Synfacts

Issue 08 · August 2018

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A117
Zanda, Matteo: SYNFORM ISSUE 2018/08 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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Synthesis of PF-06751979 FREE ACCESS

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0776
Synthesis of Shld

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Total Synthesis of (+)-Hosieine A FREE ACCESS

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0778
Synthesis of Silanediol FXIa Inhibitors

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Synthesis of (+)-Belizentrin Methyl Ester

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0780
Synthesis of HIV-1 Protease Inhibitors

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0781
Total Synthesis of (–)-Quinine

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0782
Synthesis of EPZ015666

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0783
Synthesis of Fluorinated BACE Inhibitors

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0784
Formal Synthesis of (+)-Kibdelone C

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0785
Total Synthesis of (–)-17-nor-Excelsinidine

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0786
Synthesis of Pitavastatin

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0787
Synthesis of Cyrneine Diterpenoids

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0788
Total Syntheses of (–)-Crinipellin A and (–)-Crinipellin B

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Synthesis of Heterocycles
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0789
Selective N-Alkylation of 2-Pyridones

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0790
A Halocyclization Approach to Enantioenriched Lactones

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0791
NHC-Catalyzed Asymmetric Synthesis of Cyclopentene-Fused Tetrahydroquinolines

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0792
Ferrocene-Catalyzed Electrosynthesis of Oxindoles and Dihydroquinolin-2-ones

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0793
Synthesis of Chromenopyridopyrazines and -diazepines

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0794
One-Catalyst, One-Pot, Two C–H Bond Activations

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0795
Double C–H Activation Approach to Chromenes

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0796
Stereoconserved Synthesis of Triazole-Fused Ketopiperazines

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0797
Enantioselective Syntheses of Indolines, Indoles, and Dihydro-2-quinolones

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0798
Zinc-Catalyzed Four-Component Synthesis of Highly Substituted Pyridines

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0799
Regiocontrolled Synthesis of Pentasubstituted Pyrroles

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0800
Rhodium-Catalyzed Indole/Pyrrole Cascade Synthesis

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0801
Tetrahydropyrans by an Enantioselective Cross-Dehydrogenative Coupling

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0802
Synthesis of Quinoline-4-carboxamides from Ketoxime Acetates and Isatins

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0803
Synthesis of Fused Benzothiophenes, Indoles, and Other Heterocycles

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Synthesis of Materials and Unnatural Products
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0805
Buckbowls Hold Radical Fare

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0806
Hypervalent Iodine Reagents Offer New Choice for Indole–Heteroaryl Coupling

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0807
Annulation Expands π−System of Naphthalene Dicarboximide

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0808
Arsoles with Strong Solid-State Emission

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0809
#Azaacenes #Axialchirality #CPL

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0810
Reductive Aromatization of Naphthalene Diimide to 2,7-Diazapyrene

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0811
Cooperativity is Always Key: Controlled Copolymerization Achieved with Lewis Pairs

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0812
Investigating the Antiaromaticity of Planar 12π and 16π Rings

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0813
Fluctuating Macromolecules from Controlled Defects

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0814
New Compounds Departing Trifluoromethoxylation Station

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0815
Flexible Pillar[6]arene for Enhanced Host–Guest Properties

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0816
A New Dimension to Nanographenes

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0817
Enantioselective Decarboxylative Cycloaddition by Palladium Catalysis

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0818
Asymmetric 1,3-Dipolar Cycloaddition of Cyclobutenones with Azomethine Ylides

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0819
Cobalt-Catalyzed Enantioselective Hydrogenation of Enamides FREE ACCESS

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0820
Intramolecular Enantioselective Palladium-Catalyzed Cycloaddition

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0821
Asymmetric Nickel-Catalyzed Intramolecular Hydroalkenylation FREE ACCESS

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0822
Pd/Ti Cooperative Catalysis: Diastereo-selective Synthesis of Spiro-Heterocycles

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0823
Rhodium-Catalyzed anti-Hydrosilylation of Internal Ynamides

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0824
Enantioselective Synthesis of N-Arylamines via Copper-Catalyzed Hydroamination

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0825
Copper-Catalyzed Synthesis of Chiral 1,2-Diamines

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0826
Ni-DBFOX Complex as a Bifunctional Photoredox and Lewis Acid Catalyst

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0827
Enantioselective Iridium-Catalyzed Allylation Using Enolate Surrogates

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0828
Enantioselective N-Allylic Alkylation of Hydrazones with Allylic Acetates

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0829
Copper-Catalyzed Asymmetric [3+2] Cycloaddition Reaction

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0830
1,4-Protosilylation of α,β-Unsaturated Ketimines

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0831
Palladium-Catalyzed Enantioselective Synthesis of α-Quaternary Succinimides

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0832
Rhodium-Catalyzed Asymmetric Hydrogenation to Form Chiral γ-Lactams

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0833
Enantioselective Alkenylation of Acyclic Enol Ethers

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0834
Selective Remote Ring Opening by Palladium Catalysis

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0835
Enantioselective Arylative Intramolecular 1,4-Allylations

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0836
Silver-Catalyzed Cycloaddition of Glycine Aldimino Esters to Imines

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0837
Enantioselective Arylation of γ,δ-Unsaturated β-Ketophosphonates

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0838
Biaryl Atropisomers by Pd/Norbornene-Catalyzed Three-Component Reaction

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0839
Rhodium-Catalyzed Enantioselective Synthesis of β-Stereogenic Amines

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0840
Enantioselective Palladium-Catalyzed Aza-Wacker Cyclization

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0841
Cooperative Lewis Base/Palladium-Catalyzed Allylic Alkylation of Esters

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0842
Palladium/Brønsted Acid Co-catalyzed Diazo Insertion to C–O or C–N Bonds

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0843
Enantioselective Aldol Reaction of an α-Vinylacetamide

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0844
Ytterbium-Catalyzed Enantioselective Reduction of Ketones

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0845
Palladium-Catalyzed Enantioselective Synthesis of Tetrahydroquinazolines

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0846
Copper-Catalyzed Enantioselective Formal [3+3] Annulation

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Metal-Mediated Synthesis
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0847
Nickel-Catalyzed 1,2-Dialkylation of Alkenes

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0848
Light-Induced 1,2-Carboboration of Unactivated Alkenes

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0849
Nickel-Catalyzed Decarbonylative Methylation of Phenyl and Methyl Esters

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0850
Iron-Catalyzed Difluoroalkylation of Grignard Reagents

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0851
Stereospecific S_N2-Type Substitution Using Arylboronic Acids

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0852
Electron-Catalyzed C(sp²)–C(sp²) Cross-Coupling

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0853
Mild Amination of Organoboronic Acids Using N-Hydroxylamines

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0854
Zirconium-Catalyzed Carboalumination–Transmetalation

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0855
Synthesis of Trifluoroborate-Iminiums and their Transformation into α-Aminotrifluoroborates

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0856
A Novel Palladium(II)-Initiated Borono-Catellani Reaction Under Air

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0857
Grignard-Mediated Synthesis of Trisubstituted Triazenes

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0858
Nickel-Catalyzed Cross-Couplings of Benzylic Pyridinium Salts

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0859
Regioselective Hydrostannation of Alkynes Using a Molybdenum Catalyst

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0860
Efficient Hydrotrifluoromethylation of Unactivated Alkenes

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Organo- and Biocatalysis
z0861
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0861
Hydrogen-Bonding Phase-Transfer Catalyst Enabled Asymmetric Fluorination FREE ACCESS

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0862
9-Fluorenone as Photocatalyst for the Oxidation of Alcohols with Air

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0863
Enantioconvergent Allylation of (Arylpropargyl)acetates by an S_N1 Reaction

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0864
Chiral Amidophosphate-Induced Halooxy- and Haloazacyclizations

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0865
Indanol as Scaffold for Chiral Organoiodine Catalysts

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0866
α-Oxidation of Cyclic Ketones with 1,4-Benzoquinone through Enol Catalysis

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0867
Organocatalytic Synthesis of Axially Chiral Sulfone-Containing Styrenes

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0868
Chiral Acid Catalyzed Asymmetric Cloke–Wilson Rearrangement

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0869
Whole-Cell Biotransformation of Benzene to Phenol

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0870
(–)-Ambrox Production by Biocatalysis Using Squalene Hopene Cyclase

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Polymer-Supported Synthesis
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0871
Photodehydrogenation of N-Heterocycles with Hexagonal Boron Carbon Nitride FREE ACCESS

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0872
Epoxidation of Alkenes on an Organosilica-Supported Molybdenum Complex

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0873
Controlled Oxidation of Alcohols on a Polymeric Copper Composite

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0874
Pyrido[2,3-d]pyrimidines by Domino Cyclization on a Solid Acid Catalyst

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0875
Annulation of Ynamides with Nitriles on a Gold(I) Catalyst

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0876
Controlled Hydrogenation of Alkynes on Au@N-Doped Carbon/TiO₂

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0877
[2+2+2] Cycloaddition of Alkynes by Using Pd–Au Alloy Nanoparticles

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0878
Cyclization of Alkynoic Acid Derivatitives Catalyzed by Magnetic PdO Nanoparticles

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0879
Chemoselective Hydrogenation of α-Keto Amides on Ceria Nanospheres

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0880
Decarboxylative A³-Coupling on a Chitosan-Supported Copper Catalyst

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0881
Oxidative Esterification of Thiols with Alcohols on a Cobalt Nanocatalyst

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0882
The Suzuki–Miyaura Reaction Catalyzed by Supported Pd₅₀Co₅₀ Nanoalloys

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0883
Synthesis of Imidazo[1,2-a]pyrimidines by A³-Coupling on CuO Nanoparticles

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