Synfacts
Issue 07 · July 2015
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A90
Zanda, Matteo:
SYNFORM
ISSUE 2015/07
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Synthesis of Natural Products and Potential Drugs
z677
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0677
Synthesis of Glucagon Receptor Antagonist LY2409021
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0678
Total Synthesis of Paspaline
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0679
Synthesis of Diterpenoid Steenkrotin A
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0680
Synthesis of Aliskiren
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0681
Synthesis of DZ-2384
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0682
Total Synthesis of Santalin Y
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0683
Synthesis of
rac
-Efavirenz
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0684
Formal Synthesis of Telaprevir
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0685
Synthesis of 5,6-Dihydrocineromycin B
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0686
Synthesis of Mycoleptodiscin A
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0687
Synthesis of (+)-Muironolide A
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0688
Total Synthesis of (–)-Galanthamine and (–)-Lycoramine
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0689
Synthesis of a BACE1 Inhibitor
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Synthesis of Heterocycles
z691
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0691
Rhodium(III)-Catalyzed Synthesis of 1,2-Benzothiazines
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0692
Enantioselective Copper(I)-Catalyzed Construction of Spiroketals
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0693
6-
endo
-dig versus 5-
exo
-dig. The Profound Effects of Acetonitrile
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0694
Synthesis of Dihydropyridin-2-ones via an Ugi–Aldol Reaction
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0695
Minisci-Type Synthesis of Tetrahydropyridopyridazines
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0696
Single-Step Synthesis of Isoindolinones
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0697
Synthesis of Fluorinated Diphenylpyrazole
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0698
Four New Bonds in One Pot: Isoxazolines from Olefins and 2-Ethylquinolines
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0699
Pyrido[2,3-
c
]coumarins via an Intramolecular Povarov Reaction
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0700
Synthesis of 1,2-Borazaronaphthalenes
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0701
Benzyne Route to Benzothiazoles
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0702
Copper-Catalyzed Oxidative Annulation Approach to Oxadiazoles
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0703
Enamide Umpolung for the Synthesis of Heterocycles
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0704
Oxabicycles via Sequential Prins–Wagner–Ritter Processes
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0705
Synthesis of Hexahydropyrano[3,4-
c
]chromenes via Prins Bicyclization
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Synthesis of Materials and Unnatural Products
z707
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0707
Hexaaza Macrocycles Revisited
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0708
Nestable Tetrakis(spiroborate) Nanocycles
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0709
Circulene Flow
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0710
A Mild Route to Quinoxalines Featuring Iodine
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0711
Tiny Molecule, Big Fluorescence
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0712
Synthesis of 2,5-Disubstituted Thiazoles
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0713
Phospholify and Diversify
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0714
Pitched Propeller PAHs
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0715
Bowled Over! Nitrogen Takes Center Stage from Carbon in Azacorannulenes
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0716
A Polymerization Displaying Great Tact
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0717
Incorporating More Nitrogen Atoms in Hexacenes
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0718
A Molecular Spring
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z719
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0719
Copper Hydride Catalyzed Synthesis of 2,3-Disubstituted Indolines
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0720
Asymmetric Haloaminocyclization for the Synthesis of Cyclic Sulfamates
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0721
Rhodium-Catalyzed Asymmetric Dearomatization of Naphthols with Alkynes
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0722
Synthesis of Indanes and Indanones through Tandem Catalysis
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0723
Iridium-Catalyzed Branched-Selective Hydroarylation of Vinyl Ethers
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0724
Iridium-Catalyzed Asymmetric Hydrogenation of Ketones in Ethanol
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0725
Gold-Catalyzed [2+2+2] of Allenamides, Alkenes and Aldehydes
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0726
Catalytic Stereoselective Reaction of β-Lactams with Aldehydes
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0727
Palladium-Catalyzed Enantioselective Reductive Heck Reactions
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0728
Palladium- and Chiral Phosphoric Amide/Acid-Catalyzed C–H Arylation
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0729
Enantioselective Allylic Alkylation of Ortho-Substituted Cinnamyl Bromides
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0730
Enantioselective Synthesis of α-Trifluoromethylamines
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0731
Iron-Catalyzed
Z
-Selective Olefin Synthesis
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0732
Asymmetric Transfer Hydrogenation of Ketones by Macrocyclic Iron Complexes
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0733
Addition of Allenes to Fluorinated Alcohols Catalyzed by Ruthenium
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0734
