DOI: 10.1055/s-00000131

Synfacts

Issue 04 · Volume 13 · April 2017 DOI: 10.1055/s-007-33623

Synform

A57
Zanda, Matteo: SYNFORM ISSUE 2017/04

Synthesis of Natural Products and Potential Drugs

z0335
All PDFs of this category
0335
Synthesis of the Bicyclic Darunavir Side Chain
0336
Synthesis of c-Met/ALK Inhibitor HS-10168
0337
Total Synthesis of Zaragozic Acid C
0338
Synthesis of Abacavir by Enantioselective Hydroamination
0339
Synthesis of Vortioxetine via Catalyst-Free N-Arylation
0340
Total Synthesis of (±)-Andirolide N
0341
Synthesis of (−)-Tetrodotoxin and its Congeners
0342
Syntheses of Secu’amamine E and Allosecurinine
0343
Synthesis of (3R,3aS,6aR)-Hexahydrofuro-[2,3-b]furan-3-ol
0344
Enantioselective Sulfa-Michael Reactions
0345
Synthesis of (–)-Sinoracutine
0346
Synthesis of Eravacycline
0347
Synthesis of (–)-Stemaphylline

Synthesis of Heterocycles

z0349
All PDFs of this category
0349
Thioketones in an Asymmetric Thia-Diels–Alder Reaction
0350
Iron-Mediated Synthesis of Pyrroles, Pyrrolines, and Imidazolines
0351
1,3-Dioxane Synthesis by Catalytic Prins Reaction
0352
Synthesis of Morpholines and Piperazines by an Ugi Multicomponent Reaction
0353
Diverse Heterocycles by Pd-Catalyzed Cyclization of Unsaturated N-Sulfonylamides
0354
Rhodium-Catalyzed Synthesis of 1,2,4-Triazines
0355
Reversed Regiochemistry in Halo-lactonizations of Olefins to Lactones
0356
Asymmetric Paal–Knorr Pyrrole Synthesis
0357
Asymmetric α-Arylation of Thioamides
0358
Lewis Acid Catalyzed Synthesis of Azidocyclopentane and Tetrahydropyridines
0359
Synthesis of Pyrroloisoxazole-Based Ring Systems
0360
Silver-Catalyzed Synthesis of Trifluoromethylated Heterocycles
0361
Enantioselective [2+2] Cycloaddition of N-Allenamides with N-Sulfonylketimines
0362
Aza Analogues of Benzyl Isoquinoline Alkaloids

Synthesis of Materials and Unnatural Products

z0363
All PDFs of this category
0363
Triangular Donor–Acceptor Systems
0364
‘I’s for Peptides
0365
Decarboxylative Macrocyclization of Peptides
0366
Phenylene-Containing Polycyclic Conjugated Hydrocarbons
0367
New Negative Dielectric Liquid Crystals with CF2CF2 Brothers
0368
Welcome Benzopicenes to the Family of [2+2+2] Cycloaddition Products
0369
Photochromic Torsional Switch
0370
More Nitrogen in the Pi
0371
Ways (to) N-Confused
0372
Disulfide-Catalyzed Oxidative Cleavage of Olefins
0373
When Dithioles Met Diimides: New Electron-Accepting Materials
0374
Polycyclic Pentalenes with Enhanced Antiaromaticity

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z0375
All PDFs of this category
0375
Cobalt-Catalyzed Enantio- and Diastereoselective Hydroacylation Reaction
0376
Stereodivergent Coupling with Synergistic Catalysis
0377
Synergistic Iridium and Lewis Base Catalyzed Stereodivergent Allylic Substitutions
0378
Nickel-Catalyzed Enantioselective Synthesis of Cyclic Amines from Imines
0379
Asymmetric Rhodium-Catalyzed Hydrogenation Generating Benzodiazepines
0380
Iridium-Catalyzed Asymmetric Synthesis of Spirocyclic Indolines
0381
Rhodium-Catalyzed Asymmetric Construction of Chiral Tetraorganosilanes
0382
Palladium-Catalyzed Formal [5+4] and [3+2] Cycloaddition
0383
Enantioselective Allylic Alkylation of Fluoroenolates
0384
Enantioselective Hydrogenation of Amides by Dynamic Kinetic Resolution
0385
Asymmetric Rhodium/Zinc-Catalyzed Ring Opening of Oxabicycles with Carboxylic Acids
0386
Rhodium-Catalyzed Hydrogenation of Tetrasubstituted Cyclic Enamides
0387
Gold-Catalyzed Stereoselective Synthesis of Methylene Oxindoles
0388
Copper-Catalyzed Umpolung Synthesis of Chiral Aldimines and Aldehydes
0389
Lanthanide-Catalyzed Asymmetric Bisvinylogous Mukaiyama Aldol Reactions
0390
Acid-Assisted Ruthenium-Catalyzed Asymmetric Amination of Diols
0391
Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
0392
Chromium-Catalyzed Dearomatization of Naphthalenes to Aldehydes
0393
Asymmetric Decarboxlyative Allylic Alkylation of Sterically Hindered Lactones
0394
Rhodium-Catalyzed Aromatic C–H Functionalization of α-Phenoxy Ketones
0395
Enantioselective Oxidative Ring Opening of Aziridines
0396
Silver-Catalyzed Asymmetric Aminolysis of N-Tosylaziridines
0397
Iridium-Catalyzed Asymmetric Hydrogenation of Pyrazines
0398
Nickel Complex Photocatalyzed Enantioselective Oxidation of β-Keto Esters
0399
Rhodium-Catalyzed Asymmetric Synthesis of Amides
0400
Nickel Hydride Catalyzed Selective 1,2-Reduction of α,β-Unsaturated Ketones
0401
Enantioselective Zirconium-Catalyzed α-Hydroxylation of β-Keto Esters
0402
Asymmetric Arylboration of Aralkenes

