Catalyzed Enantioselective Synthesis of β-Amino α-Hydroxy Esters
0611
Enantioselective Insertion of α-Diazoacetates into O–H Bonds
0612
Kinetic Resolution of Cyclic Enol Ethers Catalyzed by Palladium
0613
Copper-Catalyzed Enantioselective Synthesis of Substituted Pyrrolidines
0614
Rhodium-Catalyzed Sequential Allylic Amination and Olefin Hydroacylation
0615
Cu-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes
0616
Ruthenium-Catalyzed Diastereoselective Cyclization of Enediynes
0617
Enantioselective Fluoroarylation Catalyzed by Palladium
0618
Nickel-Catalyzed Asymmetric Michael–Henry Reaction
0619
Palladium-Catalyzed Cyclative Diacetoxy-lation of Alkynyl Cyclohexadienones
0620
Synthesis of Planar Chiral Metallocenes via an Asymmetric C−H Functionalization
0621
Asymmetric Hydrogenation of α-Acetamidocinnamates by Rhodium Catalysis
0622
Asymmetric Negishi Cross-Coupling en route to Chiral Tertiary Alkyl Fluorides

Metal-Mediated Synthesis

z623
All PDFs of this category
0623
Enantioselective Allene Addition to Aryl and Alkyl Imines
0624
Copper-Promoted, Three-Component Access to Trifloromethylketoximes
0625
Copper-Catalyzed Cross-Coupling and Application to Carboboration
0626
Synthesis of Phenylcyclopropanes from Allylic Alcohols
0627
MnO2-Mediated Aroylation of N-Chlorosulfoximines Using Methyl Arenes
0628
Synthesis of α-Amino Ketones via Aminocyanation of Cyclic Enones
0629
Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides Using (phen)CuRF
0630
1,4-Conjugate Addition of Grignard Reagents Catalyzed by Zinc(II) Salts
0631
Lithiation–Borylation for the Conversion of Alcohols into Pinacol Boronic Esters
0632
Metal Alkoxide Promoted Condensation of 2,3-Allenoates with Aldehydes
0633
Geminal Silicon/Zinc Reagents as CF2 Bis-carbanion Synthons
0634
Preparation of 2-Methyl-1,2-dihydro-naphthalen-1-ols
0635
Addition of Grignard and Organolithium Reagents to N-Carboxyanhydrides
0636
Transfer of Chirality in the Cycloisomerization of Enediynes
0637
Chemo- and Regioselective C(sp3)–H Arylation of Unactivated Allylarenes

Organo- and Biocatalysis

z639
All PDFs of this category
0639
A Novel Chiral NHC Catalyst: Application to an Intramolecular Stetter Reaction
0640
Organocascade Olefin Isomerization/Diels–Alder Reaction
0641
Bifunctional Urea Catalyzed Synthesis of β-Amino Thioesters
0642
Bromoetherification and Desymmetrization Using a Sulfide Organocatalyst
0643
Organocatalytic Asymmetric Fluorination of α-Substituted Cyclohexanones
0644
Catalytic Enantioselective Synthesis of Bridged Tricyclic Benzopyrans
0645
A Route to Chiral Spirocycles via Organocatalytic Bromoetherification
0646
Insights on Asymmetric Sulfoxidation Catalyzed by Imidodiphosphoric Acids
0647
Aminothiourea-Catalyzed Asymmetric Isomerization

Polymer-Supported Synthesis

z649
All PDFs of this category
0649
Adhesive Immobilization of Polymer-Stabilized Pd Nanoparticles on Cellulose
0650
Asymmetric Aldol Reaction Using Zirconium Phosphonate Supported l-Proline
0651
Direct Borylation of Arenes Catalyzed by Ir(I)-bpy-PMO
0652
Synthesis of Sulfones Using CuFe2O4 Magnetic Nanoparticles
0653
Synthesis of Trisphenols with Tungstosilicic Acid in Water
0654
S-Arylation of Malononitrile–CS2 Adduct Using CuO Nanoparticles
0655
Asymmetric Henry Reaction with Block Copolymer Supported Copper(II)
0656
Suzuki Coupling Using a Polystyrene-Supported Oxime Palladacycle
0657
Coupling of Epoxides and CO2 with a Copper Azamacrocycle Based MOF
0658
Reductive Amination of Nitriles with Platinum Nanowires
0659
Regioselective Hydroaminomethylation of Styrenes Catalyzed by Rhodium
0660
Aerobic Oxidation of Amines with Pd3Pb/Al2O3
0661
Biginelli Reaction Using Mn@PMO-IL