DOI: 10.1055/s-00000131

Synfacts

Issue 05 · Volume 11 · May 2015 DOI: 10.1055/s-005-28993

Synform

A60
Zanda, Matteo: SYNFORM ISSUE 2015/05

Synthesis of Natural Products and Potential Drugs

z453
All PDFs of this category
0453
Asymmetric Syntheses of Megacerotonic Acid and Shimobashiric Acid A
0454
Total Synthesis of Dictyodendrin B
0455
Synthesis of a FLAP Inhibitor
0456
Synthesis of an Aurora Kinase B Inhibitor
0457
Synthesis of Aeruginosin Natural Products
0458
Synthesis of Indolo-Phakellins
0459
Synthesis of Telmisartan
0460
Synthesis of Alkaloid (–)-205B
0461
Total Synthesis of (+)-Brefeldin A
0462
Synthesis (S)-RO4999200
0463
Synthesis of trans-Clerodane Natural Products
0464
Synthesis of (+)-Rugulotrosin A
0465
Synthesis of Bimatoprost
0466
Formal Synthesis of Atorvastatin
0467
Synthesis of GSK1265744

Synthesis of Heterocycles

z469
All PDFs of this category
0469
Modular Assembly of Imidazoles by 1,3-Dipolar Cycloaddition
0470
Construction of Aza/Oxa-Spirocyclic Skeletons. Formal Synthesis of (±)-Halichlorine
0471
Polycyclic Spiroindolines from Asymmetric Dearomatization of Indoles
0472
1,4-Benzothiazines by Copper-Catalyzed Ring Expansion of Benzothiazoles
0473
Synthesis of Dibenzothiazepine Dioxides by Reductive Heck Cyclization
0474
Synthesis of Pyrroles and Dihydropyrazines from Azirines and 1,2,3-Triazoles
0475
One-Pot Cycloaddition–Strecker Cascade to Imidazo[1,2-a]heterocycles
0476
Trifluoromethylthiolation of Indoles
0477
Synthesis of F5C2-Substituted Pyrazoles
0478
Carbonylated Benzofurans by Metal-Free Radical Cyclizations of 1,6-Enynes
0479
Synthesis of Substituted Pyrroles and 1,2-Oxazinanes
0480
An Unexpected Route to Pyrrolo[2,3-c]pyridazin-6-ones
0481
A Photoredox Approach for the Synthesis of Pyrrolidine-2-ones
0482
Functionalized Azides for the Synthesis of Pyrrolidin-2-ones and Pyrroles
0483
Copper-Mediated Synthesis of 3-Chloro-4-iodoisoxazoles

Synthesis of Materials and Unnatural Products

z485
All PDFs of this category
0485
Turning the Caterpillar Track
0486
Synthesis of Bis-perylene Bis-dendro Calix[4]arene, PDC
0487
π-Extended Hetrocycles via Cobalt-Catalyzed Directed C–H Activation
0488
Macrospirocyclic Oligomer via Friedel–Crafts Condensation
0489
Trendy Fullerenes
0490
Expand Your Carbo-Circles
0491
Silicon Fulleroid
0492
Bridging the Gap: Phosphaviologens Lower the Reduction Threshold in Viologen Systems
0493
C60-Fused Dihydrophenanthrenes via C–H Bond Activation
0494
N-Heterocyclic Carbenes IN 3D!
0495
Nitrogenated Holey Graphene
0496
Follow the Rhod to Dehydrogenative Coupling

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z497
All PDFs of this category
0497
Iron-Catalyzed Asymmetric Hydrosilation of 1,1-Disubstituted Alkenes
0498
Asymmetric Hydrogenation of Pyrimidines by Iridium Catalysis
0499
Ruthenium-Phosphoramide Hybrid Catalyst Enables Enantioselective Alkylations
0500
Copper-Catalyzed Enantioselective Propargylic Etherification
0501
Asymmetric Cross-Coupling of Aryl Halides with Epoxides
0502
Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds
0503
Palladium-Catalyzed Carboetherification of Allylic Amines Using an in Situ Tether
0504
Scandium-Catalyzed Asymmetric Aminative Dearomatization of 2-Naphthols
0505
Rhodium-Catalyzed Enantioselective [4+2+2] Cycloaddition
0506
Asymmetric [3+2] Cycloaddition of Isocyanoacetates with Ketones
0507
Diastereoselective Nickel-Catalyzed 1,4-Hydroboration of Chiral Dienols
0508
Asymmetric Vinylogous Mukaiyama Aldol Reaction via Indium Catalysis
0509
Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation
0510
Enantioselective Rhodium-Catalyzed Cyclization of Alkyne-Enoates
0511
Palladium-Catalyzed Hydroalkoxylation of Alkoxyallens
0512
Asymmetric Arylation of Allylic Sulfones upon Isomerization Conditions
0513
Asymmetric [4+2] Cycloaddition of Isochromene Acetals with Boronates
0514
Gold-Catalyzed Reactions of Two Diazo Compounds and Nitrosoarenes
0515
Asymmetric [2+2] Cycloadditions of Ynamides Catalyzed by Copper
0516
Enantioseletive Rhodium-Catalyzed Hydrogenation of Enamides
0517
Gold(I)-Catalyzed Asymmetric Hydroalkoxylation of Alkynes
0518
Palladium-Catalyzed Asymmetric [3+2] Cycloaddition
0519
Ru-Catalyzed Asymmetric Hydrogenation of Substituted 1,5-Naphthyridines
0520
Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids
0521
Enantioselective Synthesis of Dialkylated N-Heterocycles
0522
Enantioselective Palladium-Catalyzed N-Allylation of Indoles
0523
Highly Enantioselective Iron-Catalyzed Ketone Hydrosilylation
0524
Enantioselective Synthesis of Flavanones via Rhodium Catalysis