Metal-Mediated Synthesis

z0403
All PDFs of this category
0403
Heteroarylation of 2-Trifluoroborato-chromanones
0404
Redox-Neutral Alkylation of Imines through Organic Photocatalysis
0405
Synthesis and Application of Dichloro-methyllithium in Continuous Flow
0406
Selective Monoarylation of Aromatic Ketones and Esters
0407
Rhodium-Catalyzed Decarbonylative Borylation
0408
Photocatalytical Radical Deboronative Alkylation of Pyridine N-Oxides
0409
Asymmetric 1,2-Addition of Aldimines and Ketimines with Arylboroxines
0410
Copper-Catalyzed CO2 Insertion
0411
Copper-Catalyzed Carboboration of Alkenes
0412
Synthesis of Substituted Borazaro-naphthalenes
0413
Catalytic Enantioselective Alkylation of Enolizable N-Sulfonyl Ketimines
0414
Silole Synthesis Promoted by DIBAL-H
0415
C–H Bond Alkynylation of Heteroarenes
0416
FeCl2-Catalyzed Boration
0417
Copper-Mediated Radiofluorination

Organo- and Biocatalysis

z0419
All PDFs of this category
0419
Kinetic Resolution of Primary Amines through Chiral Phosphoric Acid Catalysis
0420
Stereospecific Glycosylation through Catalytic Stereoinversion
0421
Photoredox Activation of Carbon Dioxide in an α-Amino Acid Synthesis
0422
A Novel Baeyer–Villiger Monooxygenase for Bulky Substrates
0423
Enantioselective Synthesis of Chiral Oxime Ethers
0424
A Diazaphospholene Precatalyst for Imine and Conjugate Reductions
0425
Catalytic Regio- and Enantioselective [6+2], [4+2], and [2+2] Cycloadditions
0426
Catalytic Asymmetric Synthesis of Atropisomeric Biaryls
0427
Enamine and Iminium Catalysis with an Evolved Carboligase
0428
Synthesis of Furan Atropisomers by Central-to-Axial Chirality Conversion

Polymer-Supported Synthesis

z0429
All PDFs of this category
0429
Chiral Polymer Stabilized Bimetallic Nanocatalysts for Asymmetric Oxidations
0430
Copper-Free Sonogashira Coupling with Palladium Nanoparticles
0431
Condensation of Amines Catalyzed by a Fe3O4-Supported Sulfonic Acid
0432
Palladium/Titania-Photocatalyzed Reactions of Allylbenzenes
0433
Aerobic Photocatalytic Oxidation of Olefins on a TiO2–Co–Ascorbic Acid Nanohybrid
0434
Heterogeneous Copper-Catalyzed Halodeboronation of Arylboronic Acids
0435
Coupling Reactions on Aluminum Hydroxide-Supported Palladium Nanoparticles
0436
Aerobic Benzylic C–H Oxidation on Core–Shell Copper-Based Nanoparticles
0437
Base-Resistant Metal–Organic Framework Catalyzed Halogenation of Cycloalkanes
0438
Kabachnik–Fields Reaction on a Sulfated Polyborate
0439
C–H Bromination of 6-Phenylpurines with a Silica-Supported Ruthenium Catalyst
0440
Ferrite-Based Composite Catalyst for Aerobic Oxidation of Alcohols
0441
1,1′:4′,1′′-Terphenyl-4-ols by a Pd/C-Catalyzed Suzuki–Miyaura Reaction
0442
Copper Hydrogel Catalyzed Huisgen Reaction and Cycloaddition of CO2 to Epoxides
0443
N-Aryl Hydroxamic Acids by Continuous-Flow Hydrogenation
0444
Zeolite-Catalyzed Continuous Flow Diels–Alder Reactions
0445
Cobalt-Catalyzed Controllable Transfer Hydrogenations of Nitriles
0446
α-Ferric Oxide/Graphene Oxide-Catalyzed Suzuki–Miyaura Coupling

Erratum

447
Akula, R.; Guiry, J.: Asymmetric Allylic Alkylation Towards Dihydrocoumarins and Isochromanones