DOI: 10.1055/s-00000131

Synfacts

Issue 01 · Volume 11 · January 2015 DOI: 10.1055/s-004-28218

Synform

A1
Zanda, Matteo: SYNFORM ISSUE 2015/01

Synthesis of Natural Products and Potential Drugs

z1
All PDFs of this category
0001
Syntheses of Hapalindole-Type Alkaloids
0002
Synthesis of GSK1324726A
0003
Asymmetric Synthesis of a DPP-4 Inhibitor
0004
Synthesis of a Key Building Block for HCV Protease Inhibitor Telaprevir
0005
Synthesis and Biology of Axinellamines A and B
0006
Total Synthesis of (−)-Gephyrotoxin
0007
Synthesis of Sarpagine Alkaloids
0008
Synthesis of (R)-Rasagiline via Dynamic Kinetic Resolution
0009
Synthesis of (−)-4-Hydroxyzinowol
0010
Total Synthesis of (+)-Dihydroperaksine-17-al, (+)-Dihydroperaksine, and (+)-Peraksine
0011
Synthesis of (–)-N-Methylwelwitindolinone B Isothiocyanate

Synthesis of Heterocycles

z13
All PDFs of this category
0013
Pd-Catalyzed Synthesis of N-Aryl Indoles
0014
Direct Cyclization–Trifluoromethylthiolation to 4H-Chromen-4-ones
0015
Rhodium(I)-Catalyzed [4+2]-Cycloaddition Route to 1,2-Dihydropyridines
0016
One-Pot Diastereoselective Synthesis of Azabicyclo[2.2.2]octanes
0017
Aziridine and β-Lactam Synthesis by Amination and Carbonylation Reactions
0018
Tetrahydrofurans and Pyrrolidines from N-Tosylhydrazones via C–H Insertion
0019
Copper(I)-Catalyzed Synthesis of 3-Amino-2-pyrones and 2,5-Dihydrofurans
0020
Auto-Oxidation–Povarov Annulation Approach to Quinolines
0021
Synthesis of Indoles, Pyrazoles, and Pyridazinones
0022
NHCs in Rhodium-Catalyzed C–H Activation–Annulation to Fused Imidazolium Salts
0023
Iron-Mediated Synthesis of Pyrroles from Cyclopropanes
0024
Synthesis of 2-Aminothiophenes from Alkynoates and Thioamides
0025
An Improved Procedure for a Pd-Catalyzed Amidation Approach to Imidazopyridines
0026
Enantioselective Synthesis of 3,4-Dihydrothiacarbazol-2(9H)-ones
0027
Copper-Catalyzed Amidation of π-Excessive Heterocycles

Synthesis of Materials and Unnatural Products

z29
All PDFs of this category
0029
Taking the Dimers Out of Diazaheptacenes
0030
Triazole Your Tetrazoles
0031
Twin Helicenes Twist Benzene
0032
Divergent Synthesis of Tricyclic Biselenophene-Based Derivatives
0033
Having the Gall to Synthesize Conjugated Polymers Containing Gallium Atoms
0034
Phosgene as Key Reagent for Trifunctionalization of BODIPY Dyes
0035
PB&J: Phosphorus and Boron at the Junction of Two π-Systems
0036
A Diels–Alder Approach to Graphene Nanoribbon Precursors
0037
Not-So-Triyne Route to Heteroarylene and Arylene Macrocycles
0038
Electropolymerization Furnishes Conducting Polyfuran Films
0039
A High Cyano Content Indacene as a Stable Organic Electron Acceptor
0040
An Unusual Regioselective Di-, Tetra-, and Hexa-Bromination