Metal-Mediated Synthesis

z525
All PDFs of this category
0525
Cadmium Iodide Mediated Allenylation
0526
Oxidative Cross-Coupling of Aryl Boronic Acids
0527
Direct Cross-Coupling of Organoaluminum Reagents
0528
Copper-Mediated Dehydrative Coupling of Azine N-Oxides and Oxazoles
0529
Cobalt-Promoted Dimerization of Aminoquinoline Benzamides
0530
Chemoselective Deboronative/Decarboxylative Alkenylation
0531
Alkyltrifluoroborates in Nickel/Photoredox Cross-Coupling
0532
Palladium-Catalyzed Arylborylation Using Chiral Anion Phase Transfer
0533
Copper-Catalyzed Coupling of Arylzirconium Reagents with Aryl Iodides
0534
Enantioselective Suzuki Cross-Coupling of 1-Fluoro-1-haloalkanes
0535
Nickel-Catalyzed Three-Component Domino Reactions
0536
Arylethenylphosphonates by Suzuki–Miyaura Cross-Coupling
0537
Mild and Selective Activation and Substitution of Strong Aliphatic C–F Bonds
0538
Catalytic Asymmetric Addition of Alkylzirconium Species to Enones
0539
Arylation of Sulfones from Sulfinic Acid Lithium, Magnesium, and Zinc Salts

Organo- and Biocatalysis

z541
All PDFs of this category
0541
Catalytic Asymmetric Diels–Alder Reaction of Quinone Imine Ketals
0542
Terpene Cyclization Catalyzed Inside a Self-Assembled Cavity
0543
Facile Access to β2-Amino Esters by NHC Catalysis
0544
Chiral Squaramide Catalyzed Benzyl Thiol Synthesis via ortho-Quinone Methides
0545
Intramolecular Desymmetrization of Cyclohexanones by Enamine Catalysis
0546
Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels–Alder Reaction
0547
Cooperative Wacker Oxidation and Enzymatic Reduction in a One-Pot Process
0548
Asymmetric Redox Cross Coupling of Ketones with Aryl Hydrazines
0549
Organocatalytic Oxo-Metathesis of Aldehydes
0550
Biocatalytic Synthesis of Amino Acids Bearing α-Quaternary Stereocenters
0551
Synthesis of d- and l-Phenylalanine Derivatives by Multienzymatic Cascade

Polymer-Supported Synthesis

z553
All PDFs of this category
0553
Oxidation of Propargylic Alcohols Using Copper NPs-CN
0554
The Suzuki–Miyaura Coupling with a Carbapalladacycle Nanocomposite
0555
Supported Library-Based Screening of Peptide Catalysts
0556
Synthesis of Enol Carbamates and Benzothiazoles with Fe3O4@EDTA–Cu(II)
0557
Flow Hydrogen Transfer Reactions with an Immobilized Iridium Catalyst
0558
Dehydrogenative Coupling of Hydrosilanes with Amines Using Au/HAP
0559
SPS of Glycopeptide Antibiotic Precursor Peptides
0560
Hydrogenolysis of Epoxides Using Pt/TiO2 under Photoirradiation
0561
A Gold/CeO2-Mediated Reaction of Amines, Dichloromethane, and Phenylacetylene
0562
C–H Alkoxylation and Halogenation Using Pd-Metalated UiO-66
0563
C–H Silylation and Borylation Using Ir/UiO-MOF
0564
Asymmetric Reduction of Ketones with Borane Using Supported BINOL
0565
Photocatalytic Aerobic Oxidation with BiOCl Colloidal Ultrathin Nanosheets
0566
Transfer Hydrogenation of Unsaturated Bonds with Co@C–N
0567
A Polymeric Hydantoin Auxiliary for the Asymmetric Mannich Reaction