Synfacts

Issue 05 · May 2015

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A60
Zanda, Matteo: SYNFORM ISSUE 2015/05 FREE ACCESS

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Asymmetric Syntheses of Megacerotonic Acid and Shimobashiric Acid A

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0454
Total Synthesis of Dictyodendrin B

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0455
Synthesis of a FLAP Inhibitor FREE ACCESS

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0456
Synthesis of an Aurora Kinase B Inhibitor

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0457
Synthesis of Aeruginosin Natural Products FREE ACCESS

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0458
Synthesis of Indolo-Phakellins

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0459
Synthesis of Telmisartan

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0460
Synthesis of Alkaloid (–)-205B

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0461
Total Synthesis of (+)-Brefeldin A

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0462
Synthesis (S)-RO4999200

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0463
Synthesis of trans-Clerodane Natural Products

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0464
Synthesis of (+)-Rugulotrosin A

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0465
Synthesis of Bimatoprost

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0466
Formal Synthesis of Atorvastatin

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0467
Synthesis of GSK1265744

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Synthesis of Heterocycles
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0469
Modular Assembly of Imidazoles by 1,3-Dipolar Cycloaddition

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0470
Construction of Aza/Oxa-Spirocyclic Skeletons. Formal Synthesis of (±)-Halichlorine FREE ACCESS

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0471
Polycyclic Spiroindolines from Asymmetric Dearomatization of Indoles

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0472
1,4-Benzothiazines by Copper-Catalyzed Ring Expansion of Benzothiazoles

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0473
Synthesis of Dibenzothiazepine Dioxides by Reductive Heck Cyclization

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0474
Synthesis of Pyrroles and Dihydropyrazines from Azirines and 1,2,3-Triazoles

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0475
One-Pot Cycloaddition–Strecker Cascade to Imidazo[1,2-a]heterocycles

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0476
Triﬂuoromethylthiolation of Indoles

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0477
Synthesis of F₅C₂-Substituted Pyrazoles

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0478
Carbonylated Benzofurans by Metal-Free Radical Cyclizations of 1,6-Enynes

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0479
Synthesis of Substituted Pyrroles and 1,2-Oxazinanes

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0480
An Unexpected Route to Pyrrolo[2,3-c]pyridazin-6-ones

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0481
A Photoredox Approach for the Synthesis of Pyrrolidine-2-ones

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0482
Functionalized Azides for the Synthesis of Pyrrolidin-2-ones and Pyrroles

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0483
Copper-Mediated Synthesis of 3-Chloro-4-iodoisoxazoles

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Synthesis of Materials and Unnatural Products
z485
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0485
Turning the Caterpillar Track FREE ACCESS

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0486
Synthesis of Bis-perylene Bis-dendro Calix[4]arene, PDC

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0487
π-Extended Hetrocycles via Cobalt-Catalyzed Directed C–H Activation

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0488
Macrospirocyclic Oligomer via Friedel–Crafts Condensation

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0489
Trendy Fullerenes

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0490
Expand Your Carbo-Circles

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0491
Silicon Fulleroid

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0492
Bridging the Gap: Phosphaviologens Lower the Reduction Threshold in Viologen Systems

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0493
C₆₀-Fused Dihydrophenanthrenes via C–H Bond Activation

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0494
N-Heterocyclic Carbenes IN 3D!

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0495
Nitrogenated Holey Graphene

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0496
Follow the Rhod to Dehydrogenative Coupling

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z497
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0497
Iron-Catalyzed Asymmetric Hydrosilation of 1,1-Disubstituted Alkenes FREE ACCESS

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0498
Asymmetric Hydrogenation of Pyrimidines by Iridium Catalysis

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0499
Ruthenium-Phosphoramide Hybrid Catalyst Enables Enantioselective Alkylations

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0500
Copper-Catalyzed Enantioselective Propargylic Etherification

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0501
Asymmetric Cross-Coupling of Aryl Halides with Epoxides

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0502
Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds

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0503
Palladium-Catalyzed Carboetherification of Allylic Amines Using an in Situ Tether

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0504
Scandium-Catalyzed Asymmetric Aminative Dearomatization of 2-Naphthols

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0505
Rhodium-Catalyzed Enantioselective [4+2+2] Cycloaddition

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0506
Asymmetric [3+2] Cycloaddition of Isocyanoacetates with Ketones

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0507
Diastereoselective Nickel-Catalyzed 1,4-Hydroboration of Chiral Dienols

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0508
Asymmetric Vinylogous Mukaiyama Aldol Reaction via Indium Catalysis

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0509
Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation

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0510
Enantioselective Rhodium-Catalyzed Cyclization of Alkyne-Enoates

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0511
Palladium-Catalyzed Hydroalkoxylation of Alkoxyallens

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0512
Asymmetric Arylation of Allylic Sulfones upon Isomerization Conditions

