Synfacts

Ausgabe 03 · März 2015

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Ausgabe
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A33
SYNFORM ISSUE 2015/03 FREIER ZUGRIFF

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Synthesis of Natural Products and Potential Drugs
z225
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0225
Asymmetric Copper-Catalyzed Hydroamination of Aryl Alkynes FREIER ZUGRIFF

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0226
Synthesis of (±)-Hippolachnin A

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0227
Synthesis of (+)-Chatancin FREIER ZUGRIFF

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0228
Synthesis of ACT-280778

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0229
Synthesis of a Histone Deacetylase Inhibitor

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0230
Total Synthesis of Alsmaphorazine D

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0231
Enantioselective Synthesis of Maoecrystal V

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0232
Synthesis of DNA Gyrase Inhibitor

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0233
Photochemical Synthesis of Intricarene

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0234
Synthesis of Ipatasertib

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0235
Synthesis of Zanamivir

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0236
Synthesis of (–)-Lundurine A

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0237
Formal Synthesis of Hongoquercin B

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0238
Synthesis of a Chemokine Receptor Antagonist

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0239
Photoredox Catalysis in the Synthesis of JAK2 Inhibitor LY2784544

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Synthesis of Heterocycles
z241
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0241
Palladium-Catalyzed Synthesis of Isatins from Anilines by Double Carbonylation FREIER ZUGRIFF

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0242
Microwave-Assisted Synthesis of Pyrazolotriazines

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0243
Multicomponent Synthesis of 3-Arylmethyl-2,5-diarylthiophenes

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0244
Benzimidazole-Fused Thiadiazoles From ortho-Phenylenediamine Dithioureas

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0245
Preparation of Spirocyclic N-Heterocycles Utilizing Stannyl Amine Reagents

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0246
Difluoro-oxindoles by C–H Bond Difluoro-alkylation of Chlorodifluoroacetanilides

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0247
Aminoindolines and -indoles by Rhodium-Catalyzed C–H Bond Activation

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0248
Synthesis of Fused Pyridines by a ZnCl₂-Promoted Three-Component Reaction

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0249
Spiro[indene-1,2′-pyrrolidene] by [3+2] Annulation of Pyrroles with Alkynes

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0250
Asymmetric Synthesis of Dihydropyridinones and Derivatization

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0251
A Hydroheteroarylation Route to 2-Substituted Benzoxazoles

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0252
Metal-Free Tandem Oxidative Acylation–Cyclization to Coumarins

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0253
6-Trifluoroethylphenanthridines by Photoredox Reaction

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0254
Highly Substituted Pyrazoles from N-Propargyl Hydrazones

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0255
Indium-Catalyzed Intramolecular Hydroarylation Route to 2H-Chromenes

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Synthesis of Materials and Unnatural Products
z257
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0257
Truncated π-Helicenes

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0258
Semithiobambusurils Binding with Anions and Metal Ions

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0259
A Rapid Route to Core Nitrogen Containing Polycyclic Aromatics FREIER ZUGRIFF

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0260
Tetraphenylpyrazine-Based Aggregation-Induced Emission Luminogens

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0261
Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

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0262
Twisting the π Away

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0263
Air on the Side of Naphthyridines

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0264
Caught by Copper: Direct Synthesis of Poly(ortho-aryne)s

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0265
Annulated Phospholes from Phosphinidenes by C–H Bond Activation

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0266
Nothing Boring about this Borylation

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0267
Reactivity of Phosphinoboronate Ester

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0268
Unforeseen Helicene

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z270
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0269
Asymmetric Hetero-Diels–Alder Reaction

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0270
Palladium-Catalyzed Regio- and Enantioselective C-Alkylation of Isoxazolinones

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0271
Rhodium-Catalyzed Asymmetric C–H Functionalization of Methyl Ethers FREIER ZUGRIFF

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0272
Asymmetric Hydrogenation of Quinoxalines Catalyzed by Borane

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0273
Copper–Bis(NHC)-Catalyzed Asymmetric Conjugate Addition of Dialkylzincs to Enones

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0274
Iridium-Catalyzed Asymmetric Allylic Sulfonation

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0275
Silver-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides

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0276
A Palladium-Catalyzed Diastereo- and Enantioselective Synthesis of Pyrrolidines

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0277
Asymmetric Mannich Reaction of Silyl Ketene Imines with Isatin-Derived Ketimines

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0278
Scandium-Catalyzed Asymmetric Homologation of Ketones with α-Diazo Esters

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0279
Rhodium-Catalyzed Diastereoselective [3+1+2] Cycloaddition of Aminocyclopropanes

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0280
Stereoselective Aminoboration by Means of Copper Catalysis

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0281
Cobalt-Catalyzed Enantioselective C–H Alkylation of Indoles

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0282
Enantioselective Intramolecular Hydroacylation Catalyzed by Cobalt

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0283
Asymmetric Conjugate Addition of Malononitriles to Fluxional Substituted Enoates

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0284
Rhodium(III)-Catalyzed C–H Allylation of Benzoic Acid Derivatives

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0285
Enantioselective Mannich-Type Reaction of α-CF₃ Amide by Copper(I) Catalysis

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0286
Copper-Catalyzed Enantioselective Borylation of Aldehydes

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0287
Gold-Catalyzed Hydroamination of Alkylidene Cyclopropanes

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0288
Desymmetrization of Malonamides via Intramolecular C–N Coupling

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0289
Chiral N-Substituted 2-Pyridones via Iridium-Catalyzed Allylic Amination

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0290
Synthesis of Spiroindolenines Catalyzed by Palladium

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0291
Asymmetric Palladium-Catalyzed Cross-Coupling of Bis(boronates) and Vinyl Halides

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0292
Iron-Catalyzed Asymmetric Hydroboration of Styrenes

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0293
Iridium-Catalyzed Asymmetric Hydrogenation of Furans and Benzofurans

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0294
Enantioselective Alkylation Catalyzed by a Lewis Acid and an Organocatalyst

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0295
Enantioselective Synthesis of Piperazin-2-ones and Piperazines

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0296
Asymmetric Iridium-Catalyzed Hydrogenation for the Synthesis of Nicotine Analogues

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0297
Ester Hydrogenation Promoted Kinetic Resolution of Aliphatic Alcohols

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0298
Meyer–Schuster-like Rearrangement of Propargylic Amines

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Metal-Mediated Synthesis
z299
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0299
Directed Metalation of Ester-Substituted Indolizines FREIER ZUGRIFF

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0300
Cobalt-Catalyzed Asymmetric Kumada Cross-Coupling

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0301
Zinc-Mediated Alkynylation – Brook Rearrangement – Ene–Allene Cyclization

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0302
Copper-Mediated Trifluoromethylation

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0303
α-Alkylation of Ketones

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0304
Titanate-Mediated Iron-Catalyzed Oxidative Cross-Coupling

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0305
Synthesis of Enantiopure Cyclopentenones

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0306
Enantioselective Conjugate Addition of Grignard Reagents to Silylated Enoates

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0307
Cross-Coupling of Aryllithium Reagents with 2-Alkoxy-Substituted Aryl Chlorides

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0308
meta-Selective Arylation of O-β-Naphthyl Carbamate with Boronic Acids

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0309
Lithiation–Electrophilic Substitution of tert-Butoxythiocarbonyl Azetidines

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0310
Synthesis of Polysubstituted Pyrroles

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0311
C-3 Arylation of N-Alkyl-2-pyridones

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0312
gem-Difluorinated Nitroso Compounds Derived From Organozinc Reagents

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0313
Boron-Catalyzed Reduction of Quinolines

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Organo- and Biocatalysis
z315
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0315
Isothiourea-Catalyzed Michael Addition to Unsaturated Trichloromethyl Ketones

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0316
Enantioselective Phase-Transfer Arylation with Arene Chromium Complexes

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0317
NHC-Catalyzed Formal [4+3] and [4+1] Annulations

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0318
Organocatalytic Asymmetric Synthesis of 1,2-Dihydronaphthalenes

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0319
Phosphinothiourea-Catalyzed Hydroamination of Allenoates

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0320
‘Enol Catalysis’ in the Synthesis of Odorants

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0321
Mannich-Type Reactions via Chiral Ion Pairs

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0322
Enzyme-Catalyzed Cyclopropanation of Aryl-Substituted Olefins

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0323
Catalytic Dynamic Kinetic Resolution of β-Halo-α-keto Esters

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0324
Alkylative Desymmetrization of Cyclopentane Diones

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0325
Enantioselective Intermolecular Cross Rauhut–Currier Reaction

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0326
Catalytic Asymmetric Synthesis of Thiols

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Polymer-Supported Synthesis
z327
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0327
Solid-Phase Synthesis of Phenylalanine-Containing Peptides Using a Triazene Linkage

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0328
Flow Oxidation of Alcohols with a Gold Catalyst Under Inductive Heating

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0329
MOFs Bearing Free Carboxylic Acids for Organocatalyst Encapsulation FREIER ZUGRIFF

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0330
Click Reaction with Copper Nanoparticles Supported on Hexarylbenzene

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0331
Magnetically Separable Proton Sponge for Knoevenagel Condensation

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0332
Chemoselective Acylation of Primary Alcohols Using [γ-HGeW₁₀O₃₆]^7–

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0333
Cyanation of Aryl Iodides with K₄[Fe(CN)₆] Using Pd-BNPs

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0334
Synthesis of Substituted Benzoxazoles Using Copper Ferrite Nanoparticles

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0335
Iodine-Loaded Ni(II)-MOF Catalyst for Silylcyanation of Benzaldehyde

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0336
Synthesis of Ynamides with Copper(I)-Zeolite

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0337
Supported Iminophosphorane Superbase Organocatalysts

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0338
Synthesis of Benzodiazepines Using Fe₃O₄@Chitosan

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0339
Suzuki Coupling Using a Palladium Catalyst Supported on Carbon-Coated Cobalt NPs

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0340
α-Arylation of β-Diketones with Aryl Halides Using CuO/Aluminosilicate

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0341
Synthesis of Organozinc Halides and Subsequent Negishi Coupling in Flow

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Erratum
0342
Asymmetric Synthesis of a DPP-4 Inhibitor

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