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z41
All PDFs of this category
0041
Enantioselective C–H Insertion Reactions of Donor–Donor Carbenoids
0042
Enantioselective Rhodium-Catalyzed Allylation of 2-Pyridones
0043
Palladium-Catalyzed Nucleophilic Allylation of Aldehydes or Aldimines
0044
Enantioselective Rhodium-Catalyzed Synthesis of Axially Chiral Biaryls
0045
CuH-Catalyzed Enantioselective Anti-Markovnikov Hydroamination
0046
Zirconium/VANOL-Catalyzed Asymmetric α-Iminol Rearrangement
0047
Isomerization of Allylrhodium Intermediates During Allylations of Imines
0048
Asymmetric Conjugate Addition of Dimethylzinc to (Z)-Nitroalkenes
0049
Asymmetric Synthesis of Ferrocenes via Palladium-Catalyzed C–H Bond Activation
0050
Rhodium-Catalyzed Enantioselective Hydrogenation of Enamido Esters
0051
Divergent Reactivity of 2-Triazole Benzaldehydes under Rhodium Catalysis
0052
Cobalt-Catalyzed Asymmetric Hydroboration of Alkenes
0053
Asymmetric Reduction of α-Amino Ketones Catalyzed by Lewis Acids
0054
Chiral Furans via Asymmetric [3+2] Cycloaddition
0055
Nickel-Catalyzed Asymmetric Claisen Rearrangement
0056
Synthesis of trans-Cycloalkenes via Cyclopropanation and Rearrangement
0057
Enantioselective Zr-Catalyzed Carboalumination Plus Cu-Catalyzed Cross-Coupling
0058
Nickel-Catalyzed Asymmetric Reductive Coupling of Vinyl and Benzyl Halides
0059
Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Ketone Enolates
0060
Enantioselective Allylation of Diphenyl-phosphine Oxide
0061
Tandem α-Alkylation–Asymmetric Transfer Hydrogenation of Acetophenones
0062
Enantioselective Synthesis of β-Hydroxy Sulfones via Transfer Hydrogenation
0063
Intramolecular Asymmetric Desymmetrization via Copper Catalysis
0064
P-Chiral P,π-Dihydrobenzooxaphosphole Ligands in Asymmetric Catalysis
0065
Axially Chiral Biaryl Compounds via Dynamic Kinetic Resolution
0066
Enantioselective Palladium/Organo-Catalyzed Additions to Unsaturated Aldehydes
0067
(–)-Sparteine versus (+)-Sparteine Surrogates in Copper(II)–Diamine-Catalyzed Reactions
0068
Enantioselective Reaction of Tertiary Enamides with Salicylaldehydes
0069
Synthesis of 1,2-Amino Alcohols via Asymmetric Hydrogenation
0070
Asymmetric Reductive Amination of Ketones

Metal-Mediated Synthesis

z71
All PDFs of this category
0071
Metallacycle-Mediated Annulation for the Synthesis of Hydroindanes
0072
Cyclization of 1-(Trifluoromethyl)-4-alkyn-1-ones with Arylboronic Acids
0073
An Efficient, Practical, and Selective Multicomponent Copper-Catalyzed Process
0074
Accessing 2-(Hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes
0075
Palladium-Catalyzed Cross-Coupling of Triorganoindium Reagents
0076
Nickel-Catalyzed Intramolecular Cyclization of Dihaloalkanes
0077
Palladium-Catalyzed Cross-Coupling of 1,1-Diboronates
0078
Zirconium-Mediated Synthesis of Pyrroles
0079
Trans-Selective Silylzincation of Terminal Ynamides
0080
Titanium-Mediated Cycloaddition
0081
Aryl Sulfamate and Tosylate Cross-Coupling with Aryl Grignard Reagents
0082
Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling
0083
Oxidative Amination of the Zinc Bromide Complex of β-Enamino Esters
0084
Copper-Catalyzed Coupling of Indium Reagents
0085
Construction of a Tetrafluoroethylene-Bridging Structure via Carbocupration

Organo- and Biocatalysis

z87
All PDFs of this category
0087
A One-Pot Biocatalytic Sequence to 6-Aminohexanoic Acid
0088
Asymmetric β-Hydroxylation of Enals Catalyzed by an N-Heterocyclic Carbene
0089
Enantioselective Dearomatization of Indoles
0090
Enzyme-Controlled Regiodivergent C–H Amination
0091
Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles
0092
Amine-Catalyzed Direct Vinylogous Michael Addition of Dienols to Enals
0093
P-Chiral Phosphoramidates from a Catalytic Asymmetric Halocyclization
0094
Dynamic Kinetic Asymmetric Cross-Benzoin Additions
0095
Enantioselective Addition of Masked Acyl Cyanides to N-Boc Imines
0096
β-Functionalization of Carboxylic Anhydrides with N-Heterocyclic Carbenes

Polymer-Supported Synthesis

z97
All PDFs of this category
0097
Cyclopropanation of Alkenes with Diazoesters Using Cu@FeNPs
0098
Chemoselective Reduction of α,β-Unsaturated Aldehydes with AuNPore
0099
A Zeolitic Imidazolate Framework Catalyst for [3+3] Cycloadditions
0100
Hydroacylation of Azodicarboxylates with Aldehydes Using CoO–Fe3O4
0101
A Heterogeneous Palladium Catalyst for C2-Selective Arylation of Indoles
0102
C–H Borylation of Cyclopropanes and Cyclobutanes with Silica-SMAP–Iridium
0103
Olefin Metathesis with Ruthenium–Carbene Supported on Iron Oxide
0104
Hydroamination of Alkynes Using Amphiphiles-Based Au@SiO2
0106
Click Reaction Using Polymer-Supported CuI–Cryptand-22
0107
The Mizoroki–Heck Reaction Using a Palladium–NHC Complex Supported on MNP
0108
Visible-Light-Promoted aza-Henry Reaction Using Mesoporous Cu2O
0109
Asymmetric α-Benzylation with Cinchonidium Salt Based Polymers
0110
N-Formylation of Amines Using Molybdate Sulfuric Acid