Iridium-Catalyzed Intramolecular Asymmetric C–H Alkylations
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0735
Zirconium-Catalyzed Asymmetric Hydroamination of Primary Aminoalkenes
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0736
Enantioselective Scandium-Catalyzed 1,6-Addition of Oxindoles
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0737
Synthesis of 3-Tetrasubstituted Oxindoles by Using a Chiral Calcium Catalyst
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0738
Enantioselective Copper-Catalyzed Synthesis of Dispiropyrrolidines
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0739
Copper-Catalyzed Synthesis of CF
3
-Substituted Oxazolines
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0740
Asymmetric Mannich-Type Reaction of Ketimines and Aminoacetonitriles
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0741
Formylation of Allylic Carbonates with Formaldehyde
N
,
N
-Dialkylhydrazones
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0742
Asymmetric Transfer Hydrogenation by Means of Nickel Catalysis
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0743
Diastereoselective Synthesis of
cis
-β-Fluorocyclopropane Carboxylates
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0744
Catalytic Synthesis of Vinylcyclopropanes by Intramolecular Cyclopropanation
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0745
Ring Enlargement of Alkynyl Donor–Acceptor Cyclopropanes
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0746
Palladium-Catalyzed Dynamic Kinetic Asymmetric Spiroannulation
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Metal-Mediated Synthesis
z747
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0747
Rhodium-Catalyzed Asymmetric Cyclopropylation
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0748
Gallium-Promoted Halocyclization
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0749
Cobalt-Catalyzed Hydroboration of Alkynes
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0750
Synthesis of Fluoren-9-ones via Carbonylative C–C Bond Formation
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0751
Asymmetric Addition of Arylboronic Acids to Nitrostyrenes
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0752
1,4-Hydroboration of Pyridines
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0753
Synthesis of Vinyl Boronates
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0754
Iron(II)-Mediated C–N Bond Formation Towards 2-Aminothiazoles
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0755
Asymetric Nickel-Catalyzed Synthesis of Azetidines and Aziridines
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0756
Carbolithiation of Heterosubstituted Alkynes
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0757
Copper-Mediated Radical Trifluoromethylation
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0758
Trifluoromethylation of Substituted Arenes and Heteroarenes
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0759
Copper-Mediated Cyclization Approach to 3
H
- and 1
H
-Indoles
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0760
Desymmetrization of 1,1-Diborylalkanes via Suzuki–Miyaura Cross-Coupling
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0761
Grignard Addition to Aldimino Esters
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Organo- and Biocatalysis
z763
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0763
Enantioselective Intramolecular Aza-Diels–Alder Reactions
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0764
A Mild Neutral Silicon Lewis Acid for Hydro- and Cyanosilylations
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0765
Radical Alkylation of Aldehydes via Asymmetric Photo-Organocatalysis
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0766
Organocatalytic CO
2
Trapping Using Alkynyl Indoles
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0767
NHC-Catalyzed Benzannulation via 1,6-Addition to Conjugated Dienals
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0768
Quaternary Stereocenters via NHC-Catalyzed Sulfa-Michael Addition
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0769
Desymmetrizing Michael Reactions via Enol Catalysis
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0770
Facile Net Cycloaddition Approach to Optically Active 1,5-Benzothiazepines
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Polymer-Supported Synthesis
z771
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0771
Silica-Supported Iridium Complex Catalyst for Asymmetric Allylic Amination
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0772
C–P Bond Formation Catalyzed by a Magnetic Nanoparticle-Supported Palladium Catalyst
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0773
A Cellulose-Supported DNA-Based Ligand for Asymmetric Catalysis
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0774
Cross-Coupling of Iodides with Nucleophiles by Using Copper Clusters
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0775
Aerial Oxidation of Alcohols on a Silica–γ-Iron(III) Oxide Supported Palladium Complex
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0776
Dendrimer-Encapsulated Palladium Nanoparticles for Flow Cross-Couplings
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0777
Aerobic Oxidation of Alcohols with Gold–Platinum/Polystyrene Nanoparticles
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0778
Deoxygenation of Carbonyls by Poly(methylhydrosiloxane) on Palladium/Carbon
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0779
Gold Nanoparticle Promoted Cycloisomerization of Alkynoic Acids
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0780
Huisgen Cycloaddition on a Polymer-Supported Copper Catalyst
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0781
Well-Defined Adenosine Diphosphate Ribose Oligomers
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0782
Double Carbonylation of Aryl Iodides with Amines on Palladium Nanoparticles
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0783
Dehydrogenation of Alcohols to Carboxylic Acids on Palladium/Carbon
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0784
Ruthenium-Catalyzed Oxidative Decarboxylation of Amino Acids
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0785
C–O and C–X Bond-Forming Reactions with Pd(II)/MWCNT
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