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Synlett 1995; 1995(1): 119-120
DOI: 10.1055/s-1995-4850
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The Role of Electronic and Stereoelectronic Effects on Asymmetric Iodine and Hydrogen Transfer Reactions of Conjugated Radicals

Dennis P. Curran* , Laurence Balas1
  • *Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, USA
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Publication History

Publication Date:
31 December 2000 (online)

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Hammett studies of three different class of conjugated radicals reveal very small electronic effects on stereoselective iodine and hydrogen transfer reactions.

acyclic stereochemistry - 1,2-asymmetric induction - benzyl radicals - ester-substituted radicals - atom transfer