DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 12 · November 2016 DOI: 10.1055/s-006-32688

Synform

A160
Zanda, Matteo: SYNFORM ISSUE 2016/11

Synthesis of Natural Products and Potential Drugs

z1113
All PDFs of this category
1113
Total Synthesis of (+)-Peganumine A
1114
Synthesis of Doravirine
1115
Synthesis of (R)-Sitagliptin
1116
Total Synthesis of (+)-Aplydactone
1117
Synthesis of (–)-Spinosyn A
1118
Synthesis of an Inhibitor of Blood Coagulation Factor VIIa–Tissue Factor Complex
1119
Syntheses of Cochlearenine, N-Ethyl-1α-hydroxy-17-veratroyldictyzine, and Paniculamine
1120
Synthesis of (+)-Harringtonolide
1121
Total Synthesis of (–)-Lycopodine
1122
Synthesis of an EGFR Inhibitor
1123
Syntheses of Aspidosperma Alkaloids
1124
Synthesis of a PI3VIIδ Inhibitor via Alkyne Cyclotrimerization

Synthesis of Heterocycles

z1125
All PDFs of this category
1125
Isochromanone Synthesis by NHC-Catalyzed Annulation of o-Quinodimethanes
1126
Cobalt(III)-Catalyzed Synthesis of Quina-zolines from Benzimidates and Dioxazolones
1127
Nitro Epoxide Based Synthesis of Morpholines and Benzoxazines
1128
Copper-Catalyzed Synthesis of Isoxazoles from Nitroalkanes and Alkynes
1129
Palladium-Catalyzed Synthesis of Quinazolinone-Fused Phenanthridines
1130
Selective sp2–sp3 Suzuki–Miyaura Coupling of Heteroaryl Chlorides
1131
Gold-Catalyzed Synthesis of Imidazolidines and Tetrahydro-1H-1,3-diazepines
1132
Lewis Acid Catalyzed Synthesis of Azepines from Oxiranes and Alkynes
1133
Synthesis of Indolizidine Lactams by Reductive Cyclization of Cyclic Imides
1134
Synthesis of 1-Aryl-1,2,3,4-tetrahydroiso-quinolines via Aryne Intermediates
1135
Copper-Catalyzed Synthesis of Benzofuran[3,2-c]quinolin-6[5H]-ones
1136
Synthesis of Hetaryluracils
1137
Asymmetric Synthesis of Pyrrolizines
1138
Photocatalytic Synthesis of (Trifluoromethyl)phenanthridines

Synthesis of Materials and Unnatural Products

z1139
All PDFs of this category
1139
Overcrowded Quinonoids
1140
Four-State Nanoswitch Controls Two-Step Sequential Catalysis
1141
Nanohoop through Anthracene Photodimerization–Cycloreversion
1142
Biradicals Celebrate Reunion
1143
Alkenyl Boronic Esters
1144
Thienannulating Polycyclic Aromatic Hydrocarbons
1145
Stereo- and Temporally Controlled Coordination Polymerization
1146
Stable Porphyrin Radical Cations
1147
A Game with Gold Carbene Intermediates
1148
Power of Steric Effects in Oxidative Cyclizations
1149
Novel Heptathienoacenes with Bull’s Horn and Linear Shapes
1150
A Practical and Efficient Route to Cyclopenta[l]phenanthrenes

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1151
All PDFs of this category
1151
Chromium-Catalyzed Asymmetric Allylation
1152
Nickel-Catalyzed Stereospecific Borylation
1153
Enantio- and Diastereoselective α-Allylation
1154
Asymmetric Synthesis of Substituted Glutarimides by Ytterbium Catalysis
1155
Stereoselective Transfer Hydrogenation of α-Amino β-Keto Esters
1156
Use of a Chiral-at-Metal Rhodium Complex in the Alkynylation of 2-C(O)CF3Imidazoles
1157
Copper-Catalyzed Asymmetric Styrene–Imine Coupling
1158
Copper-Catalyzed Asymmetric Synthesis of 2-Carboxytetrahydroquinolines
1159
Enantioselective Rhodium(II)-Catalyzed [3+2] Annulation
1160
Stereoselective Rhodium(III)-Catalyzed Allylation of Arenes
1161
Iridium-Catalyzed Asymmetric Allylic Substitution Reactions
1162
Synthesis of Indolines and Isochromans by a Palladium-Catalyzed Domino Reaction
1163
Copper-Catalyzed Asymmetric Synthesis of Tetrahydroquinolines
1164
Ruthenium-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles
1165
Copper-Catalyzed Asymmetric Propargylation of Indoles and Pyrroles
1166
Copper-Catalyzed Decarboxylative Mannich Reaction of Malonic Half Esters
1167
Asymmetric Allylation of Aryloxindoles by Palladium/Hydrogen-Bonding Dual Catalysis
1168
Copper-Catalyzed Enantioselective Allylic Arylation Forming Quaternary Stereocenters
1169
Asymmetric Hydrogenation of α,β-Unsaturated Acylpyrazoles
1170
Asymmetric Hydrogenation of Maleimides with a Rh/Bisphosphine–Thiourea Catalyst
1171
Asymmetric Hydrogenation of Nonsymmetric Benzophenones
1172
Rhodium/Copper-Catalyzed Stereoselective Synthesis of Cyclopenta[b]indoles
1173
Enantioselective Synthesis of Fluorinated Propargylamines
1174
Rhodium-Catalyzed Regioselective Hydrothiolation Reaction
1175
Nickel-Catalyzed Stereospecific Cross-Coupling Reaction
1176
Enantioselective Hydrogenation of Azaindoles
1177
Palladium-Catalyzed Diastereo- and Enantioselective [3+2] Cycloaddition