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0513
Asymmetric [4+2] Cycloaddition of Isochromene Acetals with Boronates FREE ACCESS

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0514
Gold-Catalyzed Reactions of Two Diazo Compounds and Nitrosoarenes

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0515
Asymmetric [2+2] Cycloadditions of Ynamides Catalyzed by Copper

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0516
Enantioseletive Rhodium-Catalyzed Hydrogenation of Enamides

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0517
Gold(I)-Catalyzed Asymmetric Hydroalkoxylation of Alkynes

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0518
Palladium-Catalyzed Asymmetric [3+2] Cycloaddition

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0519
Ru-Catalyzed Asymmetric Hydrogenation of Substituted 1,5-Naphthyridines

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0520
Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids

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0521
Enantioselective Synthesis of Dialkylated N-Heterocycles

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0522
Enantioselective Palladium-Catalyzed N-Allylation of Indoles

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0523
Highly Enantioselective Iron-Catalyzed Ketone Hydrosilylation

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0524
Enantioselective Synthesis of Flavanones via Rhodium Catalysis

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Metal-Mediated Synthesis
z525
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0525
Cadmium Iodide Mediated Allenylation

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0526
Oxidative Cross-Coupling of Aryl Boronic Acids

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0527
Direct Cross-Coupling of Organoaluminum Reagents FREE ACCESS

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0528
Copper-Mediated Dehydrative Coupling of Azine N-Oxides and Oxazoles

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0529
Cobalt-Promoted Dimerization of Aminoquinoline Benzamides

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0530
Chemoselective Deboronative/Decarboxylative Alkenylation

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0531
Alkyltrifluoroborates in Nickel/Photoredox Cross-Coupling

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0532
Palladium-Catalyzed Arylborylation Using Chiral Anion Phase Transfer

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0533
Copper-Catalyzed Coupling of Arylzirconium Reagents with Aryl Iodides

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0534
Enantioselective Suzuki Cross-Coupling of 1-Fluoro-1-haloalkanes

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0535
Nickel-Catalyzed Three-Component Domino Reactions

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0536
Arylethenylphosphonates by Suzuki–Miyaura Cross-Coupling

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0537
Mild and Selective Activation and Substitution of Strong Aliphatic C–F Bonds

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0538
Catalytic Asymmetric Addition of Alkylzirconium Species to Enones

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0539
Arylation of Sulfones from Sulfinic Acid Lithium, Magnesium, and Zinc Salts

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Organo- and Biocatalysis
z541
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0541
Catalytic Asymmetric Diels–Alder Reaction of Quinone Imine Ketals

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0542
Terpene Cyclization Catalyzed Inside a Self-Assembled Cavity

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0543
Facile Access to β²-Amino Esters by NHC Catalysis FREE ACCESS

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0544
Chiral Squaramide Catalyzed Benzyl Thiol Synthesis via ortho-Quinone Methides

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0545
Intramolecular Desymmetrization of Cyclohexanones by Enamine Catalysis

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0546
Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels–Alder Reaction

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0547
Cooperative Wacker Oxidation and Enzymatic Reduction in a One-Pot Process

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0548
Asymmetric Redox Cross Coupling of Ketones with Aryl Hydrazines

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0549
Organocatalytic Oxo-Metathesis of Aldehydes

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0550
Biocatalytic Synthesis of Amino Acids Bearing α-Quaternary Stereocenters

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0551
Synthesis of d- and l-Phenylalanine Derivatives by Multienzymatic Cascade

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Polymer-Supported Synthesis
z553
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0553
Oxidation of Propargylic Alcohols Using Copper NPs-CN

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0554
The Suzuki–Miyaura Coupling with a Carbapalladacycle Nanocomposite

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0555
Supported Library-Based Screening of Peptide Catalysts FREE ACCESS

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0556
Synthesis of Enol Carbamates and Benzothiazoles with Fe₃O₄@EDTA–Cu(II)

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0557
Flow Hydrogen Transfer Reactions with an Immobilized Iridium Catalyst

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0558
Dehydrogenative Coupling of Hydrosilanes with Amines Using Au/HAP

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0559
SPS of Glycopeptide Antibiotic Precursor Peptides

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0560
Hydrogenolysis of Epoxides Using Pt/TiO₂ under Photoirradiation

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0561
A Gold/CeO₂-Mediated Reaction of Amines, Dichloromethane, and Phenylacetylene

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0562
C–H Alkoxylation and Halogenation Using Pd-Metalated UiO-66

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0563
C–H Silylation and Borylation Using Ir/UiO-MOF

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0564
Asymmetric Reduction of Ketones with Borane Using Supported BINOL

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0565
Photocatalytic Aerobic Oxidation with BiOCl Colloidal Ultrathin Nanosheets

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0566
Transfer Hydrogenation of Unsaturated Bonds with Co@C–N

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0567
A Polymeric Hydantoin Auxiliary for the Asymmetric Mannich Reaction

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