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Synlett 1997; 1997(9): 1073-1074
DOI: 10.1055/s-1997-1537
DOI: 10.1055/s-1997-1537
letter
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Selective Demetalations of Iron Diene Complexes. Expedient Synthesis of Substituted (Z)-Allylalcohols
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Publication History
Publication Date:
31 December 2000 (online)
(3E)-6-Oxo-1,3-dienetricarbonyliron complexes 1 can be demetalated in good yields exclusively either to the free unrearranged (3E)-6-oxodiene 2 with ceric ammonium nitrate in methanol or to the (2Z)-6-oxoallylalcohol 3 by an excess of NaOH/H2O2.
diene complexes - allylalcohols - oxidation - demetalation - iron compounds