Metal-Mediated Synthesis

z1179
All PDFs of this category
1179
Palladium-Catalyzed Suzuki–Miyaura Coupling of N-Acylsaccharins by N–C Cleavage
1180
Palladium-Catalyzed Three-Component Synthesis of Arylglycines
1181
Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids
1182
Iron-Catalyzed C–C Coupling with Redox-Active Esters
1183
Cross-Coupling of Arylboronic Acids with DAST-Type Reagents
1184
Ring Opening of Oxabenzonorbornadienes
1185
BF3·OEt2-Mediated Cross-Coupling
1186
Ligand-Controlled Copper-Catalyzed Boration of Unactivated Alkynes
1187
Ethylmagnesiation Reaction of Cyclobutenes
1188
Arylboration of 1-Arylalkenes
1189
Decarbonylative Silylation of Esters
1190
Synthesis of 2-Phenyl-2-sulfanylethyl Tertiary Amines
1191
Dehydrogenative Borylation of Terminal Alkynes
1192
Copper-Mediated Fluorination
1193
Thio-Passerini Thiophthalide Synthesis

Organo- and Biocatalysis

z1195
All PDFs of this category
1195
Novel Pyridoxamines for Enantioselective Biomimetic Transamination
1196
Asymmetric Synthesis by Pathway Engineering of an Enzymatic Cascade
1197
Kilogram-Scale Enzymatic Resolution of 1-Methyl 4-tert-Butyl 2-Propylsuccinate
1198
Carboxylic Acid Modified BINOL Phosphate Catalysis
1199
Phosphine-Catalyzed Domino Annulations of Allenoates and Ketimines
1200
Catalytic Enantioselective Dearomatization of Pyridines with C-4 Selectivity
1201
Catalytic Site- and Enantioselective Aldolizations of Diketones and Aldehydes
1202
NHC-Catalyzed Enantioselective Tropane Synthesis
1203
The Cope Rearrangement via Iminium Catalysis
1204
Catalytic Asymmetric Prins Cyclization

Polymer-Supported Synthesis

z1205
All PDFs of this category
1205
Synthesis of Chiral β-Lactones by Catalytic Hydrogenation of Ketene Dimers
1206
Polystyrene-Supported Zinc/Imidazole Catalyst for Transesterifications
1207
Shape-Selective Mesoporous Silicalite-Encapsulated Palladium Catalyst
1208
Suzuki and Hydrogenation Reactions on Magnetite-Supported Pd Nanoparticles
1209
Copper Nanoparticle Catalyzed Borylation of α,β-Unsaturated Ketones
1210
Supported Au–Pd Nanoparticle Catalyst for Aerobic Oxidative Dehydrogenation
1211
Chiral Polymers for Enantioselective Alcoholysis of Cyclic Anhydrides
1212
Oxidative Dehydrogenation of Alcohols with Metal Oxides on N-Doped Carbon
1213
Synthesis of Nitriles from Aldehydes on Ferrite Nanoparticles
1214
Zwitterionic Metal–Organic Frameworks for Lewis Acid Catalysis
1215
Synthesis of 2-Thiohydantoins with a Silica-Supported Organocatalyst
1216
Three-Component Coupling on a Pd(II)–Pb(II) Bimetallic Metal–Organic Framework
1217
Transformation of Aryl Halides into Benzyl Alcohols with Pd NPs on N-Doped Carbon
1218
Zirconium Metal–Organic Framework-Assisted Rhodium or Iridium Catalysis
1219
Hydration of Terminal Alkynes by Using Zeolite Y Nanoparticles
1220
Kumada and Negishi Cross-Coupling on Gold-Supported Nickel Nanoparticles
1221
Oxidative Amidation of Aromatic Aldehydes on Silver/Graphitic Carbon Nitride

Erratum

1222
Miaskiewicz, S.; Gaillard, B.; Kern, N.; Weibel, J.-M.; Pale, P.; Blanc, A: Synthesis of Azabicycloalkanes by Gold(I)-Catalyzed Amination of Ynones
1222
Jo, W.; Kim, J.; Choi, S.; Cho, S. H.: C2-Alkylation of Pyridine N-Oxides with 1,1-Diborylalkanes