DOI: 10.1055/s-00000131

Synfacts

Issue 04 · Volume 11 · April 2015 DOI: 10.1055/s-005-28806

Synform

A47
Zanda, Matteo: SYNFORM ISSUE 2015/04

Synthesis of Natural Products and Potential Drugs

z343
All PDFs of this category
0343
Synthesis of (±)-Tanegool and (±)-Pinoresinol
0344
Synthesis of (±)-Aureol
0345
Synthesis of PLK4 Inhibitor CFI-400945
0346
Synthessis of Tipifarnib
0347
Synthesis of Pseudopterosin (–)-G-J Aglycone
0348
A Claisen Approach to 4′-Ed4T
0349
Synthesis of Trioxacarcin DC-45-A2
0350
Synthesis of an HCV Protease Inhibitor
0351
Synthesis of (−)-Nardoaristolone B
0352
Assembly-Line Synthesis of (+)-Kalkitoxin and (+)-Hydroxyphthioceranic Acid
0353
Divergent Synthesis of Monoterpene Indole Alkaloids
0354
Synthesis of the Hydroxyquinolinone Core of β2-Receptor Agonists
0355
Synthesis of Taxadienone

Synthesis of Heterocycles

z357
All PDFs of this category
0357
Atom-Efficient Organolanthanide 1,2-Dearomatization of Pyridines
0358
Arene–Ynamide Cyclization Approach to Pyrroloquinolines
0359
Imidazoles and Imidazoliums from Propargylamines and Isonitriles
0360
Diastereoselective Synthesis of Fluorinated Amino-Sugars
0361
Synthesis of Fused Indoles and Pyridin-2-ones by Radical Cyclization Cascades
0362
Synthesis of Polyfluoro-1,3-thiazine Derivatives
0363
Preparation of Pyrido[3,4-d]azepines by Pyridine Ring Heteroannulation
0364
Synthesis of Dihydropyrazines from N-Sulfonyl-1,2,3-triazoles and Aziridines
0365
Palladium-Catalyzed Heteroannulation Route to Azaindoles
0366
Rhodium-Catalyzed Directed Halogenation of π-Excessive Heterocycles
0367
Sultams by Arylation of Cyclic N-Sulfonyl Aryl Alkyl Ketimines
0368
Ruthenium-Catalyzed Synthesis of 1,4-Benzodiazepines
0369
Seven-Membered Heterocycles by Chlorosilane-Catalyzed Heteroannulation
0370
Synthesis of Enantioriched δ-Lactones from β-Halo-α-keto Esters
0371
Rhodium-Catalyzed Oxidative Annulation Route to 1-Aminoindolenines

Synthesis of Materials and Unnatural Products

z373
All PDFs of this category
0373
Carbo-Quinoid Carbo-Benzene Switch
0374
Convenience is King: One-Pot Derivatization of Azulenes
0375
Hexaarylbenzenes with Five or Six Distinct Substituents
0376
No Metal, No Problem: Transition Metal Free ROMP
0377
Silylation of Aromatic Heterocycles with Potassium tert-Butoxide Catalyst
0378
Decorate it with Sulfur
0379
Climbing the Ladder
0380
Modular Synthesis of [6]Polynorbornane-Based Ligands
0381
SET Yourself Up for Some Fast, Cheap, and Easy Phenanthrenes
0382
One-Pot Reactions to Make Indolos? YOLO
0383
Dialkylzinc-Mediated Perfluoroalkylation
0384
Finding Propellers Among the Cascades

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z385
All PDFs of this category
0385
Enantioselective and Stereodivergent Synthesis of β,β-Diaryl-α-Amino Acids
0386
Enantioselective Gold-Catalyzed Cyclopropanation
0387
Ruthenium-Catalyzed Z-Selective Cross-Metathesis of Allylic Alcohols
0388
Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Esters
0389
Aryl Esters as Electrophiles in Nickel-Catalyzed Asymmetric α-Arylation
0390
Copper-Catalyzed Enantioselective Hydroboration of Strained Alkenes
0391
Isomerization of Terminal Alkenes to (Z)-2-Alkenes via Cobalt Catalysis
0392
Nickel-Catalyzed Enantioselective Reductive Cyclizations of Alkynones
0393
Palladium-Catalyzed Enantioselective Dearomative Cyclization of Phenols
0394
Palladium-Catalyzed Enantioselective Hydrogenolysis of N-Sulfonyloxaziridines
0395
Diastereoselective Synthesis of Highly Substituted Indolines via Palladium Catalysis
0396
Palladium-Catalyzed Desymmetrization of meso-Diols
0397
Magnesium-Catalyzed Stereoselective Dearomatization of β-Naphthols with Aziridines
0398
Asymmetric Hydrogenation Catalyzed by Chiral Alkenylboranes
0399
Rhodium-Catalyzed Asymmetric Isomerization of 4-Iminocrotonates
0400
Direct Asymmetric Vinylogous Michael Addition Catalyzed by Ytterbium(III)
0401
Asymmetric Hydroformylation of Vinylarenes via Rhodium Catalysis
0402
Rhodium-Catalyzed Enantioselective Addition of Thiols to Allenes
0403
Asymmetric Hydrogenation of Conjugated Enamides by Rhodium Catalysis
0404
Asymmetric Synthesis of P-Stereogenic Phosphinamides via Pd(II) Catalysis
0405
Palladium-Catalyzed Asymmetric Synthesis of α-Quaternary Mannich Products
0406
Copper-Catalyzed syn-Selective Alkylboration of Alkynes
0407
Asymmetric Synthesis of 5,6-Dihydrophenanthridines
0408
Catalytic Asymmetric Pauson–Khand Reaction Using Cobalt
0409
Enantioselective [3+2] Cycloaddition Catalyzed by Magnesium
0410
Desymmetrization of Maleimide-Based Bis(alkynes) via Cu-Catalyzed Click Reaction
0411
Zinc(II) Chloride Promoted Asymmetric Hydrogenation
0412
Enantioselective Oxidative Coupling of 2-Naphthols and Aryl Methyl Ketones
0413
Iron-Catalyzed Asymmetric Epoxidation of Electron-Poor Olefins

Metal-Mediated Synthesis

z415
All PDFs of this category
0415
Addition of Carboxylic Acids Using Chiral Lithium Amides as Auxiliaries
0416
Stereoselective Alkylation of Malonate-Imidazolidinones
0417
Stereoconvergent [1,2]- and [1,4]-Wittig Rearrangements
0418
Iron-Catalyzed Boration of Alkynes
0419
Tandem Arylation–Protodecarboxylation
0420
trans-2,6-Disubstituted 5-Methyl-3,6-dihydropyrans by Zinc Catalysis
0421
Phosphorylation of (Benzo)thiazoles Mediated by Silver Nitrate
0422
Regioselective Derivatizations of a Benzamide Scaffold
0423
Nickel-Catalyzed Alkynylation of Anisoles
0424
Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes
0425
Palladium-Catalyzed α-Arylation of Aryl Acetic Acid Derivatives
0426
Decomposition of Difluorocarbene for Trifluoromethylation
0427
Trifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate
0428
Copper-Catalyzed Asymmetric Allylic Alkylation
0429
Copper-Catalyzed Cross-Coupling of Epoxides with Arylboronates

Organo- and Biocatalysis

z431
All PDFs of this category
0431
Hydroxylation of Aliphatic C–H Bonds with a Ketone-Derived Organocatalyst
0432
NHC-Catalyzed Radical β-Hydroxylation of Enals
0433
Enantioselective [5+2] Cycloaddition of Oxidopyrylium Ylides and Enals
0434
Kinetic Resolution of 1,2-Amino Alcohols by Intermolecular Acetalization
0435
Asymmtric Synthesis of Indanes by 5-endo-trig Cyclization
0436
Reduction of Aryl Halides by Consecutive Two-Photon Excitation
0437
Resolution of Racemic Diols by Asymmetric Acetalization
0438
Organocatalytic Addition of Aldehydes to 4-Vinylpyridines and Vinylarenes

Polymer-Supported Synthesis

z439
All PDFs of this category
0439
Hydration of Alkynes with Au/TiO2 in the Presence of Morpholine
0440
Amination of Aryl Halides Using CuSO4@Chitosan
0441
Flow-Generated Diazo Compounds and Their Use in Cross-Coupling
0442
Hydrogenation of Nitroarenes Using a Carbon Nanotube–Ruthenium Nanohybrid
0443
Carbene Transfer Reaction Using a PS-Supported Copper Catalyst
0444
Selective Transfer Semihydrogenation of Alkynes Using AuNPore
0445
Graphitic Carbon Nitride Promoted Photoredox Fluoroalkylation of Arenes
0446
Synthesis of Pyrroles Using Supported p-Toluenesulfonic Acid
0447
Dendritic-PEGylated γ-Fe2O3–PdNPs as Catalysts for C–C Bond Formations
0448
Copper-MOF-Catalyzed Aerobic Oxidation of Olefins and Alcohols
0449
A Ruthenium Catalyst for Coupling of Benzoic Acids with Internal Alkynes
0450
C–H Arylation of Heteroarenes Using Fe3O4–CeO2 Magnetite Nanoparticles
0451
Carboxylation of Terminal Alkynes with Carbon Dioxide Using Ag@MIL-101
0452
Ring-Closing Metathesis with an Ionic MNP-Supported Ru–Carbene